Analysis of wheat farmers’ risk perceptions and attitudes: evidence from Punjab,Pakistan

Natural Hazards - Agriculture involves multiple risks of which environmental and production threats are major ones. Farmers’ risk attitudes and risk perceptions have a significant role in...     

Preparation,Characterization of a Novel Chelating Resin Functionalized with o‐Hydroxybenzamide and Its Application for Preconcentration of Trace Metal Ions

A stable extractor of metal ions was synthesized through azo linking of o‐hydroxybenzamide (HBAM) with Amberlite XAD‐4 (AXAD‐4) and was characterized by elemental analyses, IR spectral, and thermal studies. Its water regain value and hydrogen ion capacity were found to be 12.93 and 7.68 mmol g^?1, respectively. The optimum pH range (with the half‐loading time [min], t_1/2) for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were 2.0–4.0 (5.5), 2.0–4.0 (7.0), 2.0–4.0 (8.0), 4.0–6.0 (9.0), 4.0–6.0 (12.0), and 2.0–4.0 (15.0), respectively. Comparison of breakthrough and overall capacities of the metals ascertains the high degree of column utilization (>70%). The overall sorption capacities for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were found to be 0.29, 0.22, 0.20, 0.16, 0.13, and 0.11 mmol g^?1 with the corresponding preconcentration factor of 400, 380, 380, 360, 320, and 320, respectively. The limit of preconcentration was in the range of 5.0–6.3 ng mL^?1. The detection limit for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) were found to be 0.39, 0.49, 0.42, 0.59, 0.71, and 1.10 ng mL^?1, respectively. The AXAD‐4‐HBAM has been successfully applied for the analysis of natural water, multivitamin formulation, infant milk substitute, hydrogenated oil, urine, and fish.     

Base Treated Cogon Grass (Imperata cylindrica) as an Adsorbent for the Removal of Ni(II): Kinetic,Isothermal and Fixed‐bed Column Studies

The adsorption of Ni(II) from aqueous solutions using base treated cogon grass or Imperata cylindrica (NHIC) was performed under batch and column modes. Batch experiments were conducted to determine the factors affecting adsorption such as pH, adsorbent dosage, initial nickel concentration, contact time and temperature. The fixed‐bed column experiment was performed to determine the practical applicability of NHIC and to obtain the breakthrough curve. Adsorption was fast as equilibrium was achieved within 60 min, and was best described by the pseudo second order model. According to the Langmuir model, a maximum adsorption capacity of 6.96 mg/g was observed at pH 5 and at a temperature of 313 K. Thermodynamic parameters such as ΔG⁰, ΔH⁰ and ΔS⁰ were calculated, and indicated that adsorption was a spontaneous and endothermic process. The mechanistic pathway of Ni(II) uptake was examined by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and energy dispersive X‐ray (EDX) spectroscopy. The Thomas and Yoon‐Nelson models were used to analyze the fixed‐bed column data.     

Enhancing the interface friction between glass fiber-reinforced polymer sheets and sandy soils through sand coating

ABSTRACT

Soil-pile interface friction is an important geotechnical engineering factor to be considered in achieving a safe and cost-effective design. Conventional materials such as concrete, steel, and wood exhibit serious long-term soil substructure problems, particularly with regard to durability, deterioration, and corrosion. Fiber-reinforced polymer (FRP) composites are potential alternatives for addressing these long-term problems. This paper describes the results of an experimental study of the interface friction between sandy soil and glass FRP (GFRP) sheets coated with different ratios of sand per unit of surface area. A direct shear test was used to study 18 different groups of GFRP specimens. The test parameters were the amount of silica sand coating and normal stresses in the direct shear tests. The GFRP specimens were sheared against three types of soil: sand, silty sand, and sandy lean-clay, of which the first two were used in both dense and loose states. The experimental results showed that coating the GFRP sheets with silica sand was effective in enhancing the interface friction with sandy soils under different normal stresses. A pile implication analysis was also performed to compare the effect of sand coated GFRPs on the load capacity of friction piles with different length to diameter ratios.     

A Web GIS Application for Dams and Drought in India

Dams and diversion are built in India for meeting needs of water and energy. Due to variability of monsoon in space and time, precipitation falls short or exceeds causing in extreme cases drought and floods respectively. Water resource planners and engineers need information on dams and diversion. Drought information is needed in disaster management. For dissemination of these spatial data, Web GIS technology can be utilized, which is amalgamation of several information technologies. For Web GIS application, a high end, powerful and open source software, namely Mapserver is available. The software is CGI technology based. An application on dams and drought information for India is conceptualized using Mapserver. It is planned to write the application by modifying available tutorial. This will require writing DHTML pages, writing logic, using available libraries etc. Separate DHTML pages will be written for dam and drought applications. For dam application pages will be written for storage, hydropower and all dams. The drought application will provide maps of rainfall over districts for different SPI and time scales.     

Regional scale rainfall–runoff modeling using VARX–MGARCH approach

Multivariate time series modeling approaches are known as useful tools for describing, simulating, and forecasting hydrologic variables as well as their changes over the time. These approaches also have temporal and cross-sectional spatial dependence in multiple measurements. Although the application of multivariate linear and nonlinear time series approaches such as vector autoregressive with eXogenous variables (VARX) and multivariate generalized autoregressive conditional heteroscedasticity (MGARCH) models are commonly used in financial and economic sciences, these approaches have not been extensively used in hydrology and water resources engineering. This study employed VARX and VARX–MGARCH approaches in modeling mean and conditional heteroscedasticity of daily rainfall and runoff records in the basin of Zarrineh Rood Dam, Iran. Bivariate diagonal VECH (DVECH) model, as a main type of MGARCH, shows how the conditional variance–covariance and conditional correlation structure vary over the time between residuals series of the fitted VARX. For this purpose, five model fits, which consider different combinations of twofold rainfall and runoff, including both upstream and downstream stations, have been investigated in the present study. The VARX model, with different orders, was applied to the daily rainfall–runoff process of the study area in each of these model fits. The Portmanteau test revealed the existence of conditional heteroscedasticity in the twofold residuals of fitted VARX models. Therefore, the VARX–DVECH model is proposed to capture the heteroscedasticity existing in the daily rainfall–runoff process. The bivariate DVECH model indicated both short-run and long-run persistency in the conditional variance–covariance matrix related to the twofold innovations of rainfall–runoff processes. Furthermore, the evaluation criteria for the VARX–DVECH model revealed the improvement of VARX model performance.     

Earthquake hazard assessment in the Zagros Orogenic Belt of Iran using a fuzzy rule-based model

Producing accurate seismic hazard map and predicting hazardous areas is necessary for risk mitigation strategies. In this paper, a fuzzy logic inference system is utilized to estimate the earthquake potential and seismic zoning of Zagros Orogenic Belt. In addition to the interpretability, fuzzy predictors can capture both nonlinearity and chaotic behavior of data, where the number of data is limited. In this paper, earthquake pattern in the Zagros has been assessed for the intervals of 10 and 50 years using fuzzy rule-based model. The Molchan statistical procedure has been used to show that our forecasting model is reliable. The earthquake hazard maps for this area reveal some remarkable features that cannot be observed on the conventional maps. Regarding our achievements, some areas in the southern (Bandar Abbas), southwestern (Bandar Kangan) and western (Kermanshah) parts of Iran display high earthquake severity even though they are geographically far apart.     

A new contribution to the geology of the Egyptian Red Sea shelf using geophysical data

The study examines the Egyptian Red Sea shelf and throws more light on the structural set-up and tectonics controlling the general framework of the area and nature of the crust. Herein, an integrated study using gravity and magnetic data with the available seismic reflection lines and wells information was carried out along the offshore area. The Bouguer and reduced-to-pole aeromagnetic maps were processed and reinterpreted in terms of rifting and plate tectonics. The qualitative interpretation shows that the offshore area is characterized by positive gravity everywhere that extremely increases towards the centre of the graben, supporting the presence of an intrusive zone below the axial/main trough. The gravity data were confirmed by the presence of high magnetic amplitudes, magnetic linearity and several dipoles concentrated along the rift axis for at least 250 km. The lineament analysis indicates widespread of the Erythrean (Red Sea) trend that was offset/cut by transform faults in the NE direction (Aqaba). The tectonic model suggests the presence of one tensional (N65°E) and two compressional (N15°W, N30°W) phases of tectonism, resulted in six cycles of deformations, classified into three left lateral (N35°E, N15°E and N–S) and three right lateral (N85°W, N45°W and N60°W). The basement relief map reveals a rough basement surface that varies in depth between 1 and 5.6 km. It outlines several offshore basins, separated from each other by ridges. The models show that the basement consists of tilted fault blocks, which vary greatly in depth and composition and slopes generally to the west. They indicate that the coastal plain is underlain by acidic basement blocks (continental crust) with no igneous activity while suggesting elevated basic materials (oceanic crust) below the rift axis. The study suggests that northern Red Sea forms an early stage of seafloor spreading or at least moved past the late stage of continental rifting.     

Addition of Phosphorus and Nitrogen Support the Invasiveness of Alternanthera Philoxeroides Under Water Stress

Coordination of plant functional traits with changes in the environment is helpful to understand the mechanisms underlying both invasiveness and adaptation of plants. Thus, to investigate the performance and functional traits in invasive Alternanthera philoxeroides (Mart.), an experiment of water stress is conducted with different nutrient concentrations. Alternanthera philoxeroides plants are grown under natural and nutrient soils and subjected to three levels of nitrogen (N) and phosphorus (P) solution: ambient P and N concentration (P?N?), P addition with an ambient N concentration (P+N?), and P addition with high N concentration (P+N+) in combination with three different irrigation water levels as 1) 100% irrigation, 2) 50% irrigation, and 3) 25% deficit irrigation. Based on results, A. philoxeroides produces significantly higher biomass in both soils under 100% irrigation with P+N? treatment and exhibits higher values of leaf area and root length. However, 25% irrigation with P?N? treatment in both soils exerts a significant negative effect on relative growth rate and root/shoot ratio of A. philoxeroides plants. Under 50% irrigation in soils with both P+N? and P+N+ treatments, high values of leaf nitrogen are recorded. Moreover, nutrient soil is more supportive to A. philoxeroides than natural soil.