Kyanite eclogites

Prior experimental work has shown that in the laboratory the mineralogy of eclogites is sensitive to the ratio of CaO ∶ MgO ∶ FeO and that the reaction pyroxene + kyanite?garnet + quartz proceeds to the right at high pressures in rocks rich in magnesium and to the left in rocks rich in calcium and iron. Typical basalts crystallized at high pressure never contain kyanite. The chemistry and mineralogy of a large number of naturally occurring eclogites show they belong to three classes.

1. Kyanite-free magmatic eclogites, rich in magnesium, from:
2. kimberlites
3. dunites and serpentinites.
4. Kyanite-bearing eclogites and grosspydites rich in CaO and low in FeO with intermediate MgO from:
5. kimberlites
6. gneisses.
7. Kyanite-free eclogites of metamorphic origin rich in iron with low magnesium and intermediate amounts of calcium from:
8. glaucophane schists
9. gneisses.

     

A revision of the ammonite faunas of the type Cenomanian. i. Introduction,ancyloceratina

This paper forms the first part of a revision of the ammonite faunas of the Cenomanian stratotype in the environs of Le Mans, Sarthe, France. The history of research on ammonites in the area is briefly noted, as is the lithostratigraphy. The systematics of the heteromorph ammonites (Ancyloceratina) is described, and the following taxa documented: Hamites simplex d'Orbigny, Sciponoceras baculoides (Mantell), Sciponoceras gracile (Shumard), Anisoceras plicatile (J. Sowerby), A. aff. plicatile, Idiohamites alternatus vectensis Spath, I. ellipticus radiatus Spath, Hypoturrilites gravesianus (d'Orbigny), H. tuberculatus (Bosc), H. mantelli (Sharpe), H. sp., Neostlingoceras carcitanense (Matheron), N. aff. carcitanense, Turrilites costatus Lamarck, T. acutus Passy, T. scheuchzerianus (Bosc), T. boerssumensis Schlüter, Mariella dorsetensis (Spath), M. cenomanensis (Schlüter), M. group of cenomanensis (Schlüter)-lewesiensis (Spath), M. spp., M. (Plesioturrilites) sp., Scaphites equalis J. Sowerby, S. obliquus J. Sowerby, S.(?) sp., and S. sp. juv.     

Ammonites from the Pawpaw Shale (Upper Albian) in northeast Texas

The lower part of the Pawpaw Shale in northeast Texas yields an abundance of diminutive limonitic ammonites, the assemblage being: Tetragonites sp. juv., Engonoceras serpentinum (Cragin, 1900), Conlinites wrighti gen. et sp. nov., Cantabrigites wenoensis (Adkins, 1920), Neophlycticeras (Neophlycticeras) sp., Neophlycticeras (Paradolphia) occidentalis sp. nov., Stoliczkaia (Stoliczkaia) clavigera Neumayr, 1875, Stoliczkaia (Lamnayella) worthense (Adkins, 1920), Stoliczkaia (Shumarinaia) asiatica Matsumoto and Inoma, 1975, Enigmaticeras riceae gen. et sp. nov., Flickia simplex Pervinquière, 1907, Ficheuria pernoni Dubourdieu, 1953, Ficheuria americana sp. nov., Anisoceras armatum (J. Sowerby, 1817), Hamites venetzianus Pictet, 1847, Mariella (Mariella) worthensis (Adkins and Winton, 1920), Mariella (Mariella) asper sp. nov., Lechites (Lechites) comanchensis (Adkins, 1920), Worthoceras worthense (Adkins, 1920), and Scaphites hilli Adkins and Winton, 1920.This assemblage is correlated with the Mortoniceras (Subschloenbachia) rostratum Subzone of the European sequence on the basis of the occurrence of that species in the underlying Weno Limestone, in the passage beds between the Pawpaw Shale and the succeeding Main Street Limestone, and the lower part of the Main Street.Some previous authors have interpreted the diminutive limonitic ammonites of the Pawpaw as being “dwarf” or “stunted”. The overwhelming majority of individuals are nuclei of much larger ammonites, with smaller numbers of adults of small species that occur in other facies and geographic locations, together with a smaller number still of paedomorphic dwarfs. The fauna is interpreted as a preservational one, where diagenetic pyrite formed in relatively small voids, either the early phragmocone chambers of larger ammonites, or the phragmocone and body chambers of genuinely diminutive species which oxidised to limonite during the weathering process.     

The influence of rock resistance on coastal morphology around Lord Howe Island,southwest Pacific

An Erratum has been published for this article in Earth Surface Processes and Landforms 27(7) 2004, 931. Lord Howe Island, in the northern Tasman Sea, is a remnant of a much larger Late Miocene basaltic shield volcano. Much of the island's coastline is exposed to waves that have unlimited fetch, but a marked contrast is provided by a fringing coral reef and lagoon that very effectively attenuate wave energy along a portion of the western coastline. The geology of the island is varied, with hard and resistant basalt lavas, breccias and tuffs of intermediate resistance, and highly erodible eolianites. This variability provides an excellent opportunity to examine the in?uence of rock resistance on the development of the spectacular rock coast landforms that occur around the island. The hardness of rocks and the extent of weathering around the coastline were assessed using a Schmidt hammer, and statistical analysis was undertaken to remove outlying values. On all but one occasion, higher mean rebound values were returned from fresh surfaces than weathered surfaces, but only half of these differences were statistically signi?cant. Shore platforms with two distinct levels are juxtaposed along two stretches of coastline and Schmidt hammer results lend support to hypotheses that the raised surfaces may be inherited features. Relative rock resistance was assessed through a combination of Schmidt hammer data and measurements of joint density, and constrained on the basis of morphological data. This approach formed a basis for examining threshold conditions for sea‐cliff erosion at Lord Howe Island in the context of the distribution of resistant plunging cliffs and erosional shore platforms. Copyright © 2004 John Wiley & Sons, Ltd.     

Surface chemistry and relative Ni sorptive capacities of synthetic hydrous Mn oxyhydroxides under variable wetting and drying regimes

The surface binding site characteristics and Ni sorptive capacities of synthesized hydrous Mn oxyhydroxides experimentally conditioned to represent three hydrological conditions—MnO_XW, freshly precipitated; MnO_XD, dried at 37°C for 8 d; and MnO_XC, cyclically hydrated and dehydrated (at 37°C) over a 24-h cycle for 7 d—were examined through particle size analysis, surface acid-base titrations and subsequent modelling of the pK_a spectrum, and batch Ni sorption experiments at two pH values (2 and 5). Mineralogical bulk analyses by XRD indicate that all three treatments resulted in amorphous Mn oxyhydroxides; i.e., no substantial bulk crystalline phases were produced through drying. However, drying and repeated wetting and drying resulted in a non-reversible decrease in particle size. In contrast, total proton binding capacities determined by acid-base titrations were reversibly altered with drying and cyclically re-wetting and drying from 82 ± 5 μmol/m² for the MnO_XW to 21 ± 1 μmol/m² for the MnO_XD and 37 ± 5 μmol/m² for the MnO_XC. Total proton binding sites measured decreased by ≈75% with drying from the MnO_XW and then increased to ≈50% of the MnO_XW value in the MnO_XC. Thus, despite a trend of higher surface area for the MnO_XD, a lower total number of sites was observed, suggesting a coordinational change in the hydroxyl sites. Surface site characterization identified that changes also occurred in the types and densities of surface sites for each hydrologically conditioned Mn oxyhydroxide treatment (pH titration range of 2-10). Drying decreased the total number of sites as well as shifted the remaining sites to more acidic pK_a values. Experimentally determined apparent pH_zpc values decreased with drying, from 6.82 ± 0.06 for the MnO_XW to 3.2 ± 0.3 for the MnO_XD and increased again with rewetting to 5.05 ± 0.05 for the MnO_XC. Higher Ni sorption was observed at pH 5 for all three Mn oxyhydroxide treatments compared to pH 2. However, changes in relative sorptive capacities among the three treatments were observed for pH 2 that are not explainable simply as a function of total binding site density or apparent pH_zpc values. These results are the first to our knowledge, to quantitatively link the changes induced by hydrologic variability for surface acid base characteristics and metal sorption patterns. Further, these results likely extend to other amorphous minerals, such as Fe oxyhydroxides, which are commonly important geochemical solids for metal scavenging in natural environments.     

Shore platform morphology on a rapidly uplifting coast,Wellington, New Zealand

The coast of Wellington, New Zealand, is tectonically active and contains a series of uplifted and contemporary shore platforms that are developed in Triassic Greywacke. The platform profiles are rugged with relief of metre scale common. The surveyed platforms were formed at, and at two distinct levels 1–1·5 and 2–2·5 m above, mean sea level. They range in width up to 70 m and are highly fractured with fracture densities in excess of 20[sol ]m² common. The rate of development of these platforms is rapid, with lateral erosion rates of up to 0·15 m[sol ]yr calculated, allowing platform development to occur over centennial scales. Even given this rapid development, continued instantaneous uplift of the coast has meant they are unable to reach an equilibrium state, whereby the effectiveness of wave processes in removing material is reduced by platform extension. The co‐seismic uplift means that the rear of the platforms is raised beyond the limits of marine process and has become an area of deposition. Although no direct process measurements were made the highly fractured nature of the bedrock appears to play a major role in platform evolution, with wave processes being easily able to pluck blocks as evidenced by fresh erosion scars and active gravel beaches at the rear of many platforms. This coast therefore represents an extremely dynamic youthful shore platform environment, where the processes of marine abrasion can be observed over historical timescales. Copyright © 2005 John Wiley & Sons, Ltd.     

Synchrony of Southern Hemisphere Late Pleistocene arid episodes: A review of luminescence chronologies from arid aeolian landscapes south of the Equator

Luminescence-dating chronologies that have been reported in various studies of Late Pleistocene arid-land aeolian sequences from Australia, southern Africa and South America are reviewed with the objective of determining whether any pan-hemispheric synchroneity existed in the timing of landscape responses to Late Quaternary climate changes south of the equator. The results broadly show that contemporaneous regional arid-land aeolian activity occurred in Australia and southern Africa during the periods ca 65–41 and 36–9 ka. The relatively limited luminescence data from the South American subcontinent also point to recurrent arid-land aeolian deposition between 63 and 8 ka, with increasing frequency in the period ca 32–8 ka. Records from all three continents suggest a period of reduced aeolian activity between 41 and 36 ka. Overall, the data are indicative of extensive landscape instability of the low to mid-latitudes in the Southern Hemisphere during the last glacial period, particularly at the Last Glacial Maximum, which accords with mainstream opinions. Aeolian activity during the Holocene has generally been localised. The rigour with which comparisons can be made between the different studies, however, is constrained by variations in practices between laboratories and changes that have occurred to luminescence dating procedures over the years.     

Lithological control on the elevation of shore platforms in a microtidal setting

The shore platforms on Shag Point, southern New Zealand, are quasi‐horizontal surfaces and are developed between supratidal and low water spring levels. A range of morphologies occur, with more exposed platforms having a distinct low‐tide cliff, in contrast to low‐tide surfaces where the seaward edge is buried beneath rubble and macro‐algal growth. The platforms range in width from 20 to 80 m and are eroded into Late Cretaceous/Early Tertiary fine marine sandstones and mudstones. Shore platforms have formed in two principal lithological units: a homogeneous unit that is characterized by few discontinuities, and a fractured unit with joints spaced about 0·5 m apart. Rock hardness is low in both units (L‐type Schmidt hammer rebound values of 31 ± 4), and there is little systematic variation in values between the two units in which platforms have developed. Case‐hardened concretions within the sandstone are significantly harder than surrounding rock and cause local relief of metre scale as the spherical diagenetic features are eroded from the bedrock. They do not, however, appear to affect broad‐scale platform geometry. Joints within the bedrock are a primary control on platform elevation. Platforms formed in jointed rock occur at the lower portion of the intertidal zone, in contrast to platforms formed in unjointed bedrock, in which horizontal surfaces occur at or above mean high water spring tide level. Rock structure, therefore, appears to be the primary determinant factor of platform geometry at Shag Point. Copyright © 2006 John Wiley & Sons, Ltd.