Alluvial fan and wetland interactions: evidence of seasonal slope wetlands from the Silurian of south central Wales,UK

Distal environs of the Ludlow‐age Trichrug Formation from south central Wales (UK) detail deposition on the outer fringe of an ephemeral debris flow‐dominated alluvial fan. Debrites and subordinate sheetflood deposits are interbedded with sporadic thin sandstone‐dominated heterolithic units deposited in shallow, ephemeral ponds in the axial valley. The latter slope wetland system fringed the permeable alluvial fan deposits, being maintained by streamflow, precipitation and ground water recharge. A prolonged high water table is indicated by low chroma intervals interpreted as the result of gleying. A variety of redoximorphic indicators, including colour mottling and ferricrete concretions, are evidence of iron mobilization and concentration associated with a seasonally fluctuating water table. The slope wetlands were colonized periodically by Skolithos‐generating organisms, most likely to have been arthropods. The widespread occurrence of redoximorphic indicators and ferricrete contrasts markedly with calcrete Vertisols in penecontemporaneous continental deposits (Lower Old Red Sandstone) of the region. It is likely that the alluvial fan‐toe area was the site of a wetland depression, which maintained a high, though fluctuating, water table. In contrast the alluvial channel reaches of the surrounding drainage network were significantly better drained, with floodplains prone to wetting and drying and Vertisol palaeopedogenesis.     

Detection of Lateglacial distal tephra layers in the Netherlands

Three distal tephra layers or cryptotephras have been detected within a sedimentary sequence from the Netherlands that spans the last glacial-interglacial transition. Geochemical analyses identify one as the Vedde Ash, which represents the southernmost discovery of this mid-Younger Dryas tephra so far. This tephra was found as a distinct horizon in three different cores sampled within the basin. The remaining two tephras have not been geochemically 'fingerprinted', partly due to low concentrations and uneven distributions of shards within the sequences sampled. Nevertheless, there is the potential for tracing these tephra layers throughout the Netherlands and into other parts of continental Europe. Accordingly, the possibilities for precise correlation of Dutch palaeoenvironmental records with other continental, marine and ice-core records from the North Atlantic region are highlighted.     

The formation of ooids

Field and laboratory studies suggest that different types of ooids form during quiet and agitated water conditions. Both types have been synthesized in the laboratory. Quiet water types exhibit a radial orientation of carbonate crystals, whereas in those formed in agitated conditions, a tangential orientation is prevalent. Successful laboratory formation of quiet water ooids was accomplished in supersaturated seawater solutions containing humic acids. Negative results were obtained from strictly inorganic solutions, and from those containing simple amino acids, single proteins, mixtures of proteins or mucopolysaccharides, soil and sediment extracts. Partly successful results were obtained using an organic extract from Bahamian ooids. The organic parameters most important in quiet water ooid formation are molecular weight, the presence of carboxyl groups and an ability to participate in hydrophobic/hydrophilic interactions, all of which are critical to membrane formation. Membranes form concentric shells which act as growth surfaces for carbonate and also induce the periodicity in carbonate precipitation. Ooids exhibiting a tangential orientation of batten-like crystals have been synthesized under conditions of agitation, supersaturation and without the intervention of organic processes during the precipitation. Complete growth may be divided into agitation, resting and sleeping stages In the agitation stage, quartz nuclei induce an inorganic, heterogeneous nucleation from a supersaturated solution, which finally ceases as a result of Mg²⁺ and possibly H⁺ poisoning of the carbonate surfaces. No further precipitation occurs until the crystal surfaces are reactivated by removal of Mg²⁺ and H⁺ during the resting stage. Following a series of agitation and resting stages, precipitation is inhibited by a degree of poisoning which is not totally removed during the resting stage. For further growth, a new substrate is required and is provided by the development of organic membranes around the grains. This occurs when the grains are buried in the subsurface, the period of organic growth constituting the sleeping stage. Only 2% of an ooid's life is spent growing in the agitated environment, while 95% of its life is spent accreting organic membranes in the subsurface. Our experimental work indicates that ooids of Bahamian type are inorganic precipitates. The tangential arrangement of battens is the result of suspension in an environment where the degree of turbulence is sufficient to induce grain to grain contact of sufficient strength and frequency to inhibit any crystal growth other than tangential. The role of organics is to provide a substrate for further growth after precipitation has slowed to a point when no further accretion is occurring.     

FORTRAN PROGRAMME FOR THE ANALYSIS AND GRAPHICAL PRESENTATION OF GEOLOGICAL DATA

Computers are being used increasingly for the analysis of quantitative geological data. An outline is given of the advantages of contemporaneously using both computer and a connected automatic plotter. It is suggested that the quality of the automatic plotter output is such as to preclude the services of a draftsman in the preparation of many graphics for publication.