天津市滨海新区芦苇湿地恢复适宜性评价

利用综合评价模型,结合地理信息系统技术的空间分析功能,以土地利用、土壤类型、坡度、降雨量和人类干扰活动作为评价因子,对天津滨海新区芦苇湿地恢复进行了适宜性评价。结果表明,较适宜开展湿地恢复的比例为21.46%,一般适宜比例为21.87%,不适宜比例占56.68%,其中较适宜湿地恢复的区域集中分布在北大港湿地自然保护区周边、独流减河下游、北塘入海口以及沿海滩涂,海河流域两侧也有零星分布。在适宜性评价基础上,对未来芦苇湿地恢复与建设的重点区域进行了成效预评估,芦苇对TC、TN、TP的年吸收通量约为1.3935×104、0.0258×104、0.0017×104t,能有效地减少入海排污压力和污染物对近岸海域环境质量的影响。研究结论可为天津湿地治理与生态恢复、土地利用结构调整、景观优化等提供理论依据和科学参考。     

Study of Influence of Regional Geodynamic Background on Strata Behaviors in China's Tongxin Mine

Strata behaviors are mainly affected by regional geodynamic background. The influence of rock mass stress and energy distribution on strata behaviors in the Tongxin mine is studied in terms of regional tectonic movement, seismic activity and tectonic stress field. The results show that the extrusion lifting movement of Kouquan fault adjacent to the Tongxin mine results in the stress concentration in the rock of the Carboniferous coal bed and accumulation of a large amount of elastic energy and forms structural background of Tongxin mine. Due to various seismic activities in the mine area, the strain energy is known to reach much higher levels, up to 0.5×10⁸ J^1/2. Since the stratigraphic structure is sensitive to the mining operation, the strain energy could cause strong strata behaviors. A special geological structure model of the Tongxin mine is established based on the geodynamic division method. The distribution of regional structure stress field is determined by the rock mass stress analysis system. Based on this model, Tongxin mine is divided into five areas with high stress, eight areas with low stress and eight areas with gradient stress. The strong strata behaviors mostly occur in high stress areas. These results could provide guidance to predict the strength of regional or mine pressure and control strata behavior in different areas.     

A new landslide-induced tsunami simulation model and its application to the 1792 Unzen-Mayuyama landslide-and-tsunami disaster

By combining landslide dynamics research and tsunami research, we present an integrated series of numerical models quantitatively simulating the complete evolution of a landslide-induced tsunami. The integrated model simulating the landslide initiation and motion uses measured landslide dynamic parameters from a high-stress undrained dynamic-loading ring shear apparatus. It provides the numerical data of a landslide mass entering and moving under water to the tsunami simulation model as the trigger of tsunami. The series of landslide and tsunami simulation models were applied to the 1792 Unzen-Mayuyama megaslide and the ensuing tsunami disaster, which is the largest landslide disaster, the largest volcanic disaster, and the largest landslide-induced tsunami disaster to have occurred in Japan. Both the 1792 megaslide and the tsunami portions of the disaster are well documented, making this an excellent test of the reliability and precision of the new simulation model. The simulated tsunami heights at the coasts well match the historical tsunami heights recorded by “Tsunami-Dome-Ishi” (a stone showing the tsunami reaching point) and memorial stone pillars.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

Open image in new window

Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

硫酸镁对仿刺参幼参麻醉效果的研究

本研究以硫酸镁作为麻醉剂,比较了在不同水温条件下硫酸镁对仿刺参幼参的麻醉效果,分析了不同浓度硫酸镁对仿刺参幼参的麻醉效果。实验水温设置11℃、13℃、15℃、17℃、19℃和21℃六个温度梯度,实验用仿刺参幼参规格分为大规格(L)40.26±1.84g、中规格(M)21.83±1.72g、小规格(S)11.03±1.63g。实验结果显示:1.在硫酸镁麻醉剂浓度相同时,仿刺参规格越大麻醉所需时间越长,复苏时间却越短;随着麻醉剂浓度增加,对仿刺参幼参麻醉时间相应缩短,但复苏时间呈现逐渐延长。不同浓度硫酸镁麻醉剂对不同规格仿刺参的麻醉效果具有显著差异(P0.05)。2.在水温11℃~20℃范围内,随着水温的升高,对仿刺参幼参的麻醉时间从26.13±17.78min缩短到21.47±3.52min,但复苏时间从26.13±17.78min增加到71.05±12.32min,不同水温条件下硫酸镁对仿刺参幼参麻醉效果影响显著(P0.05)。研究表明,仿刺参体重在20g以下的适宜麻醉浓度为0.1~0.25mol·L-1,体重在20g以上的适宜麻醉浓度为0.25~0.35mol·L~(-1)。     

基于层次分析法的德州地面沉降易发区的可拓学划分应用

基于物元模型的可拓学理论分析,提出华北平原德州地面沉降易发区的可拓学划分方法。利用地面沉降易发性分级、分类标准和影响因子分析,构造出经典域物元和节域物元,应用物元和可拓集合中的关联函数,建立了易发性等级综合评判的可拓评价模型,通过基于层次分析法的可拓学评价分析,采用正方形等间距(2km×2km)剖分了135个网格,再将剖分单元转化成面元,经过等值差分,得到了地面沉降易发区划结果。计算结果显示,可拓学方法能够实现定量化、多因子评价地面沉降易发性等级问题,从而科学合理地指导地面沉降综合分区防治。     

赵各庄矿地下水位时间序列数字滤波分析

为了更好地了解煤矿地下水位的变化趋势,结合工程实例,运用递归和非递归2种滤波技术进行分析,通过对比2种滤波技术的滤波效果,可以得到地下水位的变化规律和成因机理。结果表明:滤波系数的调校对滤波效果的影响至关重要。根据平滑度指标、均方根误差和信噪比对现有观测数据进行计算的结果可知,当b=0.5时递归滤波效果相对较好,当q=5时非递归滤波效果相对较好。滤波结果可以作为预测未来该地区地下水位变化趋势的依据,也可以为安全生产提供参考。     

山东曹县地区土壤地球化学特征

山东省曹县地区土壤地球化学调查是按浅层土壤样品1点/4 km~2,深层土壤样品1点/16 km~2。测试N,P,K,Cu,Zn,B,Mo,Mn,F,As,Hg,Pb,Cr,Cd等14种指标。在统计这些指标的表层、深层土壤地球化学特征参数的基础上,对其与世界、全省同类参数的差异进行了分析,并分析了区内表层、深层土壤元素含量的相关性,认为该区表层土壤元素含量的显著特征是高F而低P,Zn,Mo。大部分元素在表层土壤中的含量继承了土壤母质的成分特征,但N,P,F,Hg等受人为活动和污染源的作用在表层土壤中明显富集。     

胶东埠上金矿煌斑岩地球化学特征及成因

大量的研究资料表明煌斑岩与金矿在空间上、时间上具明显的对应关系。埠上金矿位于胶东玲珑金矿田西南方向的金岭金矿田的中北部;有关该矿区煌斑岩的研究资料较少。该文结合岩石学、矿物学、大地构造学等特征,对区内煌斑岩的地球化学进行了研究,揭示其内在成因,认为区内煌斑岩是因该区受到古太平洋板块的俯冲、华北板块与杨子板块碰撞造山及郯庐断裂带等构造岩浆活动的影响,俯冲洋壳析出的流体交代地幔形成的具氧化性的EM1型富集型地幔岩浆于造山拉张期在大陆活动边缘浅成侵入而成的。     

新疆额尔宾山花岗岩侵位年龄和成因及其对南天山洋闭合时代的限定

额尔宾山花岗岩岩体位于南天山晚古生代侵入岩带,对该花岗岩进行锆石U-Pb定年获得296.1±1.8Ma的年龄,为早二叠世。岩石主量元素分析结果表明,该花岗岩的Si O2含量为66.96%~67.3%,富碱(Na2O+K2O=7.53%~7.97%),K2O/Na2O1(1.15~1.27),属高钾钙碱性系列岩石;Al2O3为15.56%~15.62%,Al2O3K2O+Na2O+Ca O,属于过铝型。岩石稀土元素配分模式呈现轻稀土元素(LREE)富集((La/Yb)N=27.03~30.62)、重稀土元素(HREE)亏损((LREE/HREE)=18.2~20.1)、具有中等程度的负Eu异常(δEu=0.64~0.68)。微量元素判别结果显示,其具有I-A型花岗岩过渡的特征。结合区域地质背景综合分析,初步认定该岩体可能形成于南天山同碰撞向后碰撞构造体制转换时期,据此可以推测南天山洋盆闭合时限至少应该在早二叠世以前。