Correlation of Néel temperature and vacancy defects in fine-particle goethites

Positron annihilation lifetime spectroscopy (PALS) has been used to study the vacancy-type defects in fine-particle goethites (α-FeOOH). The PALS spectra reveal three components. The intermediate lifetime component (τ₂, I₂) is attributed to positrons trapped at vacancy defects. The relative intensity of the intermediate lifetime component, I₂, increases significantly with decreasing Néel temperature, and this increase is attributed to increasing concentration of vacancy defects. These results support a model of magnetic ordering of clusters arising from a high concentration of iron vacancies which reduces the Néel temperature in these fine-particle goethites.     

An improved method of least-squares parameter estimation with pumping-test data

Least-squares estimation of storativity and transmissivity from pumping-test data has been concerned with finding the lowest point on a mathematical surface. Since there is no guarantee that such surfaces do not contain local minima, the accuracy of the estimate may be dependent upon the selection of “good” initial values.

An improved estimation procedure can be obtained by converting the two-dimensional minimisation problem into an equivalent form in one dimension. The resulting line function can then be easily evaluated through any given feasible interval. This approach avoids the requirement of initial estimates and always returns the true estimates after a single computation sequence.

Examples are given of the application of the method to both drawdown and recovery data, together with a simple model for the determination of estimation error.     

Monitoring unrest in a large silicic caldera,the long Valley-inyo craters volcanic complex in east-central California

Recent patterns of geologic unrest in long Valley caldera in east-central California emphasize that this large, silicic volcanic system and the adjacent, geologically youthful Inyo-Mono Craters volcanic chain are still active and capable of producing locally hazardous volcanic eruptions. A series of four magnitude -6 earthquakes in May 1980 called attention to this current episode of unrest, and subsequent activity has included numerous earthquake swarms in the south moat of the caldera accompanied by inflation of the resurgent dome by more than 50 cm over the last five years. The seismicity associated with this unrest is currently monitored by a network of 31 telemetered seismic stations with an automatic processing system that yelds hypocentral locations and earthquake magnitudes in near-real time. Deformation of the ground is monitored by a) a series of overlapping trilateration networks that provide coverage ranging from annual measurements of regional deformation to daily measurements of deformation local to the active, southern section of the caldera, b) a regional network of level lines surveyed annually, c) a regional network of precise gravity stations occupied annually, d) local, L-shaped level figures surveyed every few months, and e) a network of fourteen borehole tiltmeter clusters (two instruments in each cluster) and a borehole dilatometer, the telemetered signals from which provide continuous data on deformation rates. Additional telemetered data provide continuous information on fluctuations in the local magnetic field, hydrogen gas emission rates at three sites, and water level and temperatures in three wells. Continuous data on disharge rates and temperatures from hot springs and fumaroles are collected by several on-site recorders within the caldera, and samples for liquid and gas chemistry are collected several times per year from selected hot springs and fumaroles.     

Insights into oil cracking based on laboratory experiments

The objectives of this pyrolysis investigation were to determine changes in (1) oil composition, (2) gas composition and (3) gas carbon isotope ratios and to compare these results with hydrocarbons in reservoirs. Laboratory cracking of a saturate-rich Devonian oil by confined, dry pyrolysis was performed at T=350–450 °C, P=650 bars and times ranging from 24 h to 33 days. Increasing thermal stress results in the C₁₅₊ hydrocarbon fraction cracking to form C_6–14 and C_1–5 hydrocarbons and pyrobitumen. The C_6–14 fraction continues to crack to C_1–5 gases plus pyrobitumen at higher temperatures and prolonged heating time and the δ ¹³C_ethane–δ¹³C_propane difference becomes greater as oil cracking progresses. There is considerable overlap in product generation and product cracking. Oil cracking products accumulate either because the rate of generation of any product is greater than the rate of removal by cracking of that product or because the product is a stable end member under the experimental conditions. Oil cracking products decrease when the amount of product generated from a reactant is less than the amount of product cracked. If pyrolysis gas compositions are representative of gases generated from oil cracking in nature, then understanding the processes that alter natural gas composition is critical.     

Contrasting water management techniques in Tunisia: towards sustainable agricultural use

Tunisia is a marginal country hydrologically and it has adopted a number of distinctive methods of water management for agriculture. The central region supports modern dam irrigation, whilst traditional rainwater harvesting is practiced in the south. These contrasting techniques are described and evaluated in terms of sustainability using empirical field data and secondary literature for two study sites. Research focuses primarily on the physical environment, but socio-cultural and economic viability are also examined. Analysis indicates that traditional water management advantageously partitions the continuum dividing hazards and resources through subtle manipulation of the environment. A potentially hazardous environment is rendered secure by resourceful water management based on community action and cumulative knowledge. This practice minimizes community dependency and local economic imbalance. With dam irrigation, carrying capacity is established more forcibly by centralized control in order to place society within world markets. An almost total break from environmental variability is made in the short term, but this can lead to disequilibrium over longer durations. Additionally, the spatial and social distributions of development are uneven. In Tunisia, maintenance of traditional methods can reduce the negative impacts caused by modern programmes and support their positive characteristics. A mix of both methods offers a foundation to sustainable water supply in the new millennium.     

Sedimentary response of Pagham Harbour, southern England to barrier breaching in AD 1910

This paper examines the evolution of Pagham Harbour, southern England following storm-induced breaching of a protective barrier in AD 1910. Stratigraphic studies of sediments collected from intertidal areas show the presence of a distinct stratigraphic horizon in the northeast of Pagham Harbour at ca. 0 to +1.0 m ordnance datum (OD). Radiometric data indicate that this horizon is a ‘reclamation surface’ formed after land claim in AD 1846. Following marine flooding in AD 1910, sediment has accreted relatively rapidly (at a broadly constant rate of between 4 and 8 mm a⁻¹), wave and/or tidal energy have decreased and extensive marshes have developed. An asymptotic reduction in sediment accretion rate through time, as predicted in various theoretical models of salt marsh accretion, is not observed. Over the entire Pagham Harbour area, the period between AD 1948 and AD 1986 has seen an average marsh loss of 0.0087 km² a⁻¹, which is relatively small in comparison with other more exposed sites in the local area. Historically breached sites such as Pagham Harbour are common around European coasts, and these provide important natural laboratories within which the medium-term (decadal to centennial) coastal response to barrier breaching, and to managed-realignment coastal protection schemes, can be assessed.