近地表的烃类气体和深部油气藏

近地表土壤中的烃类微量分析是寻找油气藏气方法的一个基础,它提供了烃类是从地下深处油气藏垂直运移而来的证据。下文表提供的数据是从几个含油气地区进行地表烃类调查的结果。石油和天然气原则上是由约35个碳原子的饱和烃类组成,包括最轻的甲烷到非挥     

A spreadsheet program for two-well tracer test data analysis

Two-well tracer tests are often conducted to investigate subsurface solute transport in the field. Analyzing breakthrough curves in extraction and monitoring wells using numerical methods is nontrivial due to highly nonuniform flow conditions. We extended approximate analytical solutions for the advection-dispersion equation for an injection-extraction well doublet in a homogeneous confined aquifer under steady-state flow conditions for equal injection and extraction rates with no transverse dispersion and negligible ambient flow, and implemented the solutions in Microsoft Excel using Visual Basic for Application (VBA). Functions were implemented to calculate concentrations in extraction and monitoring wells at any location due to a step or pulse injection. Type curves for a step injection were compared with those calculated by numerically integrating the solution for a pulse injection. The results from the two approaches are similar when the dispersivity is small. As the dispersivity increases, the latter was found to be more accurate but requires more computing time. The code was verified by comparing the results with published-type curves and applied to analyze data from the literature. The method can be used as a first approximation for two-well tracer test design and data analysis, and to check accuracy of numerical solutions. The code and example files are publicly available.     

Biomarker induction in tropical fish species on the Northwest Shelf of Australia by produced formation water

Normal operation of oil well platforms results in the discharge of produced formation water (PFW). The expression of CYP1A, CYP2M1- and 2K1-like proteins was examined for use as possible biomarkers of PFW exposure. A pilot study on the Northwest Shelf of Australia had indicated that PFW contamination possibly contributes to induction of CYP1A-like proteins in Gold-Spotted Trevally (Carangoides fulvoguttatus). The pilot study samples were re-examined for CYP1A, and, in addition, CYP2K1/2M1-like proteins. In a subsequent caged fish study in the same location a second species, Stripey seaperch (Lutjanus carponotatus), caught at a clean site, were distributed to three caging sites in a PFW gradient from the Harriet A production platform: A (near-field), B (far-field) and C (a non-impacted reference site). Fish were sampled at time (T) T = 0, T = 3 and T = 10 days. Significant increases of CYP1A, one CYP2K1- and two CYP2M1-like proteins were noted at Site A at T = 10d. For another CYP2K1-like protein, a significant increase was observed at Site A only at T = 3d. These results support a previous study indicating that CYP1A protein is sensitive to PFW exposure. Importantly, statistically significant environmental induction of both CYP2M1- and CYP2K1-like proteins in tropical fish due to PFW exposure had not previously been described and induction of enzymes in the CYP2 family suggest new biomarkers for PFW. In addition, the novel response of one CYP2K-like protein requires further verification, but offers promise for improved monitoring of sub-lethal responses in marine organisms.     

The three screen doors: can marine "protected" areas be effective?

The great majority of marine protected areas (MPAs) fail to meet their management objectives. So MPAs can be effective conservation tools, we recommend two paradigm shifts, the first related to how they are located and the second related to how they are managed. MPAs are unlikely to be effective if they are located in areas that are subject to numerous, and often uncontrollable, external stressors from atmospheric, terrestrial, and oceanic sources, all of which can degrade the environment and compromise protection. MPA effectiveness is also limited by low institutional and community capacity for management and inappropriate size with respect to ecological needs. In particular, the check list approach to management does not ensure that key threats are dealt with, or that management expenditures provide a quantifiable return. We recommend a business planning approach to MPA management, in which managers focus on the viability of the management system, i.e., the ability of the MPA to provide ecological goods and services to its target users over the long term.     

Simulations to verify horizontal flow measurements from a borehole flowmeter

This paper reports on experiments and simulations of subsurface flow from a slotted acrylic tube deployed in a sand-tank flow chamber for two different purposes. In the first instance, the slotted tube is used to represent a single fracture intersected by an uncased well. In the second instance, the slotted tube is used to represent a multislot well screen within a porous medium. In both cases, the scanning colloidal borescope flowmeter (SCBFM) measures ground water velocity within the well by imaging colloids traveling through a well to measure their speed and direction. Measurements are compared against model simulations. For the case of a slotted tube representing a single fracture, SCBFM and model results agree with respect to the flow direction and to within a factor of 1.5 for the speed near the well's center. Model and experimental agreement lend confidence that for an uncased well drilled in a fractured-rock medium, a calibrated SCBFM could be used to identify and quantify flowing features. Next, the SCBFM was deployed in a four-column multislotted casing with slots aligned with the flow direction. Another numerical model was developed to estimate the flow field within this well screen to evaluate the potential usefulness of employing the SCBFM in a screened well to estimate flow speed and direction in the surrounding porous medium. Results indicate that if the slots are not aligned with the flow, the SCBFM may only provide order-of-magnitude speed measurements and direction measurements with an uncertainty of approximately +/-25 degrees .     

Polycyclic aromatic hydrocarbons in surface sediments of the East China Sea and their relationship with carbonaceous materials

This study measured concentrations of polycyclic aromatic hydrocarbons (PAHs) in surface sediments in the East China Sea (ECS) to investigate possible sources and fate of PAHs. Total concentration of PAHs in the sediments of the ECS ranged from 22 to 244 ng g(-1), with the highest levels in the coastal area and outer shelf. The observed PAH results showed elevated levels in both inner and outer shelf areas, a finding that is different from predictions by an ocean circulation model, suggesting that terrestrial sources are important for PAH contaminations in the ECS, while sediment resuspension, tidal changes and lateral transport may be important in affecting the distribution of PAHs in the outer shelf. The distribution of PAHs in the surface sediments of the ECS is similar to the distribution of carbonaceous materials (e.g., particulate organic carbon and black carbon), suggesting that carbonaceous materials may strongly affect the distribution of PAHs.     

Experimental Study of Cement - Sandstone/Shale - Brine - CO2 Interactions

Background

Reactive-transport simulation is a tool that is being used to estimate long-term trapping of CO₂, and wellbore and cap rock integrity for geologic CO₂ storage. We reacted end member components of a heterolithic sandstone and shale unit that forms the upper section of the In Salah Gas Project carbon storage reservoir in Krechba, Algeria with supercritical CO₂, brine, and with/without cement at reservoir conditions to develop experimentally constrained geochemical models for use in reactive transport simulations.

Results

We observe marked changes in solution composition when CO₂ reacted with cement, sandstone, and shale components at reservoir conditions. The geochemical model for the reaction of sandstone and shale with CO₂ and brine is a simple one in which albite, chlorite, illite and carbonate minerals partially dissolve and boehmite, smectite, and amorphous silica precipitate. The geochemical model for the wellbore environment is also fairly simple, in which alkaline cements and rock react with CO₂-rich brines to form an Fe containing calcite, amorphous silica, smectite and boehmite or amorphous Al(OH)₃.

Conclusions

Our research shows that relatively simple geochemical models can describe the dominant reactions that are likely to occur when CO₂ is stored in deep saline aquifers sealed with overlying shale cap rocks, as well as the dominant reactions for cement carbonation at the wellbore interface.     

油气地表地球化学勘查的单参数和多参数方法

自从30年代G·Iaubmeyer和V.A.Soko(?)ov第一次提出油气地表化学勘查以来,油气化探的发展几经盛衰,现在又进入了一个全面发展时期。近年来,国内外利用化探方法,找到了一大批油气藏,特别是地震方法难以发现的低缓圈闭和地层圈闭的油气藏,引起了整个石油勘查界的极大兴趣和关注。但是,由于油气地表地球化学信息较金属矿弱得很,而且受近地表的土壤性质和地表的气候变化及微生物活动等因素的干扰,地表地球化学晕的形状和强度变化多端,这就给地表地球化学资料的正确解释,推断和对比带来了严重困难。针对上述情况,谢学锦教授在1986年就提出“使用多参数的化探方法,将所获得的各种信息互相验证,互相增强,从而增加解释推断的可靠性”本文就是在这样的思想启迪下,探讨一下单参数和多参数地表地球化学方法,提高地表地球化学勘查对油气藏的识别力,以达到正确推断下伏油气藏存在的目的。     

Detections of 13C-substituted C3H2 in astronomical sources

We report observations of the 2(12)-1(01) rotational transition of the 13C isotopic species of cyclopropenylidene (C3H2) toward TMC-1, Sgr B2, and IRC +10216 using the laboratory rest frequencies which have recently become available. Our detections allow estimates to be made of the fractional abundance of the unsubstituted similar species in these sources. The fractional abundance relative to H2, f(C3H2), is 1-2 x 10(-8) in TMC-1, and this is similar to the abundance of HCN, one of the more abundant organic molecules in the interstellar medium. In IRC +10216 f(C3H2) is one order of magnitude greater than in TMC-1. The 12C species in Sgr B2 shows a self-absorbed profile and the relative abundance of C3H2 estimated to be about an order of magnitude less than in TMC-1.