WAVELENGTH SELECTION IN MULTICOMPONENT NEAR-INFRARED CALIBRATION

Modern scanning(near-)infrared reflectance/absorption(NIR)spectroscopes measure the absorptions orreflectances at a sequence of around 1000 wavelengths.Training data may consist of 10-100 carefullydesigned sample mixtures for which the true composition of the mixture is either known by formulationor accurately determined by wet chemistry.In future one wishes to predict the true composition fromthe spectrum.In this paper we compare a simple wavelength selection approach with methods whichretain all the wavelengths.It offers a powerful yet simple technique for choosing those wavelengths thatare specific to each pure component as against the other components(including the medium)for thevarying compositions.In the presence of a defined range of ingredients it thus chooses wavelengths whichare highly selective for each particular component.It has the added advantage of selecting wavelengthswhich are little effected by interaction effects and consequent non-linearities.The calibration data used consist of 125 observations of three sugars,each varying at five levels in afull 5~3 design.The validation set consists of 21 further samples specially selected to have compositionsoutside the range of the training sample.The selection methods perform much better on this predictionset than methods which retain all the wavelengths,700 in this case.The leave-one-out cross-validationinternal to the calibration data would point to the opposite finding and suggests that such cross-validations may be overly flattering to techniques such as partial least squares and may encourageoverfitting.After selection,simple straightforward least squares methods may be used,eschewing theneed for‘shrinkage’methods such as partial least squares or ridge regression.     

GREENHOUSE GASES FROM DEFORESTATION IN BRAZILIAN AMAZONIA: NET COMMITTED EMISSIONS

Deforestation in Brazilian Amazonia is a significant source of greenhouse gases today and, with almost 90% of the originally forested area still uncleared, is a very large potential source of future emissions. The 1990 rate of loss of forest (13.8 × 10³ km²/year) and cerrado savanna (approximately 5 × 10³ km²/year) was responsible for releasing approximately 261 × 10⁶ metric tons of carbon (10⁶ t C) in the form of CO2, or 274–285 × 10⁶ t of CO2-equivalent C considering IPCC 1994 global warming potentials for trace gases over a 100-year horizon. These calculations consider conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest, and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as net committed emissions, or the gases released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. For low and high trace gas scenarios, respectively, 1990 clearing produced net committed emissions (in 10⁶ t of gas) of 957–958 for CO2, 1.10–1.42 for CH₄, 28–35 for CO, 0.06–0.16 for N₂O, 0.74–0.74 for NO_x and 0.58–1.16 for non-methane hydrocarbons.     

Near shore waves,long-shore currents and sediment transport along micro-tidal beaches,central west coast of India

Coastlines are undergoing constant geomorphologic changes with respect to the incident wave climate.Based on waves measured at 9 m water depth,simulation of near shore wave transformation is done using REFDIF-1numerical model and the near shore breaker parameters are estimated at two micro-tidal beaches along central west coast of India.Model results are validated with measured values.From the breaker parameters,long-shore current and long-shore sediment transport rates（LSTR） are computed by using semi-empirical equations.Estimated long-shore current and LSTR are showing dramatic variations with respect to seasons.Predominant direction of LSTR is observed towards north since the approach waves are from south-west direction during pre-monsoon and post monsoon.During monsoon season,waves are from west south-west and resulted in southerly transport.The estimated annual net and gross LSTR by Cambridge Environmental Research Consultants（CERC） at two locations are in the same order whereas LSTR estimated by Walton ＆ Bruno and Kamphuis equations are showing different estimations because of difference in surf-zone width and foreshore slope between the two locations.For micro-tidal beaches with length less than 6 km,Kamphuis equation is giving agreeable estimation of LSTR.Sensitivity analysis of LSTR estimate shows that coastal inclination is the prominent factor in determining LSTR than incident wave angle.     

Modeling waves and longshore transport potential in Half Moon Bay, Grays Harbor, Washington, USA

A local-scale phase-resolving wave transformation model with CGWAVE is established in connection with a regional-scale coupled STWAVE-ADCIRC wave-current model for its application in the Half Moon Bay, Grays Harbor. Wave transformation from offshore to the harbor entrance is simulated by the STWAVE model which includes wave-current interaction. The STWAVE results provide incident wave conditions for the local-scale CGWAVE model at its outer boundary. A simple method is developed to take into ac- count the lateral variation of wave height in constructing the model's wave boundary conditions. The model was validated for three wave condition cases which yielded good agreement with field data. The validated model was applied to predicting nearshore waves in the Half Moon Bay and longshore transport parameters along the wave breaking line for the existing condition and three engi- neering alternatives. A comparative analysis indicated that storm waves that have a combination of long period and large height are the most destructive to the crenulate shoreline in the Half Moon Bay; both 152 m jetty extension (Alt. 2) and diffraction mound enlargement ( Alt. 3) would significantly reduce breaking wave height and longshore transport potential in the southwest comer of Half Moon Bay.     

New interpretations of Great Salt Lake ooids and of ancient non-skeletal carbonate mineralogy

Earlier interpretations of textural alteration affecting Great Salt Lake ooids have greatly influenced concepts of ooid diagenesis. Scanning electron microscope study shows, however, that the coarse radial aragonite rays are depositional, that no recrystallization of pellet cores has occurred, and that Great Salt Lake ooids have not suffered noticeable diagenesis. As suggested by Kahle (1974), radial texture in ancient calcitic ooids is probably mainly original, not diagenetic. Retention of such fine textures has been attributed to organic matter (since found to be equivalent in modern skeletal and non-skeletal grains) or to paramorphic replacement (proposed for non-skeletal grains whose original aragonite mineralogy was only inferred from modern analogs). Pleistocene ooids known to have been aragonite alter like aragonite shells to coarse neomorphic calcite, often with aragonite relics. The striking uniformity of that coarse texture in neomorphic calcite replacing known skeletal aragonites throughout the geologic record has been noted for over 100 years. In contrast, Mississippian ooids retain fine texture as do calcite layers of coexisting gastropods, but unlike the strongly altered aragonite layers of these same gastropods. Therefore, inferences of original aragonitic mineralogy of ancient non-skeletal carbonate grains (including muds) which are now calcite but retain fine texture appear unwarranted, as do assumptions of differential diagenetic behaviour of ancient aragonitic skeletal and non-skeletal grains. Accordingly, modern depositional environments of marine ooids and carbonate muds must be rejected as chemically unrepresentative of comparable ancient environments. It is inferred that ancient non-skeletal carbonates were originally predominantly or exclusively calcite because of an earlier lower oceanic Mg/Ca ratio (<2/1) which altered progressively to values favouring aragonite (modern Mg/Ca value = 5/1). Major influencing factors are: selective removal of calcium by planktonic foraminifers and coccolithophorids since Jurassic-Cretaceous time and by abundant younger, Mg-poor aragonite skeletons and an erratic trend toward decreasing dolomite formation (decreasing removal of oceanic Mg). The change to aragonite dominance over calcite for non-skeletal carbonates was probably during early to middle Cenozoic time.     

Pollen stratigraphy of the Late Pleistocene sediments at Mommark, Als, South Denmark

Past environmental changes in the Baltic area are discussed on the basis of pollen and spores recovered from marine sediments in a series of cliff sections at Mommark, in southern Denmark. The sediment succession represents Jessen & Milthers' (1928) Eemian pollen zones c-h, or Andersen's (1961 1975) zones E1/2-E7, as well as the earliest Weichselian pollen zone i, or EW-1, the Herning Stadial. A correlation with annually laminated German sequences (e.g. Bispingen) indicates that the sequence spans approximately 11 000 years. Marine deposition began c. 300 years after the beginning of the Eemian Interglacial Stage and continued to shortly before the end of pollen zone E7, at c. 10 600 years after the beginning of the Eemian. Sedimentation rates varied through the time period represented by the sequence, with initial deposition relatively rapid at c. 0.35 cm yr^-1 for the first c. 300 years. Rates then decreased to 0.029 cm yr^-1 for the next 2700 years and remained low, though varying, throughout the rest of the sequence. Overall, the rates indicate that sediment supply was highly restricted throughout the interglacial, possibly reflecting the dense forest vegetation that colonized the hinterland.