Barometric pumping effects on soil gas studies for geological and environmental characterization

Data from two free soil gas sampling programs are evaluated for the effects of barometric pumping over time on measured soil gas volumes. One program collected data from the trapped atmosphere immediately above two hazardous waste landfill areas. Of these areas, one had extremely high soil gas emanations, whereas the other had a more modest soil gas release. The second experimental program involved the collection of free soil gas samples on a rough grid with an approximate spacing of 1.6 km over a 720-sq-km area. This reconnaissance effort was designed to establish regional soil gas background values and to establish the utility of this method as a geological mapping tool in the Atlantic Coastal Plain. Methane, ethane, propane, and hydrogen data are used for this study. The data suggest that there is a predictable change in soil gas volume with a given change in barometric pressure. The rate of change is greater with large soil gas volumes in permeable soils versus lower soil gas volumes in impermeable soils; however, a simple linear relationship seems to generate a predictable curve with a margin of error of approximately 50%. Furthermore, the results of this study indicate that barometric pumping effects should be strongly considered during soil gas screening efforts at hazardous waste sites as well as in regional studies for hydrocarbon source potential mapping.     

Stokes problem for infinite vertical plate with constant heat flux

An exact solution for the Stokes problem for an infinite vertical plate has been derived on taking into account the constant heat flux at the plate. It has been observed that the velocity of the fluid increases with increasingt (time) orG (the Grashof number).     

Photoelectric study of the δ Scuti star HR 1225

The periodogram analysis of theV observations of the Scuti star HR 1225 has been carried out. Two frequencies of 6.415 cd (P ₀=0 _. ^d 1558) and 8.418 cd (P ₁=0 _. ^d 1188) have been determined. The period ratio ofP ₁/P ₀=0.762 indicates radial pulsation. The absolute magnitude, effective temperature and mass of the star are derived to be 1 _. ^m 05, 7600 K and 1.9M , respectively.     

CM-like interplanetary dust particles in lower stratosphere during 1989 October and 1991 June/July

Abstract— The stratospheric interplanetary dust particles L2005T12 and L2011O3 are linked to CM chondrite matrix. Particle L2005T12 is dominated by tabular grains of partially dehydrated greenalite-rich serpentine. Its amorphous matrix contains abundant smectite nanocrystals and annular Fe, Ni, S units. A uniquely stratified (partial) maghémite rim occurs only on S-rich parts of the matrix. Formation of this rim and Mg depletions in the matrix occurred during atmospheric entry heating of this particle. Particle L2011O3 has large iron sulfide and magnesiowüstite grains in an amorphous low-Al, ferromagnesiosilica matrix. Hydrous crystallisation of this matrix produced ultrafine-grained smectites and disseminated iron sulfides. Atmospheric entry heating of both particles is indicated by the partial iron oxide rim, vesicular sulfides, and the scatter of matrix compositions due to loss of Mg. While many uncertainties remain, the high incidence of chondritic rough particles, which include an unknown amount of CM-like particles, in the lower stratosphere during 1984, 1989, and 1991 suggests annual variations in their abundances. The timing of lower stratospheric dust samplings is critical to collect these particles.     

Discrete element modelling of fragmentable geomaterials with size dependent strength

This paper presents the application of a discrete element technique to the analysis of the dynamic indentation of either a purely brittle or a brittle viscoplastic geomaterial which can experience fragmentation resulting in fragments with size dependent strength characteristics.     

Changes in the internal spatial structure of post-communist Prague*

The article overviews the most important changes in the internal urban structure of Prague since 1989. Post-communist urban development has been influenced by government-directed reforms of political and economic system, internationalisation and globalisation, public policies favouring unregulated market development, economic restructuring in terms of deindustrialisation and growth of producer services, and increasing social differentiation. The three most transparent processes of urban change in Prague have been (1) commercialisation of the historical core; (2) revitalisation of some inner city neighbourhoods; and (3) residential and commercial suburbanisation in the outer city. This revised version was published online in July 2006 with corrections to the Cover Date.     

Investigation of carbon monoxide in heavy traffic intersections of municipal districts

In this research, an investigation of carbon monoxide in heavy traffic intersections of Kerman municipal districts in 2003–2004 has been performed. Kerman City is located at the south-eastern part of Iran. Carbon monoxide in highly toxic for human health and natural ecosystems in metropolition districts especially due to high traffic and industrial activities. For this reason, it was decided to investigate and find out the high concentration of CO pollutants in heavy traffic intersections of Kerman City. In this regards 21 heavy traffic squares and intersections were selected and the concentration of CO were measured. In the middle of each month during the year, sampling and measurement were scheduled three times at daily times according 7–12 a.m.; 12–16 and 16–20 p.m. In each period, 12 samples of 5 minutes were collected and CO concentration for 1-hr was calculated. The results obtained indicate that the hourly mean concentrations were lower than WHO guidelines and also lower than measurements of 1989, which has already done. In spite of more cases and higher populations, natural gas distribution was the cause of decline in CO concentrations.     

Prime controls on Archaean–Palaeoproterozoic sedimentation: Change over time

Although the principle of uniformitarianism may be applied to the Precambrian sedimentary record as a whole, certain periods of the Archaean and Palaeoproterozoic witnessed a changing pattern of prime influences controlling the depositional systems. This paper examines the major controls on sedimentation systems and environments during the Archaean and Palaeoproterozoic within the broader perspective of Earth evolution. Earth's earliest sedimentary system (4.4?-3.7 Ga) was presumably comprised of deep oceanic realms and probably influenced primarily by bolide impacts, major tsunamis, localized traction and global contour current patterns, and bathymetry. As continental crust began to form, the impact-dominated, tsunami type sedimentation gave way to wider varieties of sedimentary environments, known from the oldest sedimentary records. During early continental crustal evolution (c. 3.7–2.7 Ga), sedimentation was essentially of greenstone-type. Volcanic and volcaniclastic rocks were the major components of the greenstone belts, associated with thin carbonates, stromatolitic evaporites, BIF, pelites and quartzites and lesser synorogenic turbidites, conglomerates and sandstones. Volcanism and active tectonism (reflecting dynamic depositional settings during island arc and proto-continental nucleus formation) were the predominant factors influencing sedimentation during this phase of Earth evolution. Transgressions and regressions under the combined influence of tectonics and eustasy are reflected in fining- and coarsening-upwards successions from the proto-cratonic settings; low freeboard enabled the transgression to affect large areas of the proto-cratons. As the earliest, relatively stable craton formed, through a combination of plate tectonic and mantle-thermal processes, continents and supercontinents with the potential for supercontinental cycles started to influence sedimentation strongly. Major controls on Neoarchaean–Palaeoproterozoic sedimentation systems (2.7–1.6 Ga) were provided by a combination of superplume events and plate tectonics. Two global-scale ‘superevents’ at c. 2.7 Ga and c. 2.2–1.8 Ga were accompanied by eustatic rise concomitant with peaks in crustal growth rates, and large epeiric seas developed. The operation of first-order controls leading to development of vast chemical sedimentary platforms in these epeiric seas and concomitant palaeo-atmospheric and palaeo-oceanic evolution combined to provide a second-order control on global sedimentary systems in the Neoarchaean–Palaeoproterozoic period. The supercontinental cycle had become well established by the end of the Palaeoproterozoic, with the existence of large cratons across broad spectrums of palaeolatitude enabling erg development. The entire spectrum of sedimentary systems and environments came into existence by c. 1.8 Ga, prime influences on sedimentation and depositional system possibly remaining essentially uniform thereafter.     

Glacial conglomerates of the Appalachian Plateau,New York

Three generations of Quaternary conglomerates formed by cementation of glacial gravels are found in drift of the Appalachian Plateau in south-central New York. Postglacial conglomerates have been locally cemented by carbonate minerals within limestone-bearing (erratic-rich) gravels of Late Wisconsin (Woodfordian) age. Conglomerates cemented during the Mid-Wisconsin interstade occur as numerous fragments in erratic-rich Late Wisconsin drift, and as a single in situ mound near Syracuse. Mid-Wisconsin conglomerate contains fragments of a still older conglomerate believed to be of possible pre-Wisconsin (Sangamon) age. Both postglacial and Mid-Wisconsin conglomerates were cemented in the same manner, as a result of diagenetic processes in the vadose zones of limestone-bearing terraces. Information gleaned from conglomerate fragments indicates that Early Wisconsin drift was similar to Late Wisconsin drift; the Early and Late Wisconsin glaciations and deglaciations of the plateau probably proceeded in much the same fashion.