Paleoclimate changes in the late precambrian: Evidence from the upper precambrian section of the South Urals

The climatic impact on the formation of fine-grained rocks from the Riphean stratotype and Vendian Asha Group on the western slope of the South Urals during the time interval lasting approximately 1200 Ma is considered. It is shown that these rocks are largely represented by “tectonosilicate-dominated” shales. This feature combined with changes in the average K₂O/Al₂O₃ values disavows the hypothesis in (Kennedy et al., 2006), according to which the growth of free oxygen concentration in the Late Riphean and Vendian atmosphere was determined by gradual intensification of the organic carbon extraction from the biosphere by clays. The average values of the hydrolyzate module, chemical index of alteration (CIA), and several lithogeochemical parameters calculated for the Riphean and Vendian clayey rocks provide grounds for the conclusion that intensity of weathering in paleodrainage areas during the accumulation of the Upper Precambrian sedimentary successions was low. The curve reflecting changes of the average CIA values in the Upper Precambrian fine-grained siliciclastic rocks of the South Urals is similar to some extent with the “standard” CIA_correct. curve (GonzalezAlvarez and Kerrich, 2012). It is assumed that changes in microand macrobiotic communities during the Late Precambrian were controlled to a variable extent by climate fluctuations as well. At the same time, these fluctuations most likely left the chemical composition of water in the ocean virtually unchanged, which is evident from analysis of the redox conditions in the ocean and the distribution of primary producers with the average CIA_correct. and CIA values.     

Results of chemical dating of monazite from the Talnakh economic intrusion (Russia)

Economic copper, nickel, and platinum-group element (PGE) deposits are associated with the Talnakh ultramafic–mafic intrusion of the Noril’sk Province in the northwestern part of the Siberian Platform. The results of the chemical Th–U–Pb dating of monazite from the ore-bearing melanotroctolites of the Talnakh intrusion are presented. The isotope-geochemical features of monazite are compared with zircon, sulfides, and baddeleyite.     

Laser microprobe for the study of noble gases and nitrogen in single grains: A case study of individual chondrules from the Dhajala meteorite

A laser microprobe capable of analysing nitrogen and noble gases in individual grains with masses less than a milligram is described. It can be used in both continuous wave (CW) mode, useful for stepwise heating of an individual grain, as well as in pulsed mode, useful for ablating material from a small selected area of a sample, for gas extraction. We could achieve low blanks (in ccSTP units) for 4He(4.8 x 10{-12}),²²Ne(1.0 x 10{-12}),³⁶Ar(1.0 x10 ^-13),⁸⁴Kr(2.9 x 10{-14}),¹³² Xe(2.6 x 10{-14}), and N (87 pg), using this system. Preliminary data for individual chondrules from the Dhajala meteorite show that noble gases and nitrogen from grains as small as 170 microgram can be analysed using the present laser microprobe setup. The amount of trapped neon in Dhajala chondrules is very small, and nitrogen in the chondrules is isotopically heavier as compared to the bulk meteorite.     

Metal and metalloid leaching from tailings into streamwater and sediments in the old Ag–Pb–Zn Terramonte mine,northern Portugal

Tailings deposited over the Castanheira, a stream which flows through the old Ag–Pb–Zn Terramonte mine area, showed a great potential environmental risk due to sulphide weathering, facilitated by the tailings–water interaction. The high concentrations of Al, Fe, Pb and Zn in the tailings are associated with the exchangeable, reducible and sulphide fractions and suggest sphalerite and pyrite occurrences. Oxidation of pyrite is responsible for the low pH values (3.38–4.89) of the tailings. The water from the Castanheira stream is not suitable for human consumption due to high concentrations of SO₄ ^2?, Mn, Al, Cd, Ni, and Pb. The lowest concentrations of metals and metalloids were detected in downstream stretches of the Castanheira. However, As, Fe and Zn in deeper sediments tend to increase downstream. Significant concentrations of trivalent forms of arsenic were detected in water samples. In downstream stretches of the Castanheira, some free ions (Fe²⁺, Mn²⁺ and Zn²⁺) also predominate and the water is saturated with ferrihydrite, goethite, hematite, lepidocrosite and magnetite.     

Dimorphism in Placenticeras mintoi from the Upper Cretaceous Bagh Beds, central India

The Upper Cretaceous Bagh Beds yield many biota of which ammonoids are particularly well known. Previously Bagh ammonoids were grouped into many genera and species within several families. The present study, however, shows that failure to recognize dimorphism and a wide range of interspecific variation within the single genus Placenticeras perhaps results in taxonomic oversplitting. Specific dimorphism in P. mintoi has been established.     

ON A NEW GENUS OF SYRINGOPOROID CORAL FROM THE CARBONIFEROUS OF CHIHLI AND FENGTIEN PROVINCES.

In the course of my study on the Chihsia Corals from Central China, Mr. Y. T. Chao my collegue of the Geological Survey was so kind as to hand over to me two specimens of tube corals which he personally found in a limes-     

Sequence hierarchy in a Mesoproterozoic interior sag basin: from basin fill to reservoir scale,the Tombador Formation,Chapada Diamantina Basin,Brazil

The Tombador Formation exhibits depositional sequence boundaries placed at the base of extensive amalgamated fluvial sand sheets or at the base of alluvial fan conglomeratic successions that indicate basinward shifts of facies. The hierarchy system that applies to the Tombador Formation includes sequences of different orders, which are defined as follows: sequences associated with a particular tectonic setting are designated as ‘first order’ and are separated by first‐order sequence boundaries where changes in the tectonic setting are recorded; second‐order sequences represent the major subdivisions of a first‐order sequence and reflect cycles of change in stratal stacking pattern observed at 10² m scales (i.e., 200–300 m); changes in stratal stacking pattern at 10¹ m scales indicate third‐order sequences (i.e., 40–70 m); and changes in stratal stacking pattern at 10⁰ m scales are assigned to the fourth order (i.e., 8–12 m). Changes in palaeogeography due to relative sea level changes are recorded at all hierarchical levels, with a magnitude that increases with the hierarchical rank. Thus, the Tombador Formation corresponds to one‐first‐order sequence, representing a distinct intracratonic sag basin fill in the polycyclic history of the Espinhaço Supergroup in Chapada Diamantina Basin. An angular unconformity separates fluvial‐estuarine to alluvial fan deposits and marks the second‐order boundary. Below the angular unconformity the third‐order sequences record fluvial to estuarine deposition. In contrast, above the angular unconformity these sequences exhibit continental alluvial successions composed conglomerates overlain by fluvial and eolian strata. Fourth‐order sequences are recognized within third‐order transgressive systems tract, and they exhibit distinct facies associations depending on their occurrence at estuarine or fluvial domains. At the estuarine domain, they are composed of tidal channel, tidal bar and overlying shoreface heterolithic strata. At the fluvial domain the sequences are formed of fluvial deposits bounded by fine‐grained or tidal influenced intervals. Fine grained intervals are the most reliable to map in fourth‐order sequences because of their broad laterally extensive sheet‐like external geometry. Therefore, they constitute fourth‐order sequence boundaries that, at the reservoir approach, constitute the most important horizontal heterogeneity and, hence, the preferable boundaries of production zones. The criteria applied to assign sequence hierarchies in the Tombador Formation are based on rock attributes, are easy to apply, and can be used as a baseline for the study of sequence stratigraphy in Precambrian and Phanerozoic basins placed in similar tectonic settings.     

Organic carbon and nitrogen stable isotopes in the intertidal sediments from the Yangtze Estuary, China

The natural isotopic compositions and C/N elemental ratios of sedimentary organic matter were determined in the intertidal flat of the Yangtze Estuary. The results showed that the ratios of carbon and nitrogen stable isotopes were respectively −29.8‰ to − 26.0‰ and 1.6‰–5.5‰ in the flood season (July), while they were −27.3‰ to − 25.6‰ and 1.7‰–7.8‰ in the dry season (February), respectively. The δ¹³C signatures were remarkably higher in July than in February, and gradually increased from the freshwater areas to the brackish areas. In contrast, there were relatively complex seasonal and spatial changes in stable nitrogen isotopes. It was also reflected that δ¹⁵N and C/N compositions had been obviously modified by organic matter diagenesis and biological processing, and could not be used to trace the sources of organic matter at the study area. In addition, it was considered that the mixing inputs of terrigenous and marine materials generally dominated sedimentary organic matter in the intertidal flat. The contribution of terrigenous inputs to sedimentary organic matter was roughly estimated according to the mixing balance model of stable carbon isotopes.     

Radiation–hydrodynamical collapse of pre-galactic clouds in the ultraviolet background

To explain the effects of the ultraviolet (UV) background radiation on the collapse of pre-galactic clouds, we implement a radiation–hydrodynamical calculation, combining one-dimensional spherical hydrodynamics with an accurate treatment of the radiative transfer of ionizing photons. Both absorption and scattering of UV photons are explicitly taken into account. It turns out that a gas cloud contracting within the dark matter potential does not settle into hydrostatic equilibrium, but undergoes run-away collapse even under the presence of the external UV field. The cloud centre is shown to become self-shielded against ionizing photons by radiative transfer effects before shrinking to the rotation barrier. Based on our simulation results, we further discuss the possibility of H₂ cooling and subsequent star formation in a run-away collapsing core. The present results are closely relevant to the survival of subgalactic Population III objects as well as to metal injection into intergalactic space.