Wet deposition of excess sulfate at Macquarie Island, 54° S

Annual wet deposition of excess sulfate at Macquarie Island has been estimated from 5 months of rainwater composition data covering the Austral summer of 1985/86. The resulting figure of 2.1±0.6 mmol/m²/yr is at the low end of previous estimates of maritime excess sulfate deposition by precipitation. Within estimated uncertainty limits this figure is consistent with the DMS emission flux which would be predicted for latitude 50°–60° S, based solely on available Northern Hemispheric DMS measurements.Temporarily at the International Meteorological Institute, Stockholm University, S-106 91, Stockholm, Sweden.     

Cesstibtantite—a geologic introduction to the inverse pyrochlores

Summary The crystal structure of cesstibtantite has been solved from diffractometer data collected on samples from Leshaia, Russia and the Tanco pegmatite, Manitoba. Cesstibtantite from the Leshaia pegmatite (type locality) hasa 10.515(2) Å, space groupFd3m, composition Cs_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_O.91(Ta_1.88Nb_0.12)₂(O_5.69[OH, F]_0.31)₆(OH, F)_0.69, Z 8; its structure was refined toR 3.8,wR 4.3% using 96 observed (F > 3[F]) reflections (MoK). Cesstibtantite from the Tanco pegmatite hasa 10.496(1) Å, space groupFd3m, composition (Cs_0.22K_0.01)_0.23(Na_0.45Sb_0.39Pb_0.14· Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78[OH,F]_0.22)₆(OH,F)_0.55,Z 8; its structure was refined toR 3.9w R 3.7% using 104 observed reflections. Cesstibtantite differs from the normal pyrochlores in that it contains significant amounts of very large cations such as Cs. As these cations are too large (^VIII[r] > 1.60 Å) for the conventional [8]-coordinated A site, they occupy the [18]-coordinated site, which normally contains monovalent anions. Natural cesstibtantite samples are non-ideal in that both Cs and monovalent anions occur at the site; thus cesstibtantite is intermediate to thenormal pyrochlores (with only monovalent anions at the site) and theinverse pyrochlores (with only large cations at the site).

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Cesstibtantit—eine geologische Einfiihrung in die inversen Pyrochlore

Zusammenfassung Die Kristallstruktur von Cesstibtantit wurde auf der Basis von Diffraktometerdaten von Proben von Leshaia, Russland and dem Tanco Pegmatit, Manitoba, gelöst. Cesstibtantit aus dem Leshaia Pegmatit (Typlokalität) hat a 10.515(2) Å, RaumgruppeFd3m, die Zusammensetzung CS_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_0.91(Ta_1.88Nb_0.12)₂· (O_5.69OH, F_0.31)₆(OH, F)_0.69 Z 8; die Struktur wurde aufR 3.8,wR 4.3% verfeinert unter Benützung von 96 beobachteten Reflexen. Cesstibtantit vom Tanco Pegmatit hat a 10.496(1) Å, RaumgruppeFd3m, die Zusammensetzung (Cs_0.22K_0.01)_0.23(Na_0.45· Sb_0.39Pb_0.14Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78OH,F_0.22)₆(OH,F)_0.55,Z 8; seine Struktur wurde aufR 3.9wR 3.7% auf der Basis von 104 beobachteten Rettexen verfeinert. Cesstibtantit unterscheidet sich von normalen Pyrochloren insofern, als er signifikante Mengen von sehr großen Kationen, wie z.B. Cs enthält. Da these Kationen zu groß sind (^VIII r 1.60 Å) für eine konventionelle [8]-koordinierteA Stelle, nehmen she die [18]-koordinierten Positionen ein, welche normalerweise monovalente Anionen enthalten. Natürliche Cesstibtantitproben sind nicht ideal insofern als sowohl Cs als auch monovalente Anionen in der Position vorkommen. Somit ist Cesstibtantit intermediär zu den normalen Pyrochloren (mit nur monovalenten Anionen auf der Position) and den inversen Pyrochloren (mit ausschließlichen großen Kationen an der Position).

     

The upper Bathonian ammonite zonation of East Siberia

Modifications to the upper Bathonian zonal scale for northern East Siberia provided by the newly available paleontological record on Middle Jurassic reference sections in the Arctic regions of Yakutia and by the revised earlier collections, are justified. The oldest East Siberian members of Cadoceras are found to be characteristic not of the initial Callovian age as believed by Russian paleontologists, but of the terminal Bathonian age as was previously shown in the biostratigraphic scheme of East Greenland. The succession of zones and index species analogous to that of the latter is revealed in the studied region and the zonal boundaries in Siberia and East Greenland are inferred to be synchronous. Finds of Cadoceras calyx in the upper Bathonian scale permitted, for the first time, the recognition of a corresponding zone. The Bathonian-Callovian boundary is placed between the calyx and anabarense zones. The upper Bathonian zonal scale of northern East Siberia is now in total agreement with the East Greenland zonal scale.     

Cascade processes in the surface layers of pulsars

The influence of the Landau-Pomeranchuk effect on the development of a shower generated by ultrarelativistic particles bombarding the surface of a pulsar is discussed. Because of this effect, the path length of the shower increases while low-energy photon generation is strongly suppressed. In view of this, the mechanism of pair production suggested by Cheng, Ruderman, and Jones for the pulsar magnetosphere, may be essential only for pulsars whose magnetic field intensity at the surface lies in a relatively narrow range of aroundB 10¹² G.     

多维体视方法论及其在地球科学研究中的意义

本文阐述”多维体视方法论”,主张立体透视与动态、多维地看问题;它起源于医学CT(计算机层析学)透视成像、核磁共振(MRI)等体视学方法研究疾病的生理解剖结构、病理特征、监测人体有关器官的各种变化,是行之有效的方法;已成功地应用于检测工业器械、航天器及地下结构等物体的内部结构,从而发展和演绎出来的认识论方法。在医学领域将CT、MRI所得二维信息和断面图像、对病灶区引入“体显示”和“面显示”等可视化技术,将能充分反映不同疾病的病理、药理特征;在航天、地学等领域同样应用着CT多维“可视化技术”。本文试图发扬综合预测的学术思想,将医学临床应用CT、核磁共振、体视学方法结合研究其他制约因素指标,从而区分出疾病的原发、继发分期,导致绝症的进程和前兆,概括为“多维体视预测方法”;也适用于地震孕育、强震发生与火山喷发预测的研究。     

An ephemeral turbidity maximum generated by resuspension of organic-rich matter in a macrotidal estuary, S.W. Wales

An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I⁻¹ by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I⁻¹, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R³ where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m⁻³) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.     

Holocene climate variability as derived from alkenone sea surface temperature and coupled ocean-atmosphere model experiments

Holocene climate modes are identified by the statistical analysis of reconstructed sea surface temperatures (SSTs) from the tropical and North Atlantic regions. The leading mode of Holocene SST variability in the tropical region indicates a rapid warming from the early to mid Holocene followed by a relatively weak warming during the late Holocene. The dominant mode of the North Atlantic region SST captures the transition from relatively warm (cold) conditions in the eastern North Atlantic and the western Mediterranean Sea (the northern Red Sea) to relatively cold (warm) conditions in these regions from the early to late Holocene. This pattern of Holocene SST variability resembles the signature of the Arctic Oscillation/North Atlantic Oscillation (AO/NAO). The second mode of both tropical and North Atlantic regions captures a warming towards the mid Holocene and a subsequent cooling. The dominant modes of Holocene SST variability emphasize enhanced variability around 2300 and 1000 years. The leading mode of the coupled tropical-North Atlantic Holocene SST variability shows that an increase of tropical SST is accompanied by a decrease of SST in the eastern North Atlantic. An analogy with the instrumental period as well as the analysis of a long-term integration of a coupled ocean-atmosphere general circulation model suggest that the AO/NAO is one dominant mode of climate variability at millennial time scales.