Geochronology of anthropogenic pollutants in riparian wetland sediments of the Lippe River (Germany)

Anthropogenic pollutants were determined in a dated sediment core, collected from a riparian wetland of the Lippe River (Ruhr district, Germany). The historical trend in heavy metals, polycyclic aromatic hydrocarbons, organochlorines, polychlorinated biphenyls and linear alkylbenzenes as well as more recent contaminants such as industrial additives, organotins, synthetic musks, methyltriclosan and some other compounds were determined for the time period between 1930 and 1986. Emission sources, information on technical production and usage, as well as on the individual pollution pathways, with appropriate environmental stability, were considered in the interpretation of the sediment contamination over the past 50 years.Contaminants were analysed and interpreted according to two different criteria: (a) the origin of the main contaminants as related to mining and industrial activities as well as municipal sewage and agricultural effluents and (b) the pollution history. Due to a significant appearance of formerly missing contaminants in sediments deposited since 1970, we suggest classifying contaminants as either common (predating 1970) or modern (postdating 1970).In summary, the study provided a comprehensive reconstruction of the pollution history of the Lippe River system.     

Modeling preferential flow in reactive barriers: implications for performance and design

Reactive barriers are passive and in situ ground water treatment systems. Heterogeneities in hydraulic conductivity (K) within the aquifer-reactive barrier system will result in higher flux rates, and reduced residence times, through portions of the barrier. These spatial variations in residence time will affect the treatment capacity of the barrier. A numerical flow model was used to evaluate the effects of spatial variations in K on preferential flow through barriers. The simulations indicate that the impact of heterogeneities in K will be a function of their location and distribution; the more localized the high K zone, the greater the preferential flow. The geometry of the reactive barrier will also strongly influence flow distribution. Aquifer heterogeneities will produce greater preferential flow in thinner barriers compared to thicker barriers. If the barrier K is heterogeneous, greater preferential flow will occur in thicker barriers. The K of the barrier will affect the flow distribution; decreasing the K of the barrier can result in more even distribution of flow. Results indicate that less variable flow will be attained utilizing thicker, homogeneous barriers. The addition of homogeneous zones to thinner barriers will be effective at redistributing flow only if installed immediately adjacent to both the up- and downgradient faces of the barrier.     

Interaction between a circular opening and fractures originating from its boundary in a piecewise homogeneous plane

The complex variables boundary element method (CVBEM) is used to study interaction between a circular opening and fractures originating from its boundary in a piecewise homogeneous plane. A new complex hypersingular equation for piecewise homogeneous media with a circular opening is obtained. The equation is solved using the CVBEM technique with circular and straight boundary elements and polynomial approximations (with square root asymptotics for crack tip elements) for the unknown functions. The algorithm is verified through comparison with known semi‐analytical and numerical solutions that involve interaction between a circular opening and specific systems of cracks or other openings. New numerical results concerning the interaction of the circular opening with the cracks and circular inclusions are presented. The method is applied to an important problem in the petroleum industry: modelling propagation of hydraulic fractures in the vicinity of a borehole. Copyright © 2000 John Wiley & Sons, Ltd.     

Some evidence of climate change in twentieth-century India

The study of climate changes in India and search for robust evidences are issues of concern specially when it is known that poor people are very vulnerable to climate changes. Due to the vast size of India and its complex geography, climate in this part of the globe has large spatial and temporal variations. Important weather events affecting India are floods and droughts, monsoon depressions and cyclones, heat waves, cold waves, prolonged fog and snowfall. Results of this comprehensive study based on observed data and model reanalyzed fields indicate that in the last century, the atmospheric surface temperature in India has enhanced by about 1 and 1.1°C during winter and post-monsoon months respectively. Also decrease in the minimum temperature during summer monsoon and its increase during post-monsoon months have created a large difference of about 0.8°C in the seasonal temperature anomalies which may bring about seasonal asymmetry and hence changes in atmospheric circulation. Opposite phases of increase and decrease in the minimum temperatures in the southern and northern regions of India respectively have been noticed in the interannual variability. In north India, the minimum temperature shows sharp decrease of its magnitude between 1955 and 1972 and then sharp increase till date. But in south India, the minimum temperature has a steady increase. The sea surface temperatures (SST) of Arabian Sea and Bay of Bengal also show increasing trend. Observations indicate occurrence of more extreme temperature events in the east coast of India in the recent past. During summer monsoon months, there is a decreasing (increasing) trend in the frequency of depressions (low pressure areas). In the last century the frequency of occurrence of cyclonic storms shows increasing trend in the month of November. In addition there is increase in the number of severe cyclonic storms crossing Indian Coast. Analysis of rainfall amount during different seasons indicate decreasing tendency in the summer monsoon rainfall over Indian landmass and increasing trend in the rainfall during pre-monsoon and post-monsoon months.     

Assessment of the statistical significance of global changes in the annual river runoff in XXI century due to possible anthropogenic warming of climate

A number of uncertainties of forecasts of changes in the annual runoff depths at global scale, obtained using information on results of integration of 21 IPCC climate models is studied. Following possible errors of these forecasts are calculated: errors of models; differences between main (IPCC) scenarios of emission of greenhouse gases in the atmosphere and resultant changes of global temperatures; mistakes in estimates of average long-term observed values of the runoff depths for the “control” period. Global maps of a “significance index” of forecasted changes in the runoff depths (estimations of changes in the annual runoff depths divided by mean square root values of errors of these estimations) for 2025, 2050, 2075 and 2100 are presented. It is shown that the most significant global changes of the runoff depths (growth in the north of Eastern Siberia, of the Russian Far East, of North America, falling in the “Greater Mediterranean Region”) are predicted for the second quarter of 21st century. Further changes of the runoff amplify only in the Amazon basin (reduction, by 2075). Almost everywhere else (including almost all European territory of Russia, Western Siberia, south of Eastern Siberia and of the Far East) the significance of changes in the runoff depths during 21st century is negligible.     

Resolving mechanisms of toxicity while pursuing ecotoxicological relevance?

In this age of modern biology, aquatic toxicological research has pursued mechanisms of action of toxicants. This has provided potential tools for ecotoxicologic investigations. However, problems of biocomplexity and issues at higher levels of biological organization remain a challenge. In the 1980s and 1990s and continuing to a lesser extent today, organisms residing in highly contaminated field sites or exposed in the laboratory to calibrated concentrations of individual compounds were carefully analyzed for their responses to priority pollutants. Correlation of biochemical and structural analyses in cultured cells and tissues, as well as the in vivo exposures led to the production and application of biomarkers of exposure and effect and to our awareness of genotoxicity and its chronic manifestations, such as neoplasms, in wild fishes. To gain acceptance of these findings in the greater environmental toxicology community, “validation of the model” versus other, better-established often rodent models, was necessary and became a major focus. Resultant biomarkers were applied to heavily contaminated and reference field sites as part of effects assessment and with investigations following large-scale disasters such as oil spills or industrial accidents.

Over the past 15 years, in the laboratory, small aquarium fish models such as medaka (Oryzias latipes), zebrafish (Danio rerio), platyfish (Xiphophorus species), fathead minnow (Pimephales promelas), and sheepshead minnow (Cyprinodon variegatus) were increasingly used establishing mechanisms of toxicants. Today, the same organisms provide reliable information at higher levels of biological organization relevant to ecotoxicology. We review studies resolving mechanisms of toxicity and discuss ways to address biocomplexity, mixtures of contaminants, and the need to relate individual level responses to populations and communities.     

On determining the noon polar cap boundary from SuperDARN HF radar backscatter characteristics

Previous work has shown that ionospheric HF radar backscatter in the noon sector can be used to locate the footprint of the magnetospheric cusp particle precipitation. This has enabled the radar data to be used as a proxy for the location of the polar cap boundary, and hence measure the flow of plasma across it to derive the reconnection electric field in the ionosphere. This work used only single radar data sets with a field of view limited to 2 h of local time. In this case study using four of the SuperDARN radars, we examine the boundary determined over 6 h of magnetic local time around the noon sector and its relationship to the convection pattern. The variation with longitude of the latitude of the radar scatter with cusp characteristics shows a bay-like feature. It is shown that this feature is shaped by the variation with longitude of the poleward flow component of the ionospheric plasma and may be understood in terms of cusp ion time-of-flight effects. Using this interpretation, we derive the time-of-flight of the cusp ions and find that it is consistent with approximately 1 keV ions injected from a subsolar reconnection site. A method for deriving a more accurate estimate of the location of the open-closed field line boundary from HF radar data is described.     

A comparative study of geothermal and meteorological records of climate change in Kamchatka

To reconstruct the recent climate history in Kamchatka, a series of repeated precise temperature logs were performed in a number of boreholes located in a broad east-west strip (between 52 and 54°N) in the central part of Kamchatka west of Petropavlovsk-Kamchatski. Within three years more than 30 temperature logs were performed in 10 holes (one up to six logs per hole) to the depth of up to 400 metres. Measured temperature gradients varied in a broad interval 0 to 60 mK/m and in some holes a sizeable variation in the subsurface temperatures due to advective heat transport by underground water was observed. Measured data were compared with older temperature profiles obtained in the early eighties by Sugrobov and Yanovsky (1993). Even when older data are of poorer precision (accuracy of about 0.1 K), they presented valuable information of the subsurface temperature conditions existing 20–25 years ago. Borehole observations and the inverted ground surface temperature histories (GSTHs) used for the paleoclimate reconstruction were complemented with a detailed survey of meteorological data. Namely, the long-term surface air temperature (SAT) and precipitation records from Petropavlovsk station (in operation since 1890) were used together with similar data from a number of local subsidiary meteo-stations operating in Central Kamchatka since 1950. Regardless of extreme complexity of the local meteorological/climate conditions, diversity of borehole sites and calibration of measuring devices used during the whole campaign, the results of the climate reconstruction supported a general warming of about 1 K characteristic for the 20th century, which followed an inexpressive cooler period typical for the most of the 19th century. In the last three to four decades the warming rate has been locally increasing up to 0.02 K/year. It was also shown that the snow cover played a dominant role in the penetration of the climate “signal” to depth and could considerably smooth down the subsurface response to the changes occurred on the surface.     

Slump debris flows in the Akovolwo Mountains area of Benue State,Nigeria

In September 1979, rain-induced complex landslides occurred in two separate localities along the slopes of the Akovolwo Mountains near Jato-Aka in the Kwande Local Government area of Benue State, Nigeria.The two movements developed on bedrock slopes covered by a veneer of colluvium and (or) residuum no more than 1.5 to 2m deep. Each started as a slump and graduated into a debris flow. The slump, extending downhill a short distance away from the head scarp, had been reconstituted into a debris flow as the initial movement (sliding movement) of the soil mass caused remoulding of the saturated moving mass into viscous debris-laden mud. The resulting mass moved partly along a pre-existing mountain stream channel and partly along a fresh channel it cleared in the savanna forest. At the break of slope, the mass of boulders was dumped and a trail of smaller fragments littered the channels towards the Katsina-Ala River.