Kankan diamonds (Guinea) III: δ13C and nitrogen characteristics of deep diamonds

Diamonds from the Kankan area in Guinea formed over a large depth profile beginning within the cratonic mantle lithosphere and extending through the asthenosphere and transition zone into the lower mantle. The carbon isotopic composition, the concentration of nitrogen impurities and the nitrogen aggregation level of diamonds representing this entire depth range have been determined. Peridotitic and eclogitic diamonds of lithospheric origin from Kankan have carbon isotopic compositions ('¹³C: peridotitic -5.4 to -2.2‰; eclogitic -19.7 to -0.7‰) and nitrogen characteristics (N: peridotitic 17-648 atomic ppm; eclogitic 0-1,313 atomic ppm; aggregation from IaA to IaB) which are generally typical for diamonds of these two suites worldwide. Geothermobarometry of peridotitic and eclogitic inclusion parageneses (worldwide sources) indicates that both suites formed under very similar conditions within the cratonic lithosphere, which is not consistent with a derivation of diamonds with light carbon isotopic composition from subducted organic matter within subducting oceanic slabs. Diamonds containing majorite garnet inclusions fall to the isotopically heavy side ('¹³C: -3.1‰ to +0.9‰) of the worldwide diamond population. Nitrogen contents are low (0-126 atomic ppm) and one of the two nitrogen-bearing diamonds shows such a low level of nitrogen aggregation (30% B-centre) that it cannot have been exposed to ambient temperatures of the transition zone (̿,400 °C) for more than 0.2 Ma. This suggests rapid upward transport and formation of some Kankan diamonds pene-contemporaneous to Cretaceous kimberlite activity. Similar to these diamonds from the asthenosphere and the transition zone, lower mantle diamonds show a small shift towards isotopic heavy compositions (-6.6 to -0.5‰, mode at -3.5‰). As already observed for other mines, the nitrogen contents of lower mantle diamonds were below detection (using FTIRS). The mutual shift of sublithospheric diamonds towards isotopic heavier compositions suggests a common carbon source, which may have inherited an isotopic heavy composition from a component consisting of subducted carbonates.     

Reflectance spectroscopy and remote sensing data for finding sulfide-bearing alteration zones and mapping geology in Gilgit-Baltistan,Pakistan

Gilgit-Baltistan region is covering the northern most part of Pakistan where the rocks of the Kohistan-Ladakh island arc and Karakoram plate are exposed. The area has greater potential for precious and base metals deposits which are needed to be explored through spectroscopy and remote sensing techniques. Minerals and rocks can nowadays be identified through the measurement of their absorption and reflectance features by spectroscopic analysis. Spectral reflectance analysis is also very important in selecting the appropriate spectral bands for remote-sensing data analysis of unknown or inaccessible areas. In this study, reflectance spectra in the spectral range of 0.35–2.5 μm of different types of unaltered and altered rocks found in the Machulu and Astor areas of northern Pakistan were obtained using an ASD spectroradiometer. The fresh rock samples showed low spectral reflectance as compared to the altered rock samples. The minerals jarosite, goethite, and hematite showed depth of absorption minima in the range of 0.4–1.15 μm due to the presence of iron (Fe), while jarosite and limonite showed absorption depth at 2.2 μm due to the presence of hydroxyl ions (OH^¯). The clay minerals montmorillonite and illite showed absorption depth at 1.93 and 2.1 μm, respectively. Muscovite showed depth of absorption minima at 1.4 and 1.9 μm in some samples. Calcite showed deep absorption minima at 2.32 μm, while anorthite showed absorption features at 1.4, 1.9, 2.24, and 2.33 μm. Olivine showed a slight depressed absorption feature at 1.07 μm. The copper-bearing phases malachite, chrysocolla, and azurite showed, respectively, a broad absorption feature in the range of 0.6–0.9 μm, a small absorption at 1.4 μm, and a deep absorption at 1.93 μm. The unmineralized samples exhibited high reflectance in the wavelength ranges of 0.6–0.8, 1.6–1.9, 2.0–2.3, 2.1–2.25, and 2.4–2.5 μm, respectively, while the mineralized samples showed reflectance bands in the wavelength ranges of 0.4–0.6, 1.3–1.8, and 2.1–2.2 μm. On this basis, the band ratio combinations 7/5–4/3–6/3 and 7/5–6/3–4/3 of Landsat 8 and 4/7–4/3–2/1 for ASTER data were found to be very effective in the lithological differentiation of major rock units.     

Plasma wave properties of the Schwarzschild magnetosphere in a Veselago medium

We re-formulate the 3+1 GRMHD equations for the Schwarzschild black hole in a Veselago medium. Linear perturbation in rotating (non-magnetized and magnetized) plasma is introduced and their Fourier analysis is considered. We discuss wave properties with the help of wave vector, refractive index and change in refractive index in the form of graphs. It is concluded that some waves move away from the event horizon in this unusual medium. We conclude that for the rotating non-magnetized plasma, our results confirm the presence of Veselago medium while the rotating magnetized plasma does not provide any evidence for this medium.     

Dust in the disk winds from young stars as a source of the circumstellar extinction

We consider the problem of dust grain survival in the disk winds from T Tauri and Herbig Ae stars. For our analysis, we have chosen a disk wind model in which the gas component of the wind is heated through ambipolar diffusion to a temperature of ～10⁴ K. We show that the heating of dust grains through their collisions with gas atoms is inefficient compared to their heating by stellar radiation and, hence, the grains survive even in the hot wind component. As a result, the disk wind can be opaque to the ultraviolet and optical stellar radiation and is capable of absorbing an appreciable fraction of it. Calculations show that the fraction of the wind-absorbed radiation for T Tauri stars can be from 20 to 40% of the total stellar luminosity at an accretion rate ? _a = 10^?8-10^?6 M _⊙yr^?1. This means that the disk winds from T Tauri stars can play the same role as the puffed-up inner rim in current accretion disk models. In Herbig Ae stars, the inner layers of the disk wind (r ≤ 0.5 AU) are dust-free, since the dust in this region sublimates under the effect of stellar radiation. Therefore, the fraction of the radiation absorbed by the disk wind in this case is considerably smaller and can be comparable to the effect from the puffed-up inner rim only at an accretion rate of the order of or higher than 10^?6 M _⊙yr^?1. Since the disk wind is structurally inhomogeneous, its optical depth toward the observer can be variable, which should be reflected in the photometric activity of young stars. For the same reason, moving shadows from gas and dust streams with a spiral-like shape can be observed in high-angular-resolution circumstellar disk images.     

Applying landscape-ecological concept and GIS modelling for assessing and mapping of ecological situation of mountainous landscapes (on the case of Syunik marz,Armenia)

Regional landscape-ecological studies have acquired a special topicality as they assure efficient environmental conservation and sustainable use of natural resources. A landscape-ecological analysis was performed based on four basic integral indices: (1) ecological potential, (2) ecological stability, (3) ecological load and (4) ecological tension. The values of basic integral indices of the landscape-ecological analysis were calculated as sums of respective factors expressed in scores and multiplied by their significance reflecting coefficients. In agreement with that rule, a formula was derived of calculation of basic indices of landscape-ecological analysis. Subsequently, those factors were integrated by ‘Model Builder’ in ArcGIS applying ‘Weighted Sum’ functions. Finally, through geographic information systems modelling, maps of basic indices of landscape-ecological analysis were produced. In conclusion – ecological potential, stability, load and tension are best indicators for the assessment of the landscape-ecological situation of the studied territory.     

Long-term variability of air temperature and precipitation conditions in the Polish Carpathians

Mountain regions are sensitive to climate changes, which make them good indicators of climate change. The aim of this study is to investigate the spatial and temporal variability of air temperature and precipitation in the Polish Carpathians. This study consists of climatological analyses for the historical period 1851-2010 and future projections for 2021-2100. The results confirm that there has been significant warming of the area and that this warming has been particularly pronounced over the last few decades and will continue in the oncoming years. Climate change is most evident in the foothills; however, these are the highest summits which have experienced the most intensive increases in temperature during the recent period. Precipitation does not demonstrate any substantial trend and has high year-to-year variability. The distribution of the annual temperature contour lines modelled for selected periods provides evidence of the upward shift of vertical climate zones in the Polish Carpathians, which reach approximately 350 meters, on average, what indicates further ecological consequences as ecosystems expand or become extinct and when there are changes in the hydrological cycle.     

Identification of hydrochemical facies in the Roswell Artesian Basin,New Mexico (USA), using graphical and statistical methods

Analysis of groundwater chemistry can yield important insights about subsurface conditions, and provide an alternative and complementary method for characterizing basin hydrogeology, especially in areas where hydraulic data are limited. More specifically, hydrochemical facies have been used for decades to help understand basin flow and transport, and a set of facies were developed for the Roswell Artesian Basin (RAB) in a semi-arid part of New Mexico, USA. The RAB is an important agricultural water source, and is an excellent example of a rechargeable artesian system. However, substantial uncertainties about the RAB hydrogeology and groundwater chemistry exist. The RAB was a great opportunity to explore hydrochemcial facies definition. A set of facies, derived from fingerprint diagrams (graphical approach), existed as a basis for testing and for comparison to principal components, factor analysis, and cluster analyses (statistical approaches). Geochemical data from over 300 RAB wells in the central basin were examined. The statistical testing of fingerprint-diagram-based facies was useful in terms of quantitatively evaluating differences between facies, and for understanding potential controls on basin groundwater chemistry. This study suggests the presence of three hydrochemical facies in the shallower part of the RAB (mostly unconfined conditions) and three in the deeper artesian system of the RAB. These facies reflect significant spatial differences in chemistry in the basin that are associated with specific stratigraphic intervals as well as structural features. Substantial chemical variability across faults and within fault blocks was also observed.     

Geochronological constraints on the Legs Lake shear zone with implications for regional exhumation of lower continental crust, western Churchill Province, Canadian Shield

The Legs Lake shear zone marks the southeastern boundary of an extensive region (>20,000 km²) of high-pressure (0.8–1.5+ GPa) granulite-facies rocks in the western Churchill Province, Canada. The shear zone is one of the largest exhumation-related structures in the Canadian Shield and coincides with the central segment of the ∼2,800 km long Snowbird tectonic zone. The movement history of this shear zone is critical for the development of models for the exhumation history of the high-pressure region. We used electron microprobe U–Th–Pb dating of monazite with supplemental ID-TIMS U–Pb geochronology to place constraints on the timing of shear zone activity. Combining these and other data, we suggest that regional exhumation occurred during at least three distinct phases over an ∼150 million year period. The first phase involved high temperature decompression from ∼1.0 to 0.8–0.7 GPa shortly following 1.9 Ga peak metamorphism, possibly under an extensional regime. The second phase involved rock uplift and decompression of the hanging wall to 0.5–0.4 GPa during east-vergent thrusting across the Legs Lake shear zone at ca. 1.85 Ga. This phase was likely driven by early collision-related convergence in the Trans-Hudson orogen. The final phase of regional exhumation, involving the removal of 15–20 km of overburden from both footwall and hanging wall, likely occurred after ∼1.78 Ga and may have been related to regional extensional faulting.Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at .     

Convective activity over heat-low region and Indian summer monsoon rainfall during contrasting phases of ESI tendency

In this paper, the changes in convective activity over heat-low region over northwest India during contrasting phases of effective strength index (ESI) tendency have been examined. During contrasting phases of ESI tendency, evolution of surface pressure and temperature field over India from winter to spring is exactly opposite, and hence, the heat-low over northwest India depicts temporal and spatial variations in magnitude and location. During positive ESI tendency, the evolution of surface cooling and high surface pressure from winter to spring suggests reduced convective activity over heat-low region, while during the negative phase of ESI tendency, anomalously warm surface temperatures and low surface pressure evolve from winter to spring suggesting enhanced convective activity over the heat low region. The temporal variability in the relationship between surface temperature/pressure over heat-low region and Indian summer monsoon rainfall (ISMR) is also examined in this paper. During positive ESI tendency, heat-low temperature anomaly in February is significantly associated with ISMR, whereas during negative ESI tendency, both temperature/pressure over heat-low region in May are significantly associated with ISMR. These parameters may help in long range forecasting of ISMR.