Impact of different surface sources of pollution on the quality of ground water in Madurai,India

Seepage of pollutants from surface and subsurface sources of pollution are known to occur. Here the effect of the type, number and the proximity of the visible surface sources of pollution on the extent and degree of pollution in the neighbouring water sources is investigated. In Madurai the pollution loadings are more or less continuous and hence there is no possibility of reducing pollution levels.     

Stability and sensitivity analysis of Himalayan road cut debris slopes: an investigation along NH-58, India

The complex geological environment due to active tectonics and varied lithology with multiple phases of deformation and metamorphism led to a rugged topography and large destabilization of slopes in the Himalayan region. However, the ever-rising activities due to various ongoing developmental and urbanization processes in the region are contributing to instability of slopes. The significant number of causalities and massive economic loss is deliberately endangering Himalayan ecosystem due to landslide-related phenomena. Transportation corridors within Himalayan terrain experience frequent landslides, particularly the sections manifested by debris slopes. From several decades, the national highway-58, in Uttarakhand, Himalayas, has been endangered due to diverse and incessant slope failures. The present investigation demonstrates the stability appraisal along the strategic transportation corridor. These studies incorporate the various issues and causes pertaining to debris slides from Rishikesh to Devprayag, Uttarakhand. The numerical simulation assessment was undertaken by deterministic and sensitivity analyses by conventional limit equilibrium methods which is being augmented by much advanced and robust finite element tool. Factor of safety for each slope was determined, and correspondingly, best efficient slope stabilization remedies were proposed to enhance the stability of slopes. It is recommended that such strategic slope stability assessment should be performed within different vulnerable sections of the Himalayas and likewise regions for fruitful and sustainable step toward disaster mitigation.     

Flow characteristics of Metresa: an Oligocene seismoturbidite in the Dukla Unit, Polish Carpathians

Metresa is a thick, distinctive turburdite within the Menilite Shales in the Carpathians of south-east Poland. It was deposited by a SE-flowing turbidity current derived from the Silesian cordillera and can be traced for 55 km downcurrent; it has a width of at least 15 km. The current contained roughly 3 km³ of sediment and conforms to the definition of a seismoturbidite. Grain-size analyses of samples from the nine localities where Metresa is exposed indicate average velocities decreasing from 2 m s^?1 to less than 1 m s^?1 over the 55 km. Massive divisions are poorly developed; instead, the turbidite, although graded, tends to be laminated throughout. Flat lamination predominates with intercalated cross-lamination and erosion structures at various levels. Small-scale cross-lamination, presumably associated with ripples, occurs at some upper levels. An exceptional feature is a large-scale wave-like structure somewhat resembling hummocky cross-stratification. The structures are not consistent with the inferred velocities. It is suggested that the stability fields relating structures to stream power (herein called the ‘Allen fields’) are displaced in respect to deposition from waning turbidity currents.     

Multi-scale permeability estimation for a tropical catchment

Physically based and spatially distributed modelling of catchment hydrology involves the estimation of block or whole-hillslope permeabilities. Invariably these estimates are derived by calibration against rainfall–runoff response. Rarely are these estimates rigorously compared with parameter measurements made at the small scale. This study uses a parametrically simple model, TOPMODEL, and an uncertainty framework to derive permeability at the catchment scale. The utility of expert knowledge of the internal catchment dynamics (i.e. extent of saturated area) in constraining parameter uncertainty is demonstrated. Model-derived estimates are then compared with core-based measurements of permeability appropriately up-scaled. The observed differences between the permeability estimates derived by the two methods might be attributed to the role of intermediate scale features (natural soil pipes). An alternative method of determining block permeabilities at the intermediate or hillslope scale is described. This method uses pulse-wave tests and explicitly incorporates the resultant effects of phenomena such as soil piping and kinematic wave migration. The study aims to highlight issues associated with parameterizing or validating distributed models, rather than to provide a definitive solution. The fact that the permeability distribution within the Borneo study catchment is comparatively simple, assists the comparisons. The field data were collected in terrain covered by equatorial rainforest. Combined field measurement and modelling programmes are rare within such environments. © 1998 John Wiley & Sons, Ltd.     

Karst Hazard Assessment of Eastern Saudi Arabia

Karst phenomena exist in areas in the eastern part of Saudi Arabia, forming solution features such as sinkholes, collapsed dolines and solution caverns, as a result of the chemical leaching of the carbonate and evaporite formations by percolating water. The instability of these karst phenomena could produce land subsidence problems. This paper reviews the geology of documented karstic rock units in Saudi Arabia and proposes a simple engineering classification of the solution features characteristic of limestone. Two case histories in the Dhahran area, eastern Saudi Arabia, will be used as examples for the application of a modified engineering classification.     

Development of a reactive zone technology for simultaneous in situ immobilisation of radium and uranium

Simultaneous in situ immobilisation of uranium (U) and radium (²²⁶Ra) by injectible amounts of grey cast iron (gcFe), nano-scale iron (naFe) and a gcFe/MnO₂ mixture (1:1) was studied in batch and column tests. Both 0.5 g/L naFe and gcFe are effective in ²²⁶Ra and U removal from mine water, whereas MnO₂ addition clearly increased the efficiency of gcFe for ²²⁶Ra and U immobilisation. In a column test with 0.6 wt% gcFe/MnO₂ mixture (1:1), neither ²²⁶Ra nor U was detected in the effluent after replacement of 45 pore volumes. A sequential extraction under flow condition revealed ²²⁶Ra to be mostly occluded in manganese oxides. Uranium was mostly sorbed onto poorly crystalline iron hydroxides, but a significant part was found to be occluded in manganese oxides also. The results of this study suggest that MnO₂ promotes iron hydroxide formation under slightly reducing environmental conditions resulting in an increased pollutant retention capacity.     

The impact of over 100 years of wildfires on mercury levels and accumulation rates in two lakes in southern California,USA

In southern California, USA, wildfires may be an important source of mercury (Hg) to local watersheds. Hg levels and Hg accumulation rates were investigated in dated sediment cores from two southern California lakes, Big Bear Lake and Crystal Lake, located approximately 40-km apart. Between 1895 and 2006, fires were routinely minimized or suppressed around Big Bear Lake, while fires regularly subsumed the forest surrounding Crystal Lake. Mean Hg concentrations and mean Hg accumulation rates were significantly higher in Crystal Lake sediments compared to Big Bear Lake sediments (Hg levels: Crystal Lake 220 ± 93 ng g⁻¹, Big Bear Lake 92 ± 26 ng g⁻¹; Hg accumulation: Crystal Lake 790 ± 1,200 μg m⁻² year⁻¹, Big Bear 240 ± 54 μg m⁻² year⁻¹). In Crystal Lake, the ratio between post-1965 and pre-1865 Hg concentrations was 1.1, and several spikes in Hg levels occurred between 1910 and 1985. Given the remote location of the lake, the proximity of fires, and the lack of point sources within the region, these results suggested wildfires (rather than industrial sources) were a continuous source of Hg to Crystal Lake over the last 150 years.     

Structural properties of (Mn1-x Fe x )Nb2O6 columbites from X-ray diffraction and IR spectroscopy

A suite of (Mn_1-x Fe _x )Nb₂O₆ (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented. The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe²⁺ for the larger Mn²⁺ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by Fe.     

Carbon, sulfur and O2 across the Permian–Triassic boundary

A model for the carbon and sulfur cycles across the Permian–Triassic boundary has been constructed from carbon and sulfur isotopic data. Results indicate a drop in global organic matter burial, the formation of an anoxic deep ocean, and a large drop in atmospheric oxygen over the time span 270 to 240 Ma. Much of these changes were probably due to a drop in terrestrial productivity and preservation and an increase in global aridity.     

New U–Pb isotopic data for detrital zircons from metasedimentary sequences of northwestern Taimyr

This work presents the U–Pb (LA–ICP–MS) data of detrital zircons from metasedimentary sequences of northwestern Taimyr. An analysis of the youngest populations of detrital zircons testifies to the wide distribution of Cambrian sequences in the study area, but not Precambrian sequences as was considered earlier, and the need for a substantial revision of the stratigraphic scheme of this area. The detrital zircon age distribution shows that the Timan margin of the Baltic paleocontinent was a major provenance area of the Cambrian sediments in northern and northwestern Taimyr, as well as the coeval sediments of the Severnaya Zemlya archipelago.