A measurement of the 362 GHz absorption line of Mars atmospheric H2O2

The 362.156 GHz absorption spectrum of H₂O₂ in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H₂O₂ abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (L_s) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HO_x abundances above ∼10 km altitudes between the L_s=112° period of the Encrenaz et al. upper limit measurement and the current L_s=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H₂O₂ line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H₂O₂. Observation of Mars H₂O₂ also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own.     

Is the transition impact to post‐impact rock complete? Some remarks based on XRF scanning,electron microprobe,and thin section analyses of the Yaxcopoil‐1 core in the Chicxulub crater

Abstract The transition from impact to post‐impact rocks in the Yaxcopoil‐1 (Yax‐1) core is marked by a 2 cm‐thick clay layer characterized by dissolution features. The clay overlies a 9 cm‐thick hardground, overlying a 66 cm‐thick crossbedded unit, consisting of dolomite sandstone alternating with thin micro‐conglomerate layers with litho‐ and bioclasts and the altered remains of impact glass, now smectite. The micro‐conglomerates mark erosion surfaces. Microprobe and backscatter SEM analysis of the dolomite rhombs show an early diagenetic, complex‐zoned, idiomorphic overgrowth, with Mn‐rich zones, possibly formed by hot fluids related to cooling melt sheet in the crater. The pore spaces are filled with several generations of coelestite, barite, K‐feldpar, and sparry calcite. XRF core scanning analysis detected high Mn values in the crossbedded sediments but no anomalous enrichment of the siderophile elements Cr, Co, Fe, and Ni in the clay layer. Shocked quartz occurs in the crossbedded unit but is absent in the clay layer. The basal Paleocene marls are strongly dissolved and do not contain a basal Paleocene fauna. The presence of a hardground, the lack of siderophile elements, shocked quartz, or Ni‐rich spinels in the clay layer, and the absence of basal Paleocene biozones P0 and Pa all suggest that the top of the ejecta sequence and a significant part of the lower Paleocene is missing. Due to the high energy sedimentation infill, a hiatus at the top of the impactite is not unexpected, but there is nothing in the biostratigraphy, geochemistry, and petrology of the Yax‐1 core that can be used to argue against the synchroneity of the end‐Cretaceous mass‐extinctions and the Chicxulub crater.     

Modes to replace transitional asymptotic ray fields in a vertically inhomogeneous earth model

Summary. Asymptotic ray theory (ART) fails in transition regions near critically reflected, bottom glancing or caustic-forming rays in a vertically inhomogeneous layered earth. These deficiencies are repaired here by replacing the transitional ray fields with guided modes plus truncation remainders. Exact ray-mode equivalences and their high-frequency asymptotic approximations are formulated, and their validity and efficiency are verified by numerical comparisons for SH motion in a two-layer earth model comprised of an inhomogeneous sediment above an homogeneous semi-infinite bedrock.     

Self-similar solutions for the blast wave problem in radiative gasdynamics,I

Similarity solutions, describing the flow of a perfect gas behind spherical shock waves, are investigated including the radiation heat flux. The shock is assumed to be propagating in a medium at rest. Shock radius varies exponentially with time and density is inversely proportional to fifth power of the shock radius immediately ahead of the shock front.     

Thermal stability of a layer with permeable boundaries and variable gravitational field

The aim of this paper is to investigate the thermal stability of a fluid layer with permeable boundaries and a variable gravitational field. It is observed that the principle of exchange of stabilities is valid when the layer is heated form below and the complex growth rate of an arbitrary oscillatory mode exists outside of a circle whose radius depends upon the permeability parameter, Prandtl number and wavelength of the mode. In the case of a layer heated from below, gravity increasing upward has a destabilizing effect whereas the permeability parameter has a stabilizing effect.