Atypical stratiform sulfide-poor platinum-group element mineralisation in the Agnew – Wiluna Belt komatiites,Wiluna, Western Australia

A new style of komatiite-associated sulfide-poor platinum-group element (PGE: Os, Ir, Ru, Rh, Pt, Pd) mineralisation has been identified at Wiluna in the strongly nickel sulfide (NiS) mineralised Agnew – Wiluna Greenstone Belt, Western Australia. The komatiite sequence at Wiluna is ～200 m thick and comprises a basal pyroxenite layer, a thick ortho-to-mesocumulate-textured peridotite core, which is overlain by rhythmically layered wehrlite, oikocrystic pyroxenite and thick upper gabbroic margins. Pegmatoid and dendritic (harrisitic) domains are common features, whereas spinifex-textured horizons and flow-top breccias are absent. The presence of anomalous PGE-enriched horizons (ΣPt – Pd = 200 – 500 ppb) in the oikocrystic pyroxenite and in the layered melagabbro and gabbronorite horizons directly overlying the wehrlite unit is due to the presence of fine-grained (1 – 10 μm) platinum-group minerals (PGMs). More than 70 PGM grains were identified, and a considerable mineralogical variability was constrained. However, only Pd – Pt-bearing phases were identified, whereas no Ir – Ru-bearing PGMs were found in any of the sections examined. Interestingly, all PGMs are not in paragenetic association with sulfides, and only sulfide-poor/free intervals contain significant PGM concentrations. The whole-rock PGE sequence largely reflects the PGM distribution. It is hypothesised that the Pd – Pt enrichment in the oikocrystic pyroxenite and melagabbros and the overall Ir – Ru depletion in the upper mafic section of the sequence are the result of extensive olivine and chromite crystallisation in the basal ultramafic section. PGE saturation was driven by extensive crystallisation of silicate and oxide phases in a sulfide-undersaturated environment. The crystallisation of clinopyroxene in the oikocrystic pyroxenite horizon may have triggered the formation of Pt – Pd-bearing alloys and arsenides, which were the first PGMs to form. Stratiform sulfide-poor PGE mineralisation at Wiluna is more similar in stratigraphic setting, style and composition to PGE-rich sulfide-poor mineralisation zones in thick differentiated intrusions, rather than to other PGE-enriched zones in komatiite-hosted systems, where PGE enrichment is directly associated with accumulations of magmatic sulfides.     

The Kabanga Ni sulfide deposit, Tanzania: I. Geology, petrography, silicate rock geochemistry, and sulfur and oxygen isotopes

The Kabanga Ni sulfide deposit represents one of the most significant Ni sulfide discoveries of the last two decades, with current indicated mineral resources of 23.23 Mt at 2.64% Ni and inferred mineral resources of 28.5 Mt at 2.7% Ni (Nov. 2008). The sulfides are hosted by a suite of ∼1.4 Ga ultramafic–mafic, sill-like, and chonolithic intrusions that form part of the approximately 500 km long Kabanga–Musongati–Kapalagulu igneous belt in Tanzania and Burundi. The igneous bodies are up to about 1 km thick and 4 km long. They crystallized from several compositionally distinct magma pulses emplaced into sulfide-bearing pelitic schists. The first magma was a siliceous high-magnesium basalt (approximately 13.3% MgO) that formed a network of fine-grained acicular-textured gabbronoritic and orthopyroxenitic sills (Mg# opx 78–88, An plag 45–88). The magma was highly enriched in incompatible trace elements (LILE, LREE) and had pronounced negative Nb and Ta anomalies and heavy O isotopic signatures (δ¹⁸O +6 to +8). These compositional features are consistent with about 20% contamination of primitive picrite with the sulfidic pelitic schists. Subsequent magma pulses were more magnesian (approximately 14–15% MgO) and less contaminated (e.g., δ¹⁸O +5.1 to +6.6). They injected into the earlier sills, resulting in the formation of medium-grained harzburgites, olivine orthopyroxenites and orthopyroxenites (Fo 83–89, Mg# _opx 86–89), and magmatic breccias consisting of gabbronorite–orthopyroxenite fragments within an olivine-rich matrix. All intrusions in the Kabanga area contain abundant sulfides (pyrrhotite, pentlandite, and minor chalcopyrite and pyrite). In the lower portions and the immediate footwall of two of the intrusions, namely Kabanga North and Kabanga Main, there occur numerous layers, lenses, and veins of massive Ni sulfides reaching a thickness of several meters. The largest amount of high grade, massive sulfide occurs in the smallest intrusion (Kabanga North). The sulfides have heavy S isotopic signatures (δ³⁴S wr = +10 to +24) that broadly overlap with those of the country rock sulfides, consistent with significant assimilation of external sulfur from the Karagwe–Ankolean sedimentary sequence. However, based partly on the relatively homogenous distribution of disseminated sulfides in many of the intrusive rocks, we propose that the Kabanga magmas reached sulfide saturation prior to final emplacement, in staging chambers or feeder conduits, followed by entrainment of the sulfides during continued magma ascent. Oxygen isotope data indicate that the mode of sulfide assimilation changed with time. The heavy δ¹⁸O ratios of the early magmas are consistent with ingestion of the sedimentary country rocks in bulk. The relatively light δ¹⁸O ratios of the later magmas indicate less bulk assimilation of the country rocks, but in addition the magmas selectively assimilated additional S, possibly through devolatization of the country rocks or through cannibalization of magmatic sulfides deposited in the conduits by preceding magma surges. The intrusions were tilted at ca. 1.37 Ga, during the Kibaran orogeny and associated synkinematic granite plutonism. This caused solid-state mobilization of ductile sulfides into shear zones, notably along the base of the intrusions where sulfide-hornfels breccias and lenses and layers of massive sulfides may reach a thickness of >10 m and can extend for several 10 s to >100 m away from the intrusions. These horizons represent an important exploration target for additional nickel sulfide deposits.     

The contribution of agricultural and urban activities to inorganic carbon fluxes within temperate watersheds

The lateral transport of bicarbonate as dissolved inorganic carbon (DIC) to the oceans is an integral component of the global carbon budget and can represent the sequestration of CO₂ from the atmosphere. Recently studies have implicated land use change, in particular agricultural development, as an accelerator of bicarbonate export. However, due to the co-variation of land use, bedrock and surficial geologies, and the relationship between bicarbonate export and climate, the impact of anthropogenic activities on DIC export remains an important research question. In order to examine the land use controls on DIC export from small temperate watersheds we sampled 19 streams draining catchments of varying land uses with similar bedrock and surficial geologies. In addition to an agricultural effect, there was a strong correlation between the percent of watershed in urban development and DIC concentrations and DIC yields. Urban watersheds exported 7.8 times more DIC than their nearby forested counterparts and 2.0 times more DIC than nearby agricultural catchments. Isotopic data suggest that excess DIC export from altered systems results from increased chemical weathering, enhanced CO₂ production within urban green spaces, and as a result of organic matter loading from septic systems and leaky sewer lines. Furthermore, we found that nitrogen additions (e.g. fertilizers and manure) are aiding in the dissolution of lime, increasing the total export of DIC from agricultural watersheds. Calculated anthropogenic loading rates ranged from 0.43 to 0.86 mol C m^− 2 yr^− 1. These loading rates suggest that a significant portion of global DIC export might be attributable to human activities, although the impacts on CO₂ sequestration are difficult to determine.     

“This Is Like Déjà Vu All over Again”

Understanding the Changing Planet is the latest in a long line of reports that makes the case for the relevance of the discipline of geography by invoking big “S” science. My commentary argues that this model of science, with its celebration of large data sets, sophisticated methodological techniques, and various material tools and hardware, is only one model of geography's contribution. Instead, I suggest that the strength of geography is in its pluralism and methodological variety, and in the end that will do more for understanding the changing planet than anything else.     

The Gravity Module Assembly used in airborne full tensor gradiometry surveys

In airborne gravity gradiometry, the Gravity Module Assembly is an optional gravimeter unit that is mounted on the same stabilized platform as the Full Tensor Gradiometer. Direct measurements of the gravity field are needed from this device to constrain the long wavelengths when gradient data are integrated mathematically to form high-resolution gravity fields. The Gravity Module Assembly is, however, capable of providing independent gravity data with a specification approaching that expected from a dedicated airborne gravity system. Presented here is an error analysis of data from this instrument collected alongside the Full Tensor Gradiometer during an airborne survey. By having both gradiometry and gravity datasets, comparisons of the information content in these two types of measurement are made.     

Assessing storm surge impacts on coastal inundation due to climate change: case studies of Baltimore and Dorchester County in Maryland

Natural Hazards - Hurricane Isabel (2003) generated record flooding around Chesapeake Bay and caused extensive damage in rural Eastern Shore of Maryland and metropolitan cities like Baltimore....     

Adding bounds to kriging

The ordinary kriging interpolation algorithm is extended by the inclusion of explicit lower and upper bounds on the estimate. The associated estimation variance is written as the ordinary kriging variance plus a non-negative correction term.     

American pragmatism: Towards a geographical introduction

The purposes of the paper are to provide a historical and thematic review of some of the variants of American philosophical pragmatism (old and new), and to point to its potential relevance for geography. The paper is divided into three sections. The first, discusses the origins of American pragmatism focussing on four figures: John Dewey, Oliver Wendell Holmes, William James, and Charles Sanders Peirce. Following the argument of Louis Menand (2001) in The Metaphysical Club, I will suggest that pragmatism took on its peculiar American character as a response to the deep fissures and wounds caused by that country’s Civil War. That war produced a loss of faith, undermining notions of universal progress and absolute truth. Pragmatism was the reaction. The second section brings pragmatism to the present, by focussing on three connected contemporary American pragmatists: Richard Rorty, Richard Bernstein, and Richard Shusterman. The hallmark of their work, and which justifies treating them as a group, is a willingness to stretch pragmatism: first, by making linkages with other anti-foundational, practice-based philosophical traditions, especially those within Continental European philosophy, and which had been shut out of Anglo-American philosophy after the Second World War by the rise of analytic philosophy; and second, by applying pragmatist ideas to issues like the body and popular culture to which it had never been applied. Finally, in the conclusion the paper reflects on the prospects of tethering pragmatism to the work of human geographers. Given the anti-architectonic impulses of pragmatism, such a project cannot simply be one of holus-bolus transferring pragmatism to geography. A different approach is needed, and which is schematically outlined and briefly illustrated using the idea of place.     

The development of a non-linear autoregressive model with exogenous input (NARX) to model climate-water clarity relationships: reconstructing a historical water clarity index for the coastal waters of the southeastern USA

Theoretical and Applied Climatology - The coastal waters of the southeastern USA contain important protected habitats and natural resources that are vulnerable to climate variability and singular...