Biosorptive behaviour of mango leaf powder and rice husk for arsenic(III) from aqueous solutions

The present study deals with the biosorption of As(III) from aqueous solution using mango leaves powder (MLP) and rice husk (RH) in a batch operation. Scanning electron microscopy and Fourier transformation infrared spectrometry analysis shows the surface texture of biosorbents and metal binding of functional groups of before and after biosorption of As(III). The optimum pH was obtained at 7 and 6 with 7 and 6?g/l of dosage of MLP and RH, respectively. The adsorption of As(III) onto MLP and RH was favourably influenced by an increase in temperature. Equilibrium data were well represented by the Freundlich isotherm model. Nitric acid and ethylenediaminetetra acetic acid was found to be a better eluant for the desorption followed by hydrochloric acid and sodium hydroxide of As(III) with a maximum desorption efficiency of 69.5, 48.5 and 79.4, 86.3?%, respectively. The pseudo-second-order kinetic model was found to best fitted of the experimental data over the equilibrium time at 32?h. The positive values of heat of adsorption (23.89?kJ/mol for MLP and 52.26?kJ/mol for RH) indicate the endothermic nature of the adsorption process. The thermodynamic study showed the spontaneous nature of the sorption of As(III) onto MLP and RH.     

Energy Spectra of Cosmic-Ray Protons and Nuclei Measured in the NUCLEON Experiment Using a New Method

Astronomy Reports - Some results of studies of cosmic rays obtained during the NUCLEON space experiment in 2015–2017 are presented. This experiment was intended for direct measurements of the...     

Adularia,the characteristic mineral of felsic spilites

Sea floor rhyolites from the Iberian Pyrite Belt show strong enrichment in potassium and adularia is observed to replace plagioclase. This process is in accord with thermodynamic data for the exchange reaction with ocean water which favours adularia up to about 140° C. Archaean felsic intrusives and extrusives exhibit sodium enrichment, a contrast which we attribute to lower K levels in sea water and, or, higher ocean temperatures. All of these rocks show ¹⁸O enrichment of + 6 to + 8, in compliance with low temperature sea water exchange.     

Brittle Rock Failure in the Steg Lateral Adit of the Lötschberg Base Tunnel

Summary  During the crossing of brittle rock formations at the L?tschberg base tunnel, failure phenomena have been observed both at the tunnel face and at the walls. A detailed analysis has been undertaken to explain these behaviours, based on the recent developments of Canadian research on brittle failure mechanisms. At the tunnel walls, a very good agreement is found between the calculated and observed damage and between two prediction methods, i.e. a semi-empirical failure criterion and elastic calculations with the “brittle Hoek-Brown parameters.” Near the face, due to the 3D nature of the stress conditions, some limitations of these approaches have been highlighted, and the growth of wall failure has been analysed. This research allowed a better understanding of the brittle rock mass behaviour at the L?tschberg base tunnel and showed that brittle failure processes dominate the behaviour of deep, highly stressed excavations in massive to moderately jointed rock. It also illustrates where improvements to the adopted approaches are required.     

Mesozoic tectonic evolution of the Southeast China Block: New insights from basin analysis

In order to better understand the Mesozoic tectonic evolution of Southeast China Block (SECB in short), this paper describes geological features of Mesozoic basins that are widely distributed in the SECB. The analyzed data are derived from a regional geological investigation on various Mesozoic basins and a recently compiled 1:1,500,000 geological map of Mesozoic–Cenozoic basins. Two types of basin are distinguished according to their tectonic settings, namely, the post-orogenic basin (Type I) and the intracontinental extensional basin (Type II); the latter includes the graben and the half-graben or faulted-depression basins. Our studies suggest that the formation of these basins connects with the evolution of geotectonics of the SECB. The post-orogenic basin (Type I) was formed in areas from the piedmont to the intraland during the interval from Late Triassic to Early Jurassic; and the formation of the intracontinental extensional basin (Type II) connects with an intracontinental crustal thinning setting in the Late Mesozoic. The graben basin was generated during the Middle Jurassic and is associated with a bimodal volcanic eruption; and the half-graben or faulted-depression basin, filled mainly by the rhyolite, tuff and sedimentary rocks during Early Cretaceous, is occupied by the Late Cretaceous–Paleogene red-colored terrestrial clastic rocks. We noticed that the modern outcrops of numerous granites and basins occur in a similar level, and the Mesozoic granitic bodies contact with the adjacent basins by large normal faults, suggesting that the modern landforms between granites and basins were yielded by the late crustal movement. The modern basin and range framework was settled down in the Cretaceous. Abundant sedimentary structures are found in the various basins, from that the deposited environments and paleo-currents are concluded; during the Late Triassic–Early Jurassic time, the source areas were situated to the north and northeast sides of the outcrop region. In this paper, we present the study results on one geological and geographical separating unit and two separating fault zones. The Wuyi orogenic belt is a Late Mesozoic paleo-geographically separating unit, the Ganjiang fault zone behaves as the western boundary of Early Cretaceous volcanic rocks, and the Zhenghe–Dapu fault zone separates the SE-China Coastal Late Mesozoic volcanic-sedimentary basins and the Wuyi orogenic belt. Finally, we discuss the geodynamic mechanisms forming various basins, proposing a three-stage model of the Mesozoic sedimentary evolution.     

Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.     

Surfactants enhanced recovery of endosulfan from contaminated soils

Soil pollution due to hydrophobic organic compounds is a wide environmental problem. Extensive use of endosulfan in cotton and paddy to meet the needs of the growing population has led to contamination of soil and other ecosystems. Endosulfan is hydrophobic, highly toxic to aquatic and human population and persists in soil for more than a year. To overcome the problem of hydrophobicity and limited availability, surfactants play a major role in soil remediation. In the present study, the potential of non-ionic synthetic surfactants (Tween 80, Triton X-100) and biosurfactant (Surfactin produced by Bacillus subtilis) for enhancing the release of endosulfan from contaminated agricultural soils was evaluated using the batch method. Incorporation of the surfactant concentrations at above Criticle Miceller Concentration (0.5, 1 and 2 g/L) into soil enhances the release of endosulfan. Surfactin produced from Bacillus subtilis recorded maximum (91.5%) recovery. The observed order of recovery being surfactin > Tween 80 > Triton X-100. The result suggest that surfactants could help in the remediation of soils polluted by pesticides.     

The stiff upper LIP: investigating the High Arctic Large Igneous Province

The Canadian Arctic Islands expose a complex network of dykes and sills that belong to the High Arctic Large Igneous Province (HALIP), which intruded volatile‐rich sedimentary rocks of the Sverdrup Basin (shale, limestone, sandstone and evaporite) some 130 to 120 million years ago. There is thus great potential in studying the HALIP to learn how volatile‐rich sedimentary rocks respond to magmatic heating events during LIP emplacement. The HALIP remains, however, one of the least well known LIPs on the planet due to its remote location, short field season, and harsh climate. A Canadian–Swedish team of geologists set out in summer 2015 to further explore HALIP sills and their sedimentary host rocks, including the sampling of igneous and meta‐sedimentary rocks for subsequent geochemical analysis, and high pressure‐temperature petrological experiments to help define the actual processes and time‐scales of magma–sediment interaction. The research results will advance our understanding of how climate‐active volatiles such as CO_2, SO₂ and CH₄ are mobilised during the magma–sediment interaction related to LIP events, a process which is hypothesised to have drastically affected Earth's carbon and sulphur cycles. In addition, assimilation of sulphate evaporites, for example, is anticipated to trigger sulphide immiscibility in the magma bodies and in so doing could promote the formation of Ni‐PGE ore bodies. Here we document the joys and challenges of ‘frontier arctic fieldwork’ and discuss some of our initial observations from the High Arctic Large Igneous Province.     

A Note on Reviving the Goddard Satellite-Based Surface Turbulent Fluxes （GSSTF） Dataset

Accurate sea surface flux measurements are crucial for understanding the global water and energy cycles. The oceanic evaporation, which is a major component of the global oceanic fresh water flux, is useful for predicting oceanic circulation and transport. The global Goddard Satellite-based Surface Turbulent Fluxes Version-2 (GSSTF2; July 1987--December 2000) dateset that was officially released in 2001 has been widely used by scientific community for global energy and water cycle research, and regional and short period data analyses. We have recently been funded by NASA to resume processing the GSSTF dataset with an objective of continually producing a uniform dataset of sea surface turbulent fluxes, derived from remote sensing data. The dataset is to be reprocessed and brought up-to-date (GSSTF2b) using improved input datasets such as a recently upgraded NCEP/DOE sea surface temperature reanalysis, and an upgraded surface wind and microwave brightness temperature V6 dataset (Version 6) from the Special Sensor Microwave Imager (SSM/I) produced by Remote Sensing Systems (RSS). A second new product (GSSTF3) is further proposed with a finer temporal (12-h) and spatial (0.25^ox0.25^o) resolution. GSSTF2b (July 1987--December 2008) and GSSTF3 (July 1999--December 2009) will be released for the research community to use by late 2009 and early 2011, respectively.