Karst spring responses examined by process-based modeling

Ground water in karst terrains is highly vulnerable to contamination due to the rapid transport of contaminants through the highly conductive conduit system. For contamination risk assessment purposes, information about hydraulic and geometric characteristics of the conduits and their hydraulic interaction with the fissured porous rock is an important prerequisite. The relationship between aquifer characteristics and short-term responses to recharge events of both spring discharge and physicochemical parameters of the discharged water was examined using a process-based flow and transport model. In the respective software, a pipe-network model, representing fast conduit flow, is coupled to MODFLOW, which simulates flow in the fissured porous rock. This hybrid flow model was extended to include modules simulating heat and reactive solute transport in conduits. The application of this modeling tool demonstrates that variations of physicochemical parameters, such as solute concentration and water temperature, depend to a large extent on the intensity and duration of recharge events and provide information about the structure and geometry of the conduit system as well as about the interaction between conduits and fissured porous rock. Moreover, the responses of solute concentration and temperature of spring discharge appear to reflect different processes, thus complementing each other in the aquifer characterization.     

Transition probability/Markov chain analyses of DNAPL source zones and plumes

At sites where a dense nonaqueous phase liquid (DNAPL) was spilled or released into the subsurface, estimates of the mass of DNAPL contained in the subsurface from core or monitoring well data, either in the nonaqueous or aqueous phase, can be highly uncertain because of the erratic distribution of the DNAPL due to geologic heterogeneity. In this paper, a multiphase compositional model is applied to simulate, in detail, the DNAPL saturations and aqueous-phase plume migration in a highly characterized, heterogeneous glaciofluvial aquifer, the permeability and porosity data of which were collected by researchers at the University of Tübingen, Germany. The DNAPL saturation distribution and the aqueous-phase contaminant mole fractions are then reconstructed by sampling the data from the forward simulation results using two alternate approaches, each with different degrees of sampling conditioning. To reconstruct the DNAPL source zone architecture, the aqueous-phase plume configuration, and the contaminant mass in each phase, one method employs the novel transition probability/Markov chain approach (TP/MC), while the other involves a traditional variogram analysis of the sampled data followed by ordinary kriging. The TP/MC method is typically used for facies and/or hydraulic conductivity reconstruction, but here we explore the applicability of the TP/MC method for the reconstruction of DNAPL source zones and aqueous-phase plumes. The reconstructed geometry of the DNAPL source zone, the dissolved contaminant plume, and the estimated mass in each phase are compared using the two different geostatistical modeling approaches and for various degrees of data sampling from the results of the forward simulation. It is demonstrated that the TP/MC modeling technique is robust and accurate and is a preferable alternative compared to ordinary kriging for the reconstruction of DNAPL saturation patterns and dissolved-phase contaminant plumes.     

Changes in biodiversity of the extremely polluted Golden Horn Estuary following the improvements in water quality

Long-term biological data supported by physicochemical parameters were evaluated to investigate the biodiversity of the Golden Horn Estuary from the past to the present. Limited observations dating back to 60 years ago indicated the existence of a diverse community in this small estuary. Unfortunately, in parallel with the increase in unplanned settlements and industry around the Golden Horn, pollution stress increased since the 1960s. Preliminary studies in the 1990s indicated survival of only a couple of pollution-resistant species, in the relatively cleaner lower estuary. Following the intensification of rehabilitation studies in 1998 and particularly after the opening of the floating bridge at the mid estuary; a remarkable day-by-day recovery in marine life has begun with the improving water quality. Nutrient concentrations decreased markedly; while water clarity significantly increased. Fecal coliform values decreased 10(3) fold. Phytoplankton composition changed and dense blooms of eukaryotic phytoplankters frequently occurred. Hydrogen sulfide almost completely disappeared even during the warmest periods of the year and dissolved oxygen concentrations increased. All results clearly depicted that the Golden Horn ecosystem shifted to eutrophic conditions from an anoxic environment. SCUBA dives in 2002, documented the level of diversification of life in the Golden Horn. All appropriate substratums were intensely covered by macrobenthic forms until the Halic Bridge and filter feeders dominated the plankton-rich ecosystem. Achieving the diversity of 1940s is not possible since the Black and Marmara seas, influencing water quality of the Golden Horn, are also suffering from anthropogenic impacts and are far less diverse than their rich diversity in 1940s. However, the Golden Horn is a good example that even the most polluted ecosystems can recover when appropriate measures are taken.     

Are toxic contaminants accumulating in Massachusetts coastal sediments following startup of the Massachusetts Bay outfall: a comprehensive comparison of baseline and post-diversion periods

The Massachusetts Water Resources Authority (MWRA) conducts monitoring to address concerns related to the 2000 diversion of secondarily treated effluent discharge into Massachusetts Bay. Baseline data (1992-2000) showed multiple regions defined by physical and chemical composition. Near the Massachusetts Bay outfall, there is a series of heterogeneous sediments in relatively close proximity to the primary historic source of contaminants (Boston Harbor). Farfield sediments exhibited greater compositional definition from one another, which was attributed to the greater spatial separation of the sampling locations. Factors that influence contaminant variability include local and distributed sources, and are primarily related to gradients in depositional environments. Post-diversion sediment data suggest that 4 years of treated effluent discharge has not increased contaminant concentrations to the bay system. However, abundance of the sewage tracer, Clostridium perfringens, has increased variably in sediments located within 2 km of the outfall, providing a distinct effluent signal near the outfall.     

Salinity-induced survival strategy of Vibrio cholerae associated with copepods in Cochin backwaters

The occurrence of Vibrio cholerae in water, sediment and copepods was studied over a wide range of salinity using conventional and polymerase chain reaction (PCR) techniques in the Cochin backwaters. V. cholerae occurred either as culturable or non-culturable form in this tropical estuary. During the pre monsoon period when high salinity prevailed (35.5psu) V. cholerae was associated with copepods only in non-culturable form, but with the onset of monsoon when lower salinity prevailed, copepod-associated-V. cholerae reverted back to culturable form. The optimum salinity range for culturability was found to be 15-20psu. This points to the fact that salinity is a major factor that which influences V. cholerae's culturability and its association with copepods in Cochin backwaters.     

The use of the marine biotic index AMBI in the assessment of the ecological status of the Obidos lagoon (Portugal)

This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.     

Mediterranean fin whales at risk from fatal ship strikes

This paper reviews and analyzes ship collision records for the relatively isolated population of fin whales in the Mediterranean Sea from 1972 to 2001. Out of 287 carcasses, 46 individuals (16.0%) were certainly killed by boats. The minimum mean annual fatal collision rate increased from 1 to 1.7 whales/year from the 1970s to the 1990s. Fatal strike events (82.2%) were reported in or adjacent to the Pelagos Sanctuary, characterized by high levels of traffic and whale concentrations. Among 383 photo-identified whales, 9 (2.4%) had marks that were attributed to a ship impact. The reported rates are unusually high for baleen whales. The high likelihood of unreported fatal strikes combined with other anthropogenic threats suggests an urgent need for a comprehensive, basin-wide conservation strategy, including ship strike mitigation requirements, like real-time monitoring of whale presence and distribution to re-locate ferry routes to areas of lower cetacean density, and reducing ship speed in high cetacean density areas.     

A 3D hydrodynamic fate and transport model for herbicides in Sacca di Goro coastal lagoon (Northern Adriatic)

Sacca di Goro is a shallow coastal microtidal lagoon with a surface area of 26 km2, and an average depth of about 1.5m. Fresh water pollutant loads from Po River branches and several drainage canals lead to anthropogenic eutrophication, frequent summer anoxia crises and chemical contamination. Such events not only affect the lagoon ecosystem but also cause serious economic losses, the lagoon being the second largest producer of clams in Italy. The present work aims at using a fate model coupled with COHERENS 3D hydrodynamic model to simulate and to explain the spatial distribution and temporal variations of s-triazines herbicides in the Sacca di Goro lagoon. The simulation results of spatial and temporal dynamic behaviour of atrazine, simazine and terbuthylazine have been compared with experimental data obtained during an annual monitoring programme.     

Nitrogen isotope ratios in estuarine biota collected along a nutrient gradient in Narragansett Bay, Rhode Island, USA

Stable nitrogen isotope ratios were used to study the incorporation of anthropogenically-derived nitrogen into the food webs of salt marsh systems along a contamination gradient in Narragansett Bay. Nitrogen isotope ratios (delta(15)N) were measured in six estuarine species collected from three marshes along this gradient, monthly from June to October between 1997 and 1999. A significant decrease in delta(15)N was found with distance along the estuary for four of the six species. Significant differences were found among monthly isotope ratios for some species. Nitrogen isotope ratios in sea lettuce (Ulva lactuca) increased during the summer season with highest delta(15)N values measured during September and October. This trend was most pronounced at the station receiving the highest nutrient inputs. Elevated delta(15)N values at this station appeared to correlate with seawater ammonia/nitrate concentration ratios. The temporal variations in delta(15)N suggest that care should be taken in species selection and the design of sampling schemes of studies using delta(15)N for monitoring anthropogenic nutrients in aquatic systems. Sampling programs designed to determine long-term trends should consider species that do not show rapid fluctuations in isotope ratios. The mud snail, Nassarius obsoletus, responded this way in the present study. Studies designed to measure short-term changes should include species such as U. lactuca, which rapidly respond to isotope changes. The results from this study also help to establish a baseline for nitrogen isotope values in Narragansett Bay. This information can be used to monitor future trends in nitrogen inputs to this estuary.