Hydrothermal uranium deposits containing molybdenum and fluorite in the Marysvale volcanic field, west-central Utah

Uranium deposits containing molybdenum and fluorite occur in the Central Mining Area, near Marysvale, Utah, and formed in an epithermal vein system that is part of a volcanic/hypabyssal complex. They represent a known, but uncommon, type of deposit; relative to other commonly described volcanic-related uranium deposits, they are young, well-exposed and well-documented. Hydrothermal uranium-bearing quartz and fluorite veins are exposed over a 300 m vertical range in the mines. Molybdenum, as jordisite (amorphous MoS₂), together with fluorite and pyrite, increase with depth, and uranium decreases with depth. The veins cut 23-Ma quartz monzonite, 20-Ma granite, and 19-Ma rhyolite ash-flow tuff. The veins formed at 19-18 Ma in a 1 km² area, above a cupola of a composite, recurrent, magma chamber at least 24 × 5 km across that fed a sequence of 21- to 14-Ma hypabyssal granitic stocks, rhyolite lava flows, ash-flow tuffs, and volcanic domes. Formation of the Central Mining Area began when the intrusion of a rhyolite stock, and related molybdenite-bearing, uranium-rich, glassy rhyolite dikes, lifted the fractured roof above the stock. A breccia pipe formed and relieved magmatic pressures, and as blocks of the fractured roof began to settle back in place, flat-lying, concave-downward, “pull-apart” fractures were formed. Uranium-bearing, quartz and fluorite veins were deposited by a shallow hydrothermal system in the disarticulated carapace. The veins, which filled open spaces along the high-angle fault zones and flat-lying fractures, were deposited within 115 m of the ground surface above the concealed rhyolite stock. Hydrothermal fluids with temperatures near 200 °C, ¹⁸O_H2O∼−1.5, D_H2O∼−130, log f O₂ about −47 to −50, and pH about 6 to 7, permeated the fractured rocks; these fluids were rich in fluorine, molybdenum, potassium, and hydrogen sulfide, and contained uranium as fluoride complexes. The hydrothermal fluids reacted with the wallrock resulting in precipitation of uranium minerals. At the deepest exposed levels, wallrocks were altered to sericite; and uraninite, coffinite, jordisite, fluorite, molybdenite, quartz, and pyrite were deposited in the veins. The fluids were progressively oxidized and cooled at higher levels in the system by boiling and degassing; iron-bearing minerals in wall rocks were oxidized to hematite, and quartz, fluorite, minor siderite, and uraninite were deposited in the veins. Near the ground surface, the fluids were acidified by condensation of volatiles and oxidation of hydrogen sulfide in near-surface, steam-heated, ground waters; wall rocks were altered to kaolinite, and quartz, fluorite, and uraninite were deposited in veins. Secondary uranium minerals, hematite, and gypsum formed during supergene alteration later in the Cenozoic when the upper part of the mineralized system was exposed by erosion. Received: 23 June 1997 / Accepted: 15 October 1997     

Sulfur- and oxygen-isotopes in sediment-hosted stratiform barite deposits

Sulfur- and oxygen-isotope analyses have been obtained for sediment-hosted stratiform barite deposits in Alaska, Nevada, Mexico, and China to examine the environment of formation of this deposit type. The barite is contained in sedimentary sequences as old as Late Neoproterozoic and as young as Mississippian. If previously published data for other localities are considered, sulfur- and oxygen-isotope data are now available for deposits spanning a host-rock age range of Late Neoproterozoic to Triassic. On a δ³⁴S versus δ¹⁸O diagram, many deposits show linear or concave-upward trends that project down toward the isotopic composition of seawater sulfate. The trends suggest that barite formed from seawater sulfate that had been isotopically modified to varying degrees. The δ³⁴S versus δ¹⁸O patterns resemble patterns that have been observed in the modern oceans in pore water sulfate and water column sulfate in some anoxic basins. However, the closest isotopic analog is barite mineralization that occurs at fluid seeps on modern continental margins. Thus the data favor genetic models for the deposits in which barium was delivered by seafloor seeps over models in which barium was delivered by sedimentation of pelagic organisms. The isotopic variations within the deposits appear to reflect bacterial sulfate reduction operating at different rates and possibly with different electron donors, oxygen isotope exchange between reduction intermediates and H₂O, and sulfate availability. Because they are isotopically heterogeneous, sediment-hosted stratiform barite deposits are of limited value in reconstructing the isotopic composition of ancient seawater sulfate.     

Neotectonic faulting and the Late Weichselian shoreline gradients in SW Norway

The Younger Dryas (YD) maximum highstand shoreline in SW Norway has traditionally been considered as being slightly concave, gradually steepening in the direction of uplift. This phenomenon is attributed to geoidal and isostatic effects near the former ice-sheet margin. On the basis of isolation basin data from the region, we have reconstructed this shoreline, and a Bølling-Allerød (B-A) lowstand shoreline, along three profiles in SW Norway. Along all profiles there are shore levels which, within the error limits estimated, cannot be captured by a single straight (or curved) shoreline. The anomalous shore levels occur near major fault zones and are interpreted to reflect differential uplift rates on opposite sides of faults, superimposed on the general glacio-isostatic tilting of the region. The inferred faulting is consistent with observations previously reported as neotectonic ‘claims’ in the region and shed new light on the deformational structures observed in seismic profiles of the fjord sediments. Excluding the anomalous shore levels, a straight shoreline with gradient ca. 1.1 m/km provides the best and most consistent representation of the YD shore levels along the three profiles. The B-A lowstand shoreline is constrained by fewer data points, but is approximately parallel-dipping the highstand shoreline. Our reconstructions imply a less steep YD maximum highstand shoreline compared to previous reconstructions, where gradients up to 1.4 m/km have been inferred. This may imply that the ice load effect on the lithosphere in SW Norway during the YD is less than previously assumed.     

Learning about distant places through the Internet: Young students as global citizens?

The article explores how the use of the Internet in school settings influences the way young people develop as citizens in an interconnected world and the possible implications for teaching geography subject at school. First, this topic is approached theoretically through a discussion of new forms of citizenship. The issue is investigated by using interview data and observations on the use of the Internet by upper secondary school students in Norway when searching for information about distant places. During the interviews, knowledge about tropical rainforests was used as a practical example. The main finding is that although the students could access information about a large part of the world from their laptop, a distance remained between the students and the rainforests and those who live in them. The article also reveals that, although it is often argued that the national context is weakened as a frame for civic engagement, the students referred to it as a basic frame when engaging with what is distant. Thus, it may be questioned how the use of the Internet in schools contributes to the development of students as global citizens.     

Microbial sulfate reduction and metal attenuation in pH 4 acid mine water

Sediments recovered from the flooded mine workings of the Penn Mine, a Cu-Zn mine abandoned since the early 1960s, were cultured for anaerobic bacteria over a range of pH (4.0 to 7.5). The molecular biology of sediments and cultures was studied to determine whether sulfate-reducing bacteria (SRB) were active in moderately acidic conditions present in the underground mine workings. Here we document multiple, independent analyses and show evidence that sulfate reduction and associated metal attenuation are occurring in the pH-4 mine environment. Water-chemistry analyses of the mine water reveal: (1) preferential complexation and precipitation by H₂S of Cu and Cd, relative to Zn; (2) stable isotope ratios of ³⁴S/³²S and ¹⁸O/¹⁶O in dissolved SO₄ that are 2–3 ‰ heavier in the mine water, relative to those in surface waters; (3) reduction/oxidation conditions and dissolved gas concentrations consistent with conditions to support anaerobic processes such as sulfate reduction. Scanning electron microscope (SEM) analyses of sediment show 1.5-micrometer, spherical ZnS precipitates. Phospholipid fatty acid (PLFA) and denaturing gradient gel electrophoresis (DGGE) analyses of Penn Mine sediment show a high biomass level with a moderately diverse community structure composed primarily of iron- and sulfate-reducing bacteria. Cultures of sediment from the mine produced dissolved sulfide at pH values near 7 and near 4, forming precipitates of either iron sulfide or elemental sulfur. DGGE coupled with sequence and phylogenetic analysis of 16S rDNA gene segments showed populations of Desulfosporosinus and Desulfitobacterium in Penn Mine sediment and laboratory cultures.     

Seawater intrusion and fresh groundwater hydraulics in fjord delta aquifers inferred from ground penetrating radar and resistivity profiles—Sunndalsøra and Esebotn, western Norway

Geophysical surveys have been carried out in two fjord delta aquifers in western Norway. Geophysical methods comprised ground penetrating radar (GPR), shallow reflection seismic and resistivity measurements. The purpose of the investigations was to evaluate hydrogeological properties of the fjord delta aquifers with emphasis on the possibilities of abstracting saline groundwater for use in fish farming. At Sunndalsøra, reflection seismic was helpful in the mapping of the base of the aquifer. Resistivity profiles revealed both the spatial and seasonal variability of seawater intrusion. Penetration depths of ground penetrating radar (GPR-D) revealed the spatial variation of the boundary of the transition zone between saline and fresh groundwater. Maps of GPR-D can be used to indicate direction and magnitude of mean hydraulic gradients and thus to locate optimal sites for both fresh and saline groundwater abstraction.In fjord delta aquifers, both rivers and abandoned river channels constitute important groundwater divides. Optimal locations for saline groundwater abstraction wells are in areas separated from the rivers by abandoned river channels. In areas between the rivers and the abandoned river channels, groundwater abstraction will result in decreasing salinity of the water.     

Evidence in pre-2.2 Ga paleosols for the early evolution of atmospheric oxygen and terrestrial biota: comment and reply

The major points of disagreement between Holland and Rye and Ohmoto concern (1) the behavior of ferric iron. (2) the mechanisms of Fe loss. (3) the identification of real paleosols, and (4) the ages of some paleosols.