Geochemical techniques in geothermal research — the Hawaii example

The Hawaii Geothermal Project (HGP) was organized in 1972 to locate and utilize geothermal energy resources in Hawaii. A geophysical program was designed to select a site of high potential for a geothermal resource and to develop an understanding of the thermal processes of a basaltic volcano and its associated rift zones.The well was completed in July 1976 and after subsequent clearing was producing at 5800 kg/hr with a well head pressure of 11 kg/cm² and a temperature of 190°C (equivalent to 3.5 MW of electrical energy).The discharge fluid was only slightly saline despite the termination of the well 1768 m below sea level. The water was nearly depleted in magnesium but contained high concentrations of silica and sulfide. Geochemical thermometers based on the data of Fournier, Rowe, White, Ellis, and Truesdell are in excellent agreement with the measured downhole temperature of 275°C.Stable and radioactive isotope analyses for ¹⁴C, ¹³C and ¹³O indicate that 66% of the recharge is from local rainfall with a turnover of at least several hundred years. The remaining discharge is derived from sea water (10%) and hydrothermally altered fluids. Analyses for the gases CO₂, He and ³He indicate that the fluids have a deep-seated or magmatic source.     

Controls on pore-fluid concentration of He and Rn and the calculation of He/Rn ages

Controls governing the production of ⁴He and ²²²Rn in the solid phase as well as parameters and processes contributing to their transport into the pore fluid are discussed. ²²²Rn activity is used to quantify the uranium sources for ⁴He and the result is a simplified pore-fluid age equation which is virtually independent of the porosity, the water/rock ratio, the rock density and the uranium concentration, but does require a Th/U estimate. The crucial parameter is the ratio of the release factors for the two species, /GL_Rn//GL_He, which is discussed in terms of three possible release mechanisms: (1) recoil; (2) recoil followed by diffusion; and (3) weathering release of accumulated ⁴He. It was found that /GL_Rn//GL_He can vary over several orders of magnitude, but can be expressed in terms of the effective grain size r, and the diffusive half-length for ²²²Rn decay, r_e.⁴He measurements are used to “date” gases from known gas fields and the agreement with the assumed source-rock age is good. Application of ⁴He/ ²²²Rn measurements to continental freshwater springs indicates that the weathering release of accumulated ⁴He dominates the input and results in a large overestimate of groundwater age. Measurement in the Lardarello geothermal field indicates that the ⁴He/²²²Rn method can indicate relative transport direction. Other possible applications in various geochemical fields are suggested.     

Late-glacial and postglacial sedimentation in Lake Superior based on seismic-reflection profiles

Seismic reflection profiles (3.5 kHz) were obtained along more than 3500 km of shiptrack in Lake Superior within the last 2 yr. The acoustic character of profiles is categorized as: (I) a single, strong reflector at the lake floor, (II) a thick, acoustically transparent layer overlying a strong reflector, and (III) relatively thick sediment with internal acoustic reflectors. These profiles, in conjunction with sediment cores from the area, reveal that varved glacial-lacustrine sediment settled out preferentially in a trough between Isle Royale and the north shore, and to a lesser extent in other topographic depressions; bottom currents generated by storm waves prevent clay accumulation on till or bedrock in the open lake wherever the bottom is shallower than 100 m; bottom currents prevent deposition or erode bottom sediment in certain deep-water (> 200 m) valleys; and lacustrine sediment is disturbed by creep or slumping off Grand Portage, Minnesota, and by other processes such as dewatering in many other areas. These factors complicate sedimentation in Lake Superior, and must be considered when investigating any aspect of the lake sediment.     

Kimberlites: Their relation to mantle hotspots

Available age data support the hypothesis that kimberlite intrusions are formed by mantle hotspots. The hypothesis has been tested by inverting the volcanic traces formed by three hotspots to determine the post-Triassic motions of Africa, South America, and North America relative to these hotspots. Then, using these motions, the kimberlites intruded on these continents within the last 150 m.y. are relocated to their place of origin in the present hotspot reference frame. The result indicates that a majority of the kimberlites formed within 5° of a mantle hotspot. Statistical analysis shows that this kimberlite/hotspot correlation is significant at above the 90% level.     

Erosion and deposition by debris flows at Mt Thomas,North Canterbury,New Zealand

The grass-covered slopes on the southern flank of Mt Thomas, an upfaulted block of highly sheared sandstone and argillite 40 km NW of Christchurch, New Zealand, are presently undergoing severe erosion by a combination of mass-wasting processes. Gully erosion, soil slips, and debris flows have carved out a number of steep, deeply incised ravines, from which coarse debris is transported (primarily by debris flows) to alluvial fans below. Geologic and historical evidence indicates that debris flows have been episodically active here for at least the last 20,000 years and have been the dominant process in fan building. This demonstrates that catastrophic geomorphic processes, rather than processes acting at relatively uniform rates, can be dominant in humid-temperate areas as well as in arid and semi-arid regions. In April 1978, debris flows were triggered in one of two unstable ravines in the Bullock Creek catchment by a moderate intensity, long duration rainstorm with a return period in excess of 20 years. Surges of fluid debris, moving at velocities up to 5 m/s, transported a dense slurry of gravel, sand, and mud up to 3·5 km over a vertical fall of 600 m. Deposition on the alluvial fan occurred when the flows left the confines of an entrenched fan-head channel and spread out as a 0·16 km² sheet averaging 1·2 m thick. In all, 195,000 m³ were deposited, roughly a third of that being reworked sediments from the head of the fan. Sediment yield from this one event would be equivalent to several thousand years worth of erosion at average sediment discharge rates for small South Island mountain catchments. Samples of viscous fluid debris during surges contained up to 84 per cent solids, composed of 70 per cent gravel, 20 per cent silt, and 4 per cent clay. Fluid density of the material ranged between 1·95 and 2·13 g/cm³, and it was extremely poorly sorted. Between surges the fluid was less viscous, less dense, and unable to carry gravel in suspension. Severe fan-head entrenchment of the stream channel (approximately 10 m in less than 24 hours) was accomplished by the erosive action of the surges. Tectonic uplift of the Mt Thomas block and the weak, crushed condition of the bedrock appear to be ultimately responsible for the catastropic erosion of slopes in the Bullock Creek catchment. However, forest clearing within the last few centuries appears to have greatly increased the rate of mass wasting and gully erosion on these slopes.     

Egg extrusion as a kepone-clearance route in the blue crab,Callinectes sapidus

The concentration of Kepone in extruded egg masses and the backfin muscles of the blue crab,Callinectes sapidus, collected from seven stations in the lower James River and lower Chesapeake Bay was determined. Crabs from the lower James River were generally more contaminated than those from the lower Chesapeake Bay. Extruded eggs contain approximately three times more Kepone than backfin muscle. Egg extrusion is concluded to be a major route of Kepone clearance from female blue crabs.     

Transposed Climates for Study of Water Supply Variability on the Laurentian Great Lakes

Hydrological models of the Great Lakes basin were used to study the sensitivity of Great Lakes water supplies to climate warming by driving them with meteorological data from four U.S. climate zones that were transposed to the basin. Widely different existing climates were selected for transposition in order to identify thresholds of change where major impacts on water supplies begin to occur and whether there are non-linear responses in the system. The climate zones each consist of 43 years of daily temperature and precipitation data for 1,000 or more stations and daily evaporation-related variables (temperature, wind speed, humidity, cloud cover) for approximately 20–35 stations. A key characteristic of these selected climates was much larger variability in inter-annual precipitation than currently experienced over the Great Lakes. Climate data were adjusted to simulate lake effects; however, a comparison of hydrologic results with and without lake effects showed that there was only minor effects on water supplies.     

A Three-year Study of Nonmethane Hydrocarbons in Surface Air over Saxony (Germany)

Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source.