Thermal decarboxylation of acetic acid: Implications for origin of natural gas

Laboratory experiments on the thermal decarboxylation of solutions of acetic acid at 200°C and 300°C were carried out in hydrothermal equipment allowing for on-line sampling of both the gas and liquid phases for chemical and stable-carbon-isotope analyses. The solutions had ambient pH values between 2.5 and 7.1; pH values and the concentrations of the various acetate species at the conditions of the experiments were computed using a chemical model.Results show that the concentrations of acetic acid, and not total acetate in solution, control the reaction rates which follow a first order equation based on decreasing concentrations of acetic acid with time. The decarboxylation rates at 200°C (1.81 × 10^?8 per second) and 300°C (8.17 × 10^?8 per second) and the extrapolated rates at lower temperatures are relatively high. The activation energy of decarboxylation is only 8.1 kcal/mole. These high decarboxylation rates, together with the distribution of short-chained aliphatic acid anions in formation waters, support the hypothesis that acid anions are precursors for an important portion of natural gas.Results of the δ¹³C values of CO₂, CH₄, and total acetate show a reasonably constant fractionation factor of about 20 permil between CO₂ and CH₄ at 300°C. The δ¹³C values of CO₂ and CH₄ are initially low and become higher as decarboxylation increases.     

U–Pb zircon geochronology of the Daraban leucogranite,Mawat ophiolite,Northeastern Iraq: A record of the subduction to collision history for the Arabia–Eurasia plates

The Mawat ophiolite is part of the Mesozoic Neo‐Tethyan ophiolite belt of the Middle East and is located in the Zagros Imbricate Zone of Iraq. It represents fossil fragments of the Neo‐Tethyan oceanic lithosphere within the Alpine collisional system between the Arabian and Eurasia Plates. The first U–Pb zircon dating of the Daraban leucogranite from the Mawat ophiolite provides a ²⁰⁷Pb–²⁰⁶Pb age of 96.8 ± 6.0 Ma. The age is 59.0 ± 6.0 m.y. older than the previously published age of the Daraban leucogranite obtained by ⁴⁰Ar–³⁹Ar muscovite dating method. The U–Pb dating of magmatic zircons collected from the Daraban leucogranite, which intrudes into the Mawat ophiolite, reveals that melting of the pelagic sediment beneath the hot Zagros proto‐ophiolite in an intra‐oceanic arc environment led to anatexis at the subduction front and the generation of granitic melts at 96.8 ± 6.0 Ma, which were emplaced in the overlaying mantle wedge. This process was a response to the initial formation of the Neo‐Tethys ophiolite above a northeast‐dipping intra‐oceanic subduction zone at 96.8 ± 6.0 Ma. Published ⁴⁰Ar–³⁹Ar muscovite dating from the same leucogranite dike yields plateau ages of 37.7 ± 0.3 Ma, reflecting that the age was reset during the Arabia–Eurasia continental collision. Therefore, the bimodal age populations from the granitic intrusion in the Mawat ophiolite preserve a record of the subduction to the collision cycle of the Zagros Orogenic Belt. The 59.0 ± 6.0 m.y. age difference from the Daraban leucogranite represents the duration of the subduction‐collision cycle of the Zagros Orogenic Belt in the Kurdistan region of Iraq and the time span for the closure of the Neo‐Tethys Ocean along the northern margin of the Arabian plate.     

Geochemical Characteristics of Oil from Oligocene Lower Ganchaigou Formation Oil Sand in Northern Qaidam Basin,China

Oil from the Oligocene oil sands of the Lower Ganchaigou Formation in the Northern Qaidam Basin and the related asphaltenes was analyzed using bulk and organic geochemical methods to assess the organic matter source input, thermal maturity, paleo-environmental conditions, kerogen type, hydrocarbon quality, and the correlation between this oil and its potential source rock in the basin. The extracted oil samples are characterized by very high contents of saturated hydrocarbons (average 62.76%), low contents of aromatic hydrocarbons (average 16.11%), and moderate amounts of nitrogen–sulfur–oxygen or resin compounds (average 21.57%), suggesting that the fluid petroleum extracted from the Oligocene oil sands is of high quality. However, a variety of biomarker parameters obtained from the hydrocarbon fractions (saturated and aromatic) indicate that the extracted oil was generated from source rocks with a wide range of thermal maturity conditions, ranging from the early to peak oil window stages, which are generally consistent with the biomarker maturity parameters, vitrinite reflectance (approximately 0.6%), and T_max values of the Middle Jurassic carbonaceous mudstones and organic-rich mudstone source rocks of the Dameigou Formation, as reported in the literature. These findings suggest that the studied oil is derived from Dameigou Formation source rocks. Furthermore, the source- and environment-related biomarker parameters of the studied oil are characterized by relatively high pristane/phytane ratios, the presence of tricyclic terpanes, low abundances of C₂₇ regular steranes, low C₂₇/C₂₉ regular sterane ratios, and very low sterane/hopane ratios. These data suggest that the oil was generated from source rocks containing plankton/land plant matter that was mainly deposited in a lacustrine environment and preserved under sub-oxic to oxic conditions, and the data also indicate a potential relationship between the studied oil and the associated potential source rocks. The distribution of pristane, phytane, tricyclic terpanes, regular steranes and hopane shows an affinity with the studied Oligocene Lower Ganchaigou Formation oil to previously published Dameigou Formation source rocks. In support of this finding, the pyrolysis–gas chromatography results of the analyzed oil asphaltene indicate that the oil was primarily derived from type II organic matter, which is also consistent with the organic matter of the Middle Jurassic source rocks. Thus, the Middle Jurassic carbonaceous mudstones and organic rock mudstones of the Dameigou Formation could be significantly contributing source rocks to the Oligocene Lower Ganchaigou Formation oil sand and other oil reservoirs in the Northern Qaidam Basin.

     

Flood hazard in Wadi Rahbaa area, Egypt

In the last decade, attention has been devoted to the southern part of the Egyptian Red Sea coast due to the large touristic and mining activities. Egypt spares no effort to develop it, to build new urban communities, and to create new job opportunities. Many comprehensive planning studies have been conducted. Many luxurious tourist spots, airports, and harbors have been constructed. These areas are subjected to flash floods, which represent a frequent threat to these urbanization activities that may cause losses in livelihood. By analyzing the geomorphologic features of the study area, intense stream networks are detected that, with the available metrological data, require flood management and analysis to mitigate the possible negative effects and to benefit from the estimation of flood water. Rahbaa basin is a sub-catchment of wadi Hodin. Flash floods within this area threaten the Red Sea coastal plain as well as the main coastal roads. It also directly drained out to the sea, which leads to a loss of huge amounts of flood water that is useful for arid regions. Using geographic information system and remote-sensing tools with the application of a comprehensive graphical modeling (watershed modeling system) supports the hydrological modeling of HEC-1. The total amount of runoff is calculated and the hydrograph of the 50-year return period is computed using rainfall historical data.     

Quantification of carbon stock to understand two different forest management regimes in Kayar Khola watershed,Chitwan, Nepal

The impact of forest management activities on the ability of forest ecosystems to sequester and store atmospheric carbon is of increasing scientific and social concern. This is because a quantitative understanding of how forest management enhances carbon storage is lacking in most forest management regimes. In this paper two forest regimes, government and community-managed, in Kayar Khola watershed, Chitwan, Nepal were evaluated based on field data, very high resolution (VHR) GeoEye-1 satellite image and airborne LiDAR data. Individual tree crowns were generated using multi-resolution segmentation, which was followed by two tree species classification (Shorea robusta and Other species). Species allometric equations were used in both forest regimes for above ground biomass (AGB) estimation, mapping and comparison. The image objects generated were classified per species and resulted in 70 and 82 % accuracy for community and government forests, respectively. Development of the relationship between crown projection area (CPA), height, and AGB resulted in accuracies of R² range from 0.62 to 0.81, and RMSE range from 10 to 25 % for Shorea robusta and other species respectively. The average carbon stock was found to be 244 and 140 tC/ha for community and government forests respectively. The synergistic use of optical and LiDAR data has been successful in this study in understanding the forest management systems.     

An integrated approach for groundwater assessment at the Northwestern Coast of Egypt (Ras El Hekma area): case study

Ras El Hekma area was chosen for the present study due to its special conditions; the area lacks water for human and agriculture proposes. This area represents one of the main headlands along the southern Mediterranean coast, where population growth and agricultural activities require the corresponding development of groundwater. The main objective of this paper is to monitor and record data about the current groundwater as well as to have a systematic understanding of the hydrogeological setting in the area of study. Also, one of the study objectives is to identify and assess the factors which affect the groundwater occurrence and quality. This assessment will contribute to groundwater protection. The study area has three aquifers: Holocene, Pleistocene, and Middle Miocene aquifers. The recharge to these aquifers comes from the direct infiltration of rainfall and from the surface runoff. Rock–water interaction and the effect of solution and leaching processes on the mineralization of groundwater are studied using the PHREEQC model. Seawater intrusion contributes effectively to the increase in water salinity. The present study clarifies the relationship between the depth to water, the sea level and salinity of water. The groundwater in the area of study is evaluated for drinking, domestic, livestock and agricultural purposes. The present study suggests some recommendations for developing the groundwater in the study area.     

A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models

A controlled field pilot has been developed in Bozeman, Montana, USA, to study near surface CO₂ transport and detection technologies. A slotted horizontal well divided into six zones was installed in the shallow subsurface. The scale and CO₂ release rates were chosen to be relevant to developing monitoring strategies for geological carbon storage. The field site was characterized before injection, and CO₂ transport and concentrations in saturated soil and the vadose zone were modeled. Controlled releases of CO₂ from the horizontal well were performed in the summers of 2007 and 2008, and collaborators from six national labs, three universities, and the U.S. Geological Survey investigated movement of CO₂ through the soil, water, plants, and air with a wide range of near surface detection techniques. An overview of these results will be presented.     

Predicting the chemical and mechanical properties of gypseous soils using different simulation technics

Acta Geotechnica - Gypseous soils are soils that contain sufficient quantities of gypsum that are considered collapsible soil. The present study's objective is to predict the shear strength...     

美国犹他州中部Green River流域农业区硒的淋出速度和形态

尽管硒(Se)是一种重要的生命元素,但是即使浓度很低,也有可能会造成危害。在美国西部,包括犹他州中部GreenRiver流域斯图尔特湖水鸟管理区,大面积的农业排水区中都存在硒。为了对该场地进行地球化学研究和进行修复,取未受扰动的岩芯分析了硒的形态、浓度和迁移。用酸消解进行前处理对土壤和曼柯斯页岩风化壳进行了分析,结果表明,硒的最高浓度为3ppm,采用连续萃取法的分析结果表明,有19%~79%的硒是以有机物形式存在的,有17%~67%的硒是以元素形式存在的。柱实验研究结果表明,硒可以从深部土壤迅速淋出,可溶性硒的质量分数很高,达到了292×10-9。表层土壤中硒的淋出速度最初很慢,但是非常稳定,最终淋出速度会超过深部土壤。当对岩心通过放射灭菌后,表层土壤和深部土壤的淋出速度都会加快。计算结果表明,在修复富含硒的土壤时,所需的水量很大,每kg土壤需要约500L的水量。