Development of secondary porosity in the Fairholme carbonate complex (southwest Alberta, Canada)

Because of their economic importance as hydrocarbon reservoirs, the Upper Devonian dolomitized carbonate reefs in southwest Alberta have been the subject of several studies. Still, there is no consensus on the process of matrix dolomitization and furthermore, the process of vug development is not often addressed. The studied outcrops show features of an early diagenetic matrix-selective dolomitization by a Late Devonian seawater-derived fluid. Seepage reflux dolomitization combined with latent reflux is proposed, which best explains most chemical characteristics. The cements in the vugs are precipitated from warm saline, ⁸⁷Sr-enriched fluids and testify to thermogenic sulphate reduction based on the presence of sulphur, CO₂ and H₂S in inclusions, relatively high homogenization temperatures and depleted δ¹³C values, which sets constraints on the timing of vug formation. Secondary porosity may be created by the mixing of formation water with a tectonically and topographically driven fluid and by the dissolution of anhydrite nodules.     

Novel applications of fluid inclusions and isotope geochemistry in unravelling the genesis of fossil travertine systems

The Denizli Basin is a fault‐bounded Neogene–Quaternary depression located in the Western Anatolian Extensional Province, Western Turkey. The basin is a unique geological site with abundant active and fossil (Quaternary) travertine and tufa deposits. Fluid inclusion microthermometry and isotopic analysis were applied to study the genesis of the Ball?k fossil travertine deposits, located in the south‐eastern part of the basin. Microthermometry on fluid inclusions indicates that the main travertine precipitating and cementing fluids are characterized by low salinity (<0·7 wt% NaCl equivalent) and variable temperatures that cluster at <50°C and ca 100°C. Fluids of meteoric origin have been heated by migration to the deeper subsurface, possibly in a local high geothermal gradient setting. A later uncommon cementation phase is related to a fluid with a significantly higher salinity (25·5 to 26·0 wt% bulk). The fluid obtained its salinity by interaction with Late Triassic evaporite layers. Strontium isotopes indicate that the parent carbonate source rock of the different travertine precipitates is very likely to be the Triassic limestone of the Lycian Nappes. Carbon isotopes suggest that the parent CO₂ gas originated from thermal decarbonation of the Lycian limestones with minor contributions of magmatic degassing and organic soil CO₂. Oxygen isotopes confirm the meteoric origin of the fluids and indicate disequilibrium precipitation because of evaporation and degassing. Results were integrated within the available geological data of the Denizli Basin in a generalized travertine precipitation model, which enhanced the understanding of fossil travertine systems. The study highlights the novel application of fluid inclusion research in unravelling the genesis of continental carbonates and provides several recommendations for hydrocarbon exploration in travertine‐bearing sedimentary basins. The findings suggest that travertine bodies and their parent carbonate source rocks have the potential to constitute interesting subsurface hydrocarbon reservoirs.     

Speciation and Mobility of Selected Trace Metals (As, Cu, Mn, Pb and Zn) in Sediment with Depth in Cam River-Mouth, Haiphong, Vietnam

The speciation and mobility of some selected trace metals (As, Cu, Mn, Pb and Zn) in sediments with depth was investigated in the Cam River-mouth (Vietnam) by collecting sediment cores and analysing porewater and sediment composition, complemented with single (ammonium-EDTA) and sequential (BCR 3-step) extractions and mineralogical analysis (XRD). All trace metals show overall decreasing trends with depth in porewater as a result of anthropogenic input in upper sediment layers. High porewater concentrations of As, Mn and Pb in oxic and suboxic sediment layers may result in groundwater pollution. Sediment-bound Pb and Mn dominate in the reducible and the acid-soluble fraction, respectively, while Cu and Zn distribute rather evenly between four extracted fractions. The porewater metal speciation, as predicted by a geochemical model Visual MINTEQ version 3.0, indicates that the toxicity of Cu, Mn, Pb and Zn (presented by the proportions of free metal ions) decreases with depth, while the toxicity of As increases when As(III) becomes more abundant. The dissolved concentrations of trace metals are not only controlled by the precipitation/dissolution of discrete hydroxide/oxide, carbonate and phosphate minerals, but also by sorption processes on major sorbents (i.e. As on goethite, and Mn and Zn on calcite and dolomite). Sulphide minerals do not show any control even in the anoxic zone most likely because of the low concentration of sulphur.     

X-ray timing behaviour of Cygnus X-2 at low intensities

It is known that the overall (mean) intensity of the low-mass X-ray binary Cyg X-2 varies on time-scales from a day to months, independently of the variations on time-scales of hours to a day by which the source moves between the horizontal, normal and flaring branches.
We present RXTE PCA observations of Cyg X-2, taken when its overall intensity was near its lowest values, in 1996 October and 1997 September. For the first time we perform a study of the fast timing behaviour at such low intensities. During the 1996 October observations, the source was in the left part of the horizontal branch, and during the 1997 September observations was most likely in the lower parts of the normal branch and flaring branch.
We find that the properties of the very low-frequency noise during the 1997 September observations are consistent with a monotonic decrease in its strength and power-law index as a function of overall intensity. In contrast, the strength of the ∼6 Hz normal branch quasi-periodic oscillations does not vary monotonically with overall intensity. They are strongest at medium overall intensity and weaker both when the overall intensity is low and when the overall intensity is high.     

A detailed study of the 5-Hz quasi-periodic oscillations in the bright X-ray transient and black hole candidate GRS 1739–278

We present a detailed study of the 5-Hz quasi-periodic oscillation (QPO) recently discovered in the bright X-ray transient and black hole candidate (BHC) GRS     (Borozdin & Trudolyubov) during a Rossi X-ray Timing Explorer observation taken on 1996 March 31. In total 6.6 ksec of on-source data were obtained, divided in two data sets of 3.4 and 3.2 ksec which were separated by ∼2.6 ksec. The 5-Hz QPO was only present during the second data set. The QPO increased in strength from below 2 per cent rms amplitude for photon energies below 4 keV to ∼5 per cent rms amplitude for energies above 10 keV. The soft QPO photons (below 5 keV) lagged the hard ones (above 10 keV) by almost 1.5 rad. Besides the QPO fundamental, its first overtone was detected. The strength of the overtone increased with photon energy (from < 2 per cent rms below 5 keV to ∼8 per cent rms above 10 keV). Although limited statistics did not allow for an accurate determination of the lags of the first overtone, indications are that also for this QPO the soft photons lagged the hard ones. When the 5-Hz QPO was not detected (i.e., during the first part of the observation), a broad noise component was found for photon energies below 10 keV but it became almost a true QPO (with a Q value of ∼1.9) above that energy, with a frequency of ∼3 Hz. Its hard photons preceded the soft ones in a way reminiscent of the 5-Hz QPO, strongly suggesting that both features are physically related. We discuss our finding in the framework of low-frequency QPOs and their properties in BHCs.     

Establishing a transboundary network of marine protected areas: Diplomatic and management options for the east African context

International conservation efforts and cooperation are increasingly necessary, particularly at an ecoregion level, for the achievement of international targets for protecting biodiversity and degradation of ecosystems. Whereas more than 11 percent of land is protected, less than 1 percent of marine space is similarly protected. Transboundary networks of marine protected areas and transboundary marine protected areas (TBMPAs) are an essential form of cooperation for meeting these international targets. This paper explores the diplomatic and political options for regional and sub-regional cooperation between Tanzania, Mozambique, and South Africa, for the establishment of transboundary conservation mechanisms in the Eastern African Marine Ecoregion (EAME). Five options for the establishment and management of these mechanisms are presented, together with actions to be taken to facilitate cooperation. The paper deal with a proposed strategy for the implementation of transboundary conservation mechanisms, focusing on TBMPAs, between the three countries at a biogeographical/sub-regional level, supported by lessons learnt in other transboundary marine conservation experiences. The paper concludes that although political will may exist among States sharing borders to establish TBMPAs, the complexity of dealing with sub-regional realities is a difficult obstacle to overcome in a single step. The situation at each border must be taken into account in order that different multi-scale and multivariate solutions, supported by a common baseline will ultimately converge in a common trilateral framework. Finally, a two-step approach seems to be in course with the declaration (October 2009) of a TBMPA linking Ponta do Ouro in Mozambique to iSimangaliso Wetland Park in South Africa, following one of the options formerly presented.     

Near-infrared polarization studies of Saturn and Jupiter

Polarization measurements of Jupiter, Saturn, and Saturn's rings from 1 to 3.5 μm are presented. At 1.6 μm on the discs of the two planets, the radially directed limb polarizations observed in the visible undergo, in some cases, a surprising 90° rotation to a tangential direction, particularly on the poles. The only immediate explanation for this effect is double Mie scattering, due to aerosols which must be of the order of a micrometer in size. On Jupiter the patterns are not uniform and are not stable, reflecting variable aerosol concentrations on the two poles. The ring polarization is uniformly negative (E vector parallel to the ecliptic plane) from the visible through 3.5 μm, and is inversely proportional to the albedo. This is as expected from Wolff's model for scattering from rough solid surfaces; but the degree of polarization seems uncommonly high, exceeding 2% at 3.5 μm.     

Observations of Saturn in the 5- to 8-μm spectral region

A spectrum of Saturn obtained from the Kuiper Airborne Observatory exhibits an emission peak at 6.8 μm attributed to ethane, but is otherwise dominated by absorption from 5.3 to 7.2 μm. While the large absorption in this spectral region is consistent with the presence of ammonia gas or ammonia ice, or both, such an explanation is inconsistent with the lack of a major absorption near 3.0 μm.     

A NICMOS-3 based spectrograph for near infrared astronomy

We describe a design for a compact cooled spectrograph which incorporates two cameras and two collimators to achieve high throughput from 0.8 to 2.5m. The spectrograph utilizes multiple NICMOS 3 arrays, specially mounted to minimize their separation in the spectral dimension. This accommodates the broad wavelength range while providing extensive coverage in the spatial dimension.