Refractive optical systems for astronomical instruments using infrared arrays in the 0.8 to 2.5 micron bands

As modern infrared arrays evolve towards larger formats and smaller pixel sizes, their use in instruments requires optics of increasingly higher performance. Refractive systems are attractive for many applications because they can accommodate wide fields of view or fast focal ratios while permitting a compact, unobscured layout. We examine design considerations for lenses which can address the entire near-infrared spectral region of 0.8 to 2.5 m. Achromatization over this broad range is a particular challenge. We discuss a systematic study of candidate materials and combinations of materials having useful chromatic properties, with particular emphasis on alkaline earth halides and metallic oxides. We present an example of a practical design being incorporated into an instrument currently under construction.     

XMM–Newton observations of the black hole X-ray transient XTE J1650–500 in quiescence

We report the result of an XMM–Newton observation of the black hole X-ray transient XTE J1650–500 in quiescence. The source was not detected, and we set upper limits on the 0.5–10 keV luminosity of  0.9–1.0 × 10³¹ erg s⁻¹  (for a newly derived distance of 2.6 kpc). These limits are in line with the quiescent luminosities of black hole X-ray binaries with similar orbital periods (∼7–8 h).     

Nine nations,one ocean: A benchmark appraisal of the South Western Indian Ocean Fisheries Project (2008–2012)

Coastal and island states of the Western Indian Ocean lack scientific and management capacity to draw sustainable benefits from their Exclusive Economic Zones. Declining ecosystem services and unregulated fishing has prompted nine riparian countries to develop a regional framework for capacity building and scientific development towards collective management of shared resources. Supported by the Global Environment Facility (GEF), the Agulhas and Somali Currents large marine ecosystems programme consists of three inter-related modules, supported by different agencies: land-based impacts on the marine environment (UNEP); productivity, ecosystem health and nearshore fisheries (UNDP) and transboundary shared and migrating fisheries resources (World Bank). The latter is the South Western Indian Ocean Fisheries Project (SWIOFP), a 5-year joint data gathering and fisheries assessment initiative. SWIOFP is a prelude to long-term cooperative fisheries management in partnership with the newly established FAO–South Western Indian Ocean Fisheries Commission (SWIOFC). We describe the development of SWIOFP as a model of participatory regional scientific cooperation and collective ocean management.     

Investigation of microbial influences on seafloor gas-hydrate formations

Microbial communities flourish at gas hydrate occurrences in ocean sediments. Studies are reported in this paper on the laboratory production, separation, characterization and hydrate catalysis of biosurfactants from cultures of the Bacillus subtilis bacterium associated with Gulf of Mexico gas-hydrate accumulations. The B. subtilis bacterium from ATCC 21332 species was cultured anaerobically with glucose as carbon-source to produce surfactin, one of the more potent surface active agents known. The surface-active agent was removed from the broth in foam created by bubbling inert gas through the mixture, and biosurfactant was then recovered from the collapsed-foam distilled water solution by acid precipitation and dichloromethane extraction. According to HPLC spectra, five surfactin isomers were identified in the sample of laboratory-generated biosurfactant. Recovered surfactin was then used to perform gas-hydrate formation studies in porous media saturated with the surfactin-water solution. Gas-hydrate induction time and formation rate determinations showed that the anaerobically-produced biosurfactants catalyzed hydrate formation markedly. The tests suggest prolific surfactin production by the B. subtilis bacterium and of other species under prevailing anaerobic conditions around seafloor gas hydrates that promotes hydrate formation and the propensity of the bioproduct to be dispersed in the porous media by natural gas vents.     

Application of the BCR sequential extraction scheme to dredged pond sediments contaminated by Pb–Zn mining: A combined geochemical and mineralogical approach

The modified BCR sequential extraction procedure [Rauret, G., López-Sanchez, J., Sauquillo, A., Rubio, R., Davidson, C., Ure, A., Quevauviller, Ph., 1999. Improvement of the BCR three step sequential extraction procedure prior to certification of new soil and sediment reference materials. J. Environ. Monit. 1, 57–60.] was applied to 4 sediments from a mine tailing pond in La Calamine (East-Belgium). The results showed a very different behaviour of different samples towards the same extraction scheme. In samples with an elevated acid neutralizing capacity, a significant increase in the pH of the extracts was measured after the first two extraction steps. Other artefacts, such as readsorption of metals and precipitation could be deduced by comparing X-ray diffraction patterns after different extraction steps. For example, anglesite was effectively dissolved during the acid extraction step (step 1) but relatively low Pb concentrations were measured in the CH₃COOH extract because of the readsorption of Pb. Mineralogical analysis of the sediments after each extraction step also indicated the incomplete oxidation of sulphides by H₂O₂. Besides a mineralogical analysis, the monitoring of the pH of the extracts and the analysis of major elements (Fe, Ca, Al, Mn) can be helpful for the interpretation of the results of the sequential extraction.The combination of sequential extractions with mineralogical sample investigation provided information on the reactivity and solubility of minerals in the samples. This improved the interpretation, at least within the detection limits of the mineralogical analysis applied. Besides the improved interpretation of the results of the sequential extractions for sediments in which minerals are identified, the information concerning the reactivity of minerals is an important tool to evaluate the risk associated with contaminated sediments.     

Reflux stratabound dolostone and hydrothermal volcanism-associated dolostone: a two-stage dolomitization model (Jurassic, Lebanon)

The Kesrouane Formation, which is characterized by pervasive dolomitization, has a stratigraphic thickness that exceeds 1000 m. It is part of a broad carbonate platform deposited in the Levant region and represents 60% of the Lebanese Jurassic rocks. Two genetically distinct dolostones are recognized within this unit: (1) fine‐to‐medium crystalline non‐planar grey dolostone; and (2) coarse‐crystalline planar beige dolostone. The former is stratabound and of Early Jurassic age (⁸⁷Sr/⁸⁶Sr = 0·707455). This dolostone locally exhi‐bits pseudomorphs of evaporite nodules, pointing towards seepage‐reflux dolomitization by hypersaline‐ to marine‐related fluids. Exposures of the coarse‐crystalline dolostone are associated with regional pre‐Cretaceous faults, along which Late Jurassic volcanics also occur. Sedimentological and diagenetic considerations coupled with microthermometry support a hydrothermal origin for this dolostone, with T_H values of primary inclusions between 50 and 80 °C. The related dolomitizing fluids are mesosaline (3·5–12·0 eq. wt% NaCl), and are believed to result from the mixing of evaporative brines and sea water. Dolomitization is thus believed to have occurred in two stages, whereby fluids invaded the host rocks first by seepage‐reflux, explaining the resulting Early Jurassic stratabound dolostone, and later through fracture flow along the faults associated with the Late Jurassic volcanism, explaining the coarse‐crystalline hydrothemal dolostone.     

Paleoclimate reconstruction in the Levant region from the geochemistry of a Holocene stalagmite from the Jeita cave, Lebanon

Dated oxygen and carbon isotopic profiles from a Holocene stalagmite (11.9–1.1 ka) from the Jeita cave, Lebanon, are compared to variations in crystallographic habit, stalagmite diameter and growth rate. The profiles show generally high δ¹⁸O and δ¹³C values during the late-glacial period, low values during the early Holocene, and again high values after 5.8 ka. On the basis of the good correlation between the morphological and crystallographic aspect of the stalagmite and its isotopic records, as well as the isotopic response of speleothems from central and northern Israel, we relate high δ¹⁸O and δ¹³C values to drier conditions. Between 6.5 and 5.8 ka an increase in isotopic values, a decrease in growth rate and stalagmite diameter suggest a transition from wet conditions in the early Holocene towards drier conditions in the mid-Holocene. The transition occurred in two steps, first a progressive change to drier conditions started at 6.5 ka but was interrupted by a short ( 100 years) return to wetter conditions, followed by an equally rapid (< 200 years) change to drier conditions.     

Determination of the cleat angle distribution of the RECOPOL coal seams, using CT-scans and image analysis on drilling cuttings and coal blocks

Cleat orientation, cleat frequency and cleat angle distribution of deep coal seams are only available by the use of drilling cores and from coal mine samples. Coal drilling cuttings are a cheap and fast alternative to measure cleat angle distributions with the use of image analysis techniques. In this study oriented coal samples and drilling cuttings of the RECOPOL field experiment are compared and used to explain and validate the proposed method. In other words, cleat angle distributions from drilling cuttings are measured by image analysis. The geological framework of the polish coals is described. The image analysis methodologies for the measurement of fracture faces of cuttings and from CT-scan images, derived from these coals, are explained. The results of the methods on the cuttings are compared with cleat orientation distributions from CT-scans and artificial fragments from coal blocks of the same seams. These evaluations show high agreements between the methods. The cleat angle distributions of drilling cuttings of four seams are compared with the cleat orientation distributions of a regional structural geological study. The high correlation in this study shows that cleat angle distributions of coal seams can be used as input parameters for reservoir modelling.