Methane,carbon monoxide and light non-methane hydrocarbon emissions from African savanna burnings during the FOS/DECAFE experiment

Atmospheric samples from savanna burnings were collected in the Ivory Coast during two campaigns in January 1989 and January 1991. About 30 nonmethane hydrocarbons from C₂ to C₆, carbon monoxide, carbon dioxide and methane were measured from the background and also at various distances from the burning. Concentrations in the fire plume reached ppmv levels for C₂-C₄ hydrocarbons, and 5300, 500 and 93 ppmv for CO₂, CO and CH₄ respectively. The excess in the mixing ratios of these gases above their background level is used to derive emission factors relative to CO and CO₂. For the samples collected immediately in the fire plume, a differentiation between high and low combustion efficiency conditions is made by considering the CO/CO₂ ratio. Ethene (C₂H₄), acetylene (C₂H₂), ethane (C₂H₆) and propene (C₃H₆) are the major NMHC produced in the flaming stage, whereas a different pattern with an increasing contribution of alkanes is observed in samples typical of post flaming processes. A strong correlation between methane and carbon monoxide suggests that these compounds are produced during the same stage of the combustion. In samples collected at a distance from the fire and integrated over a period of 30 minutes, the composition is very similar to that of flaming. NMHC/CO₂ is of the order of 0.7%, CH₄/CO₂ of the order of 0.4% and CO/CO₂ of the order of 6.3%. From this study, a global production by African savanna fires is derived: 65 Tg of CO-C, 4.2 Tg of CH₄-C and 6.7 Tg of NMHC-C. Whereas acetylene can be used as a conservative tracer of the fire plumes, only ethene, propene and butenes can be considered in terms of their direct photochemical impact.     

Visualization of multi-scale dynamics of hydrous cold plumes at subduction zones

Recent increases in the computational power of high-performance computing systems have led to a large gap between the high-resolution runs of numerical simulations—typically approaching 50–100 million tracers and 1–5 million grid points in two dimensions—and the modest resolution of 1–2 million pixels for conventional display devices. This technical problem is further compounded by the variety of fields produced by numerical simulations and the limited bandwidth available through the Internet in the course of collaborative ventures. We have developed a visualization system using the paradigm of web-based inquiry to address these mounting problems. We have employed, as a case study, a problem involving two-dimensional multi-scale dynamics of hydrous cold plumes at subduction zones. A Lagrangian marker method, in which the number of markers varies dynamically, is used to delineate the many different fields, such as temperature, viscosity, strain, and chemical composition. We found commercially available software to be insufficient for our visualization needs and so we were driven to develop a new set of tools tailored to high-resolution, multi-aspect, multi-scale simulations, and adaptable to many other applications in which large datasets involving tens of millions of tracers with many different fields are prevalent. In order to address this gap in visualization techniques, we have developed solutions for remote visualization and for local visualization. Our remote visualization solution is a web-based, zoomable image service (WEB-IS) that requires minimal bandwidth while allowing the user to explore our data through time, across many thermo–physical properties, and through different spatial scales. For local visualization, we found it optimal to use bandwidth-intensive, high-resolution display walls for performing parallel visualization in order to best comprehend the causal and temporal relationships between the multiple physical and chemical properties in a simulation.Electronic Supplementary Material Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s10069-004-0017-2     

Field study of macropore flow processes using tension infiltration of a dye tracer in partially saturated soils

Macropores are important preferential pathways for the migration of water and contaminants through the vadose zone. The objective of this study was to examine small‐scale preferential flow processes during infiltration in macroporous, low permeability soils. A series of tension infiltration tests were conducted using Brilliant Blue dye tracer at two field sites in southwestern Ontario, Canada. The maximum applied pressure head was varied for each test and the resulting dye stain patterns and macropore networks were characterized by excavation, mapping, photography, and image analysis. Worm burrows were the dominant macropore type, with average macropore densities exceeding 400 m^?2 and peak densities of more than 750 m^?2 at 30 cm depth at both sites. Flow in macropores became significant at infiltration pressures > ? 3 cm, with corresponding increases in infiltration rate, soil water content variability (spatially and temporally), and depth of dye staining. The results demonstrated clear evidence for partially saturated macropore flow under porewater tension conditions and the associated importance of macropore–matrix interaction in controlling this flow. Field observations of transient infiltration showed that film and rivulet flow along macropores yielded vertical flow velocities exceeding 40 m d^?1. Simple calculations showed that film flow along the walls and corners of irregularly shaped macropores could explain the observed results. Copyright © 2009 John Wiley & Sons, Ltd.     

Upscaling Point Velocity Measurements to Characterize a Glacial Outwash Aquifer

Small‐scale point velocity probe (PVP)‐derived velocities were compared to conventional large‐scale velocity estimates from Darcy calculations and tracer tests, and the possibility of upscaling PVP data to match the other velocity estimates was evaluated. Hydraulic conductivity was estimated from grain‐size data derived from cores, and single‐well response testing or slug tests of onsite wells. Horizontal hydraulic gradients were calculated using 3‐point estimators from all of the wells within an extensive monitoring network, as well as by representing the water table as a single best fit plane through the entire network. Velocities determined from PVP testing were generally consistent in magnitude with those from depth specific data collected from multilevel monitoring locations in the tracer test, and similar in horizontal flow direction to the average hydraulic gradient. However, scaling up velocity estimates based on PVP measurements for comparison with site‐wide Darcy‐based velocities revealed issues that challenge the use of Darcy calculations as a generally applicable standard for comparison. The Darcy calculations were shown to underestimate the groundwater velocities determined both by the PVPs and large‐scale tracer testing, in a depth‐specific sense and as a site‐wide average. Some of this discrepancy is attributable to the selective placement of the PVPs in the aquifer. Nevertheless, this result has important implications for the design of in situ treatment systems. It is concluded that Darcy estimations of velocity should be supplemented with independent assessments for these kinds of applications.