Characterization of Mason Gully (H5): The second recovered fall from the Desert Fireball Network

Mason Gully, the second meteorite recovered using the Desert Fireball Network (DFN), is characterized using petrography, mineralogy, oxygen isotopes, bulk chemistry, and physical properties. Geochemical data are consistent with its classification as an H5 ordinary chondrite. Several properties distinguish it from most other H chondrites. Its 10.7% porosity is predominantly macroscopic, present as intergranular void spaces rather than microscopic cracks. Modal mineralogy (determined via PS‐XRD, element mapping via energy dispersive spectroscopy [EDS], and X‐ray tomography [for sulfide, metal, and porosity volume fractions]) consistently gives an unusually low olivine/orthopyroxene ratio (0.67?0.76 for Mason Gully versus ~1.3 for typical H5 ordinary chondrites). Widespread “silicate darkening” is observed. In addition, it contains a bright green crystalline object at the surface of the recovered stone (diameter ≈ 1.5 mm), which has a tridymite core with minor α‐quartz and a rim of both low‐ and high‐Ca pyroxene. The mineralogy allows the calculation of the temperatures and ?(O₂) characterizing thermal metamorphism on the parent body using both the two‐pyroxene and the olivine‐chromite geo‐oxybarometers. These indicate that MG experienced a peak metamorphic temperature of ~900 °C and had a similar ?(O₂) to Kernouvé (H6) that was buffered by the reaction between olivine, metal, and pyroxene. There is no evidence for shock, consistent with the observed porosity structure. Thus, while Mason Gully has some unique properties, its geochemistry indicates a similar thermal evolution to other H chondrites. The presence of tridymite, while rare, is seen in other OCs and likely exogenous; however, the green object itself may result from metamorphism.     

生物硅的生成与溶解速率的研究-以胶州湾为例

营养盐的含量与元素间的比值直接控制着生态系统的生产力和浮游植物的种类组成.近岸海区硅藻可占初级生产的75%,但其生长速率受Si(OH)4含量的限制.胶州湾浮游植物的物种组成以硅藻为主.用29Si同位素示踪培养方法,采用四极杆质谱同位素稀释技术同时测定了胶州湾硅的生成速率与溶解速率.胶州湾生物硅(BSi)的含量为0.90～1.14 μmol/L,岩成硅(LSi)的含量为46.3～52.3 μmol/L.岩成硅是生物硅的约50倍.胶州湾BSi的含量处于世界近岸海区的低值范围,LSi的含量与LSi/BSi的比值均处于高值区.BSi的绝对生成速率为4～6 nmol/L*d,比生成速率为6～17/d.BSi的绝对溶解速率为<9 nmol/d,比溶解速率为<23/d.进一步开展胶州湾不同季节水体中BSi的生成速率与溶解速率的研究,是深入认识海湾浮游植物生长限制及其资源可持续利用的基础.     

Significance of enhanced infiltration due to groundwater extraction on the disappearance of a headwater lagoon system: Toluca Basin, Mexico

Mexico City relies significantly on groundwater resources drawn from the Sistema Lerma well field located in the Toluca Basin, Mexico. Enhanced infiltration caused by groundwater extraction is suspected to be both a prime factor in the disappearance of a lagoon system at the Toluca Basin and a potential risk to long-term groundwater quality. A combined approach of field investigation and numerical modeling was adopted to assess the groundwater-surface water interactions within the lagoon system. Potentiometric data indicate that current downward vertical hydraulic gradients below the lagoon and surrounding wetland area are extremely low suggesting very slow infiltration rates. Geochemical and isotope data from surface water and groundwater sampling also indicate that very little surface water infiltration has occurred. Numerical simulations demonstrate that enhanced surface water infiltration is unlikely to be the primary cause in the significant reduction in size of the lagoon system. Other factors such as modifications to the surface water drainage system and capture of spring flow from the surrounding mountainous regions are likely more significant. Simulations also suggest that contaminants originating in the lagoon system are currently entering nearby production wells although the total contaminant mass flux to the wells is still very low and significantly diluted.

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Resumen La Ciudad de México depende significativamente de los recursos de aguas subterráneas obtenidos del campo de pozos Sistema Lerma ubicado en la Cuenca Toluca, oeste de la Cuenca de México. Se sospecha que la infiltración estimulada causada por extracción intensiva de aguas subterráneas es un factor principal en la desaparición de un sistema de lagunas en la cabeceras del Río Lerma en el centro de México y un riesgo potencial para la calidad de aguas subterráneas a largo plazo en la región. Se adoptó un enfoque combinado de investigación de campo y modelizado numérico para evaluar las interacciones de agua superficial-agua subterránea dentro del sistema de lagunas. Datos potenciométricos indican que los gradientes hidráulicos verticales descendentes actuales, ubicados por debajo de la laguna y vecina área de humedales, son extremadamente bajos sugiriendo ritmos de infiltración muy lentos. Datos geoquímicos e isotópicos provenientes del muestreo de agua superficial y subterránea también indican que ha ocurrido muy poca infiltración de agua superficial. Las simulaciones numéricas demuestran cuantitativamente que no es probable que la infiltración estimulada de agua superficial sea la causa principal en la reducción significativa del tamaño del sistema de lagunas en la cabecera. Otros factores tal como modificaciones al sistema superficial de drenaje de agua y captura de flujo de manantial en las regiones montañosas vecinas son probablemente más significativos. Las simulaciones también sugieren que los contaminantes que se originan en el sistema de lagunas están actualmente ingresando a pozos de producción cercanos aunque el flujo de masa contaminante total a los pozos es aún muy bajo y diluido significativamente en los volúmenes grandes de extracción. La magnitud de la amenaza a largo plazo a la calidad del agua subterránea en los pozos de producción Sistema Lerma proveniente de contaminantes infiltrados es una preocupación y amerita estudios futuros.

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Résumé La Cité de Mexico dépend significativement des ressources en eau souterraine pompées au site de captages de Sistema Lerma, dans le Bassin de Toluca, à lOuest du Bassin de Mexico. Laugmentation de linfiltration, causée par lextraction extensive des eaux souterraines, est suspectée dêtre à la fois un facteur primaire de la disparition dun système de lagons en amont de la rivière Lerma au centre de Mexico, et un risque potentiel à long-terme pour la qualité de leau souterraine dans la région. Uen approche combinée détudes de terrain et de modélisation numérique a été adoptée pour estimer les interactions entre les eaux de surface et les eaux souterraines, au sein du système de lagons. Les données potentiométriques indiquent que les gradients hydrauliques verticaux descendants sont très bas au niveau des lagons, ce qui suppose un taux dinfiltration faible. Les données géochimiques et isotopiques provenant des eaux de surface et souterraines, indiquent également que peu deau de surface sinfiltrent. La simulation numérique démontre quantitativement que laugmentation de linfiltration des eaux de surface nest probablement pas la première cause de réduction des lagons. Dautres facteurs, tels que les modifications du drainage des eaux de surface, laménagement en captage des sources situées aux pieds des montagnes environnantes, sont probablement plus importants. Les simulations suggèrent également que les contaminants provenant des lagons se retrouvent également dans les captages les plus proches, bien que le flux total de contaminants entrant dans les captages reste faible. Les volumes dextraction étant très important ils diluent effectivement les contaminants. Les effets à long-terme de lextraction critique au niveau des forages de Sistema Lerma et de la dégradation de la qualité des eaux souterraines par les contaminants, nécessite une grande attention pour le futur.

     

Levels and spatial distribution of polycyclic aromatic hydrocarbons (PAHs) in sediments from Lenga Estuary, central Chile

The Lenga Estuary is a small brackish wetland located southwest of San Vicente Bay, Region VIII, Chile. Surface sediment from nine sites in the estuary were analysed for PAHs and compared to Sediment Quality Guidelines (SQG). Sediment samples were freeze dried and soxhlet extracted for 16 h using DCM. Identification and quantification was carried out by HPLC. Organic carbon was also determined. Results showed total PAH concentrations ranged from 290 to 6118 (2025 ± 1975) ng g⁻¹ d.w. (2025 ± 1975). Results for organic carbon percentages ranged from 1% to 7%. Statistical analysis showed a significant positive correlation (Pearson test) between organic carbon percentage PAHs. Comparison of contaminant levels and international Sediment Quality Guidelines (SQG) (ERL and ER) suggested that sediment of the Lenga estuary did not show any ecotoxicologial risk for benthic organisms where high levels of PAHs were detected. Monitoring of this and other contaminants is recommended in Chile.     

WEB-IS (integrated system): an overall view

WEB-IS, Web-based Integrated System, allows remote, interactive visualization of large-scale 3-D data over the Internet, along with data analysis and data mining. In this paper, we discuss the overall structure of WEB-IS. Up until now we have developed three sub-modules geared towards geophysical problems. WEB-IS1 allows geoscientists to navigate through their 3-D geophysical data, such as seismic structures or numerical simulations, and interactively analyze the statistics or apply data-mining techniques, such as cluster analysis. WEB-IS2 lets a user control Amira (a powerful 3-D visualization package) remotely and analyze, render and view large datasets across the Internet. WEB-IS3 is an imaging service that enables the user to control the scale of features to view through interactive zooming. In the near future, we propose to integrate the three components together through a middleware framework called NaradaBrokering (iNtegrated Asynchronous Real-time Adaptive Distributed Architecture, a distributed messaging infrastructure that can be used to intelligently route data between the originators and registered consumers) without regard for time or location. As a result, WEB-IS will improve its scalability and acquire properties of fault-tolerance. WEB-IS uses a combination of Java, C++, and through the use of NaradaBrokering will seamlessly integrate the server-side processing and user interaction utilities on the client. The server takes care of the processor intensive tasks, such as visualization and data mining, and sends either the resulting bitmap image or statistical results to the middleware across the Internet for viewing. WEB-IS is an easy-to-use service, which will eventually help geoscientists collaborate from different sites in a natural manner. It will be very useful in the next 10 years because of the increasing number of space missions and geophysical campaigns.     

Measurements of Volatile Organic Compounds (VOC) During POPCORN 1994: Applying a New On-Line GC–MS-Technique

Atmospheric concentrations of ca. 250 C6–C15 hydrocarb on and C4–C12 oxygenated volatile organic compounds (VOC) including alkanes, benzene and alkyl benzenes, monoterpenes and aldehydes were measured in August 1994 during the POPCORN campaign (POPCORN = Photo-Oxidant formation by Plant emitted Compounds and OH Radicals in North-Eastern Germany). About 80 substances together contributed 90% of the atmospheric carbon in this range of molecular weight. During this field campaign VOC-emissions from several crop and tree species and the ambient concentrations of CO, C2–C7 non-methane hydrocarbons (NMHC), C1 and C2 aldehydes, nitrogen oxides, ozone and hydroxyl-radicals (OH) were also measured. These data were used to interpret the VOC measurements presented here. The on-line GC–MS used for the VOC measurements combines adsorptive sampling with thermal desorption and GC–MS analysis in an automated system. Internal standards were used to quantify the measurements. Ozone was destroyed prior to the sample preconcentration through the gas phase reaction with NO. Aromatic compounds like benzene, toluene and xylenes were the most abundant compound class among the measured substances, -pinene and 3-carene, most probably originating from pineforests ca. 1 km away from the measuring site, were the most abundant monoterpenes. The highest mixing ratios of most compounds were measured in nights with strong inversion situations. The toluene mixing ratios then reached 630 pptv; -pinene mixing ratios went up to 430 pptv. The median of all toluene and -pinene measurements during the campaign was 125 pptv or 22 pptv, respectively. These values are on the lower end of ambient measurements reported for continental sites. In most samples also n-pentanal, n-hexananl, n-nonanal and n-undecanal were present. Median mixing ratios were 9, 16, 14 and 8 pptv, respectively. Emission studies indicate that these highly reactive compounds are most probably emitted from maize. It is shown by a simple first order approach that the potential for ozone formation during the POPCORN campaign was roughly equal for anthropogenic and biogenic VOC. From measured concentrations of ozone, OH-radicals, methane, CO, C2–C15 nonmethane hydrocarbons (NMHC) and C5–C11 aldehydes a photochemical production of ozone in the order of 3.5 ppb/h can be estimated. Apart from formaldehyde and acetaldehyde, which are at least partly products of VOC oxidation, the substance group with the largest contribution to the VOC turnover are the monoterpenes. They contribute ca. 30%. However, the mechanism of terpene oxidation is very complex and presently only partly understood. Thus the actual contribution of monoterpenes to ozone formation is very uncertain. Other measured compound classes such as light alkenes, alkanes, aromatics, and C5–C11 aldehydes contribute each between 10% and 15% to ozone formation. The measuring site was not influenced directly from strong biogenic or anthropogenic sources, and the results obtained during the POPCORN campaign can be regarded as a typical picture of a remote rural central European environment.