Early diagenetic influences on iron transformations in a freshwater lake sediment

Iron transformations in a calcium carbonate rich fresh-water sediment were studied by analyzing the relevant constituents of both interstitial water and solid matter. Analysis of interstitial water shows that the observed redox sequence NO⁻₃/NH⁺₄, MnO₂/Mn(II), FeOOH/Fe(II), SO²⁻₄/S(−II) is roughly in agreement with that predicted by the Gibbs Free Energy for the corresponding reactions. In contrast to marine sediments, these redox transitions occur in the uppermost sediments, i.e., at depths of 0–4 cm.

Deeper in the sedimentary sequence, the depth profile for dissolved iron exhibits a steady non-linear increase up to 400 μmol dm⁻³. In this anoxic zone, according to thermodynamic predictions, iron (II)-minerals such as iron sulfide, siderite, and vivianite should precipitate while Fe(III) oxides should be completely dissolved. However, microscopic analysis showed that Fe(III) oxides were present throughout the studied sediment. Furthermore, scanning electron microscope/energy dispersive spectroscopy analysis suggests the presence of iron sulfide could be verified but not that of siderite or vivianite. These observations indicate kinetic control of iron transformations.

We have investigated the importance of kinetic control of iron distribution in anoxic sediments using a diagenetic model for dissolved iron(II). A rough estimate of time scales for dissolution and precipitation rates was made by imposing limiting boundary conditions. Using the calculated rate constant, we established that more than 1000 years would be required for the complete dissolution of Fe(III) oxides, which is agreement with our observations and experimental data from the literature. Calculated precipitation rates of Fe(II) for a given mineral phase such as siderite yield a maximum value of 3 μg_(FeCO3) g⁻¹_{(dry sediment)} yr⁻¹. Such low rates would explain the absence of siderite and vivianite.

Finally, it can be inferred from the Mn_T/Fe_T ratio in the sediments that this ratio depends on the redox conditions of the sediment-water interface at the time of deposition. Thus, this ratio can be used as “paleo-redox indicator” in lacustrine sediments.     

Search for finite dimensional attractors in atmospheric turbulence

The question is investigated whether the dynamics of turbulent wind fields in the atmospheric boundary layer can be satisfactorily described by a low-dimensional deterministic system. Special emphasis is laid on the detection of a possibly existing, underlying strange attractor. Fast response wind measurements of an ultrasonic anemometer with a sampling rate of 21 Hz were carried out over periods of several days in the near surface boundary layer. The correlation dimension of the resulting time series, several million data points long, is estimated by means of the Grassberger-Procaccia algorithm. No sign of a low dimensional attractor can be detected. By comparison with different types of random noise, the existence of an attractor with dimension lower than six can be excluded in the present data sets.     

Windstorm of the eighteenth century in the Czech Lands: course,extent, impacts

Theoretical and Applied Climatology - This paper addresses the course, extent, and impacts of a windstorm that occurred on 20–21 December 1740, in the Czech Lands. The analysis is based on...     

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Determination of the deformation properties of bedrock under turbine foundations

Summary This paper presents an improved investigation technique for in-situ determination of the deformation properties of rock masses, which are important parameters in the desing of foundations. This technique permits testing on a circular, one square metre area of the rock. In order to obtain reproducible loading conditions when testing, an equipment was introduced that gave almost uniformly distributed loading of the rock surface. This device is described in this paper. Displacement measurements are made in a central measuring hole, since a point of zero displacement, located equidistant between the loaded surface and the upward-pointing anchoring forces, offered a suitable reference point. In this way, the measuring device is also well protected against disturbing variations in temperature. During cyclic loading and unloading, charateristic load/deflection graphs are recorded, which directly demonstrate the deformation properties of the rock, such as the modulus of deformation at different loads, linearity deviation from linearity, as well as hysteresis effects and creep. It is clear that the results of the investigation apply only to the measuring point—the place at which the investigation was carried out. The properties of the rock nearby may vary considerably. The procedure for using this method of investigation for testing improvement measures for turbine foundations is shown in some examples.     

The Staffelegg Formation: a new stratigraphic scheme for the Early Jurassic of northern Switzerland

The deposits of the Early Jurassic in northern Switzerland accumulated in the relatively slowly subsiding transition zone between the southwestern part of the Swabian basin and the eastern part of the Paris basin under fully marine conditions. Terrigenous fine-grained deposits dominate, but calcarenitic and phosphorit-rich strata are intercalated. The total thickness varies between 25 and 50 m. In the eastern and central parts of N Switzerland, sediments Sinemurian in age constitute about 90% of the total thickness. To the West, however, in the Mont Terri area, Pliensbachian and Toarcian deposits form 70% of the total thickness. Stratigraphic gaps occur on a local to regional scale throughout N Switzerland. Such hiatus comprise a subzone to a stage in time. With respect to lithology and fossil content, the Early Jurassic deposits in northern Switzerland are similar to those in SW Germany. Nonetheless, an exact stratigraphic correlation is hardly possible, particulary in the southern and southwestern Folded Jura where distinct facies changes occur over short distances. Revised existing and new litho- and biostratigraphic data form the base to refine the stratigraphic subdivision of the deposits that have been informally called “Lias”. The name Staffelegg Formation is suggested and defined as the mapping unit for the Early Jurassic. The Staffelegg Formation is introduced for Early Jurassic sediments in northern Switzerland between the Doubs River and Mt. Weissenstein in the west and the Randen Hills located north of the city of Schaffhausen in the east. The Staffelegg Formation starts within the Planorbis zone of the Hettangian. The upper boundary to the overlying Aalenian Opalinus-Ton is diachronous. The lithostratigraphic names previously in use have been replaced by new ones, in accordance within the rules of lithostratigraphic nomenclature. The Staffelegg Formation comprises 11 members and 9 beds. Several of these beds are important correlation horizons in terms of allostratigraphy. Some of them correspond to strata or erosional unconformities encountered in the Swabian realm, some of them can be correlated with strata in the Paris basin. The facies transition to the Paris basin is expressed by introduction of a corresponding lithostratigraphic unit.     

Centimeter-Level Positioning of a U. S. Coast Guard Buoy Tender

With the availability of high-accuracy, differential global positioning system (GPS) results in real-time, there is a new opportunity to use GPS to accurately measure a marine vessel's dynamic draft (settlement and squat) and 3D attitude (roll, pitch, and heading). The National Geodetic Survey (NGS) and the Coast Survey (CS), offices of the National Ocean Service (NOS), National Oceanic and Atmospheric Administration (NOAA), propose to transfer this technology to the shipping industry. The overall goal of this project is to provide the position of a vessel's keel in real time to within 10 cm (about 4 inches) relative to the bottom of the shipping channel. In support of this phase of the project, there were three meetings hosted by the Port of Oakland, California and NOS to discuss the real-time positioning of vessels project. On December 3 and 4, 1996, CS, NGS, Trimble Navigation Ltd., and the U. S. Coast Guard (USCG) performed GPS tests on a USCG buoy-tender ship. GPS data were used to compute the vessel's dynamic draft and 3D attitude. During the test, five receivers continually collected data; one receiver was located at a base station on the USCG pier on Yerba Buena Island, and four were on the ship: two on the stern and two on the bow. CS installed a TSS-335B vertical reference unit (to measure heave, pitch, and roll) in the engine room of the ship. NOS processed the GPS data and computed the vessel's dynamic draft and 3D attitude. The results indicate that the linear equivalent to the vessel's dynamic draft and 3D attitude were accurate to the 10-cm level using GPS. It was also demonstrated how a ship can be used to measure local water-level changes and actual water-level values everywhere it travels. ? 1999 John Wiley & Sons, Inc.