Lake ecosystem responses to catchment disturbance and airborne pollution: an 800-year perspective in southern Sweden

Sediment sequences spanning the last 800 years from two small lakes in the south Swedish uplands were explored for assessment of effects of changing human population, local land-use practices and airborne pollution on lake-ecosystem functioning and resilience. Variations in nutrient cycling and deposition of lithogenic elements were studied, using a multi-proxy stratigraphic approach. Carbon and nitrogen elemental and isotopic analyses were applied in combination with records of hydrocarbons (n-alkanes) to investigate the sources and depositional conditions of sediment organic matter. Changes in fluvial and airborne delivery of inorganic matter were based on X-ray fluorescence measurements. The results reveal that population growth and related increases in land-use pressure had a major impact on catchment erosion and input of terrestrial organic matter to the lakes from the 1500s to the end of the 1800s. Evidence also exists of a brief period of catchment disturbance at ca. 1200–1300, followed by recovery, likely connected to the Black Death pandemic. At ca. 1900 synchronous shifts in most of the proxy records suggest a marked change in external forcing common to the two lakes related to a major decrease in population density and the introduction of modern forestry following the industrial revolution. Interestingly, the two sediment records exhibit generally coherent trends in C/N ratio, organic C content and δ¹³C, both before and after 1900, indicating broadly similar sensitivities of the lake ecosystems to human impact. In contrast, deviating trends in total N content, δ¹⁵N and lithogenic element concentrations (K, Ti, Rb and Zr) reflect site-specific responses to local disturbances during the last century due to different nutrient conditions and catchment properties. Our companion sediment records highlight the importance of understanding long-term human impact on watersheds and demonstrate how regional versus local forcing of lake ecosystems, as well as site-specific responses related to catchment characteristics can be reconstructed.     

Growth of multilayered polycrystalline reaction rims in the MgO–SiO<Subscript>2</Subscript> system,part II: modelling

Part I of this contribution (Gardés et al. in Contrib Mineral Petrol, 2010) reported time- and temperature-dependent experimental growth of polycrystalline forsterite-enstatite double layers between single crystals of periclase and quartz, and enstatite single layers between forsterite and quartz. Both double and single layers displayed growth rates decreasing with time and pronounced grain coarsening. Here, a model is presented for the growth of the layers that couples grain boundary diffusion and grain coarsening to interpret the drop of the growth rates. It results that the growth of the layers is such that (Δx)² ∝ t ^1−1/n , where Δx is the layer thickness and n the grain coarsening exponent, as experimentally observed. It is shown that component transport occurs mainly by grain boundary diffusion and that the contribution of volume diffusion is negligible. Assuming a value of 1 nm for the effective grain boundary width, the following Arrhenius laws for MgO grain boundary diffusion are derived: log D _gb,0^Fo (m²/s) = −2.71 ± 1.03 and E _gb^Fo = 329 ± 30 kJ/mol in forsterite and log D _gb,0^En (m²/s) = 0.13 ± 1.31 and E _gb^En = 417 ± 38 kJ/mol in enstatite. The different activation energies are responsible for the changes in the enstatite/forsterite thickness ratio with varying temperature. We show that significant biases are introduced if grain boundary diffusion-controlled rim growth is modelled assuming constant bulk diffusivities so that differences in activation energies of more than 100 kJ/mol may arise. It is thus important to consider grain coarsening when modelling layered reaction zones because they are usually polycrystalline and controlled by grain boundary transport.     

Les minéralisations stratiformes à F-Ba de Hammam Zriba,Jebel Guébli (Tunisie nord orientale): l'apport des études d'inclusions fluides à la modélisation génétique

Résumé Le gîte de H. Zriba-J. Guebli (réserves: 5 millions de tonnes à 15–35% CaF₂) est constitué pour l'essentiel d'amas stratoïdes encaissés dans des formations phosphatifères argileuses et carbonatées, d'âge Campanien inférieur. Quatre formations minéralisées (Mo, Fr, F₂ et F₃) ont été distinguées. La plus ancienne (formation Mo) ne contient pas de fluorine; elle est à dominante quartzeuse ou barytique avec quelques sulfures. Le minerai à fluorine rubanée (formation F₁) est le plus important sous l'angle économique. Trois types d'inclusions fluides ont été observés dans la fluorine: 1) d'abondantes inclusions aqueuses, 2) de rares inclusions gazeuses et 3) de fréquentes inclusions à hydrocarbures liquides jaunes, fluorescentes en éclairage U.V. Les études microthermométriques montrent une augmentation des températures d'homogénéisation (100 à 130°C dans la fluorine F₁, 150–185°C dans la fluorine F₃) avec augmentation parallèle de la salinité des solutions piégées. On propose un modèle de mise en place de la fluorine par voie épigénétique à partir de solutions semblables aux eaux de formation des champs pétrolifères, suivi par des remaniements liés à des circulations hydrothermales récentes.

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In the H. Zriba-J. Guebli mine (5 millions tons of ore with 15%–35% CaF₂) the ore deposits are mostly stratiform bodies hosted by lower-Campanian clay-carbonate sediments with significant phosphate contents. Four successive ore formations are apparently fluorite-free and either quartz-rich or barite-rich with minor amounts of sulfides. The fluorine rubannée (formation F₁) is the main economic ore. Three major fluid inclusions types have been observed in fluorite: (1) abundant aqueous inclusions, (2) rare gas inclusions, and (3) usually yellow oil-bearing inclusions with intense UV fluorescence. In microthermometric investigations on primary aqueous inclusions a general increase in the homogenization temperature from about 100°C to 130°C in fluorite F₁ up to 150°–185°C in fluorite F₃ with a simultaneous increase in salinity was observed. Finally, fluorite crystallized epigenetically in formation-water-type brines; the last geodic filling by fluorite F₃ is tentatively related to Miocene hydrothermal circulation.

     

Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.     

Thermal radiation from cloudless skies in Granada

Summary Data on thermal radiation from clear skies obtained at Granada from May to November 1983 were utilized to carry out a detailed comparison between measured and calculated values of longwave radiation with several analytical and empirical equations. The goal of this work is to check the aplicability of these equations to Granada conditions. The results obtained for all the equations are quite satisfactory. Nevertheless, Idso's formula significantly overestimates our experimental results, probably as a consequence of the differences in atmospheric dust conditions between our test area and the location for which that equation was originally derived. A reduction in the independent coefficient, in accordance with previous results of other authors, provides a better fit to our data set and clearly shows the climatological dependence of the constants in the estimation equations.

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Zusammenfassung Die von Mai bis November 1983 in Granada gesammelten Daten über Wärmestrahlung bei klarem Himmel wurden dazu verwendet, um einen detaillierten Vergleich zwischen gemessenen und errechneten Werten der langwelligen Strahlung aus verschiedenen analytischen und empirischen Gleichungen durchzuführen. Das Ziel dieser Arbeit ist es, die Anwendbarkeit dieser Gleichungen auf die Verhältnisse in Granada zu überprüfen. Die gewonnenen Ergebnisse sind für alle diese Gleichungen ganz zufriedenstellend. Idsos Formel überschätzt jedoch deutlich unsere experimentellen Ergebnisse, möglicherweise als Folge der unterschiedlichen atmosphärischen Staubbedingungen in unserem Testgebiet und dem Standort, für den die Gleichung ursprünglich abgeleitet wurde. Eine Reduktion des unabhängigen Koeffizienten, in Übereinstimmung mit früheren Ergebnissen anderer Autoren, bietet eine bessere Anpassung an unseren Datensatz und zeigt deutlich die klimatologische Abhängigkeit der Konstanten in Schätzungsgleichungen.

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With 3 Figures     

The two-step shape and timing of the last deglaciation in Antarctica

The two-step character of the last deglaciation is well recognized in Western Europe, in Greenland and in the North Atlantic. For example, in Greenland, a gradual temperature decrease started at the Bölling (B) around 14.5 ky BP, spanned through the Alleröd (A) and was followed by the cold Younger Dryas (YD) event which terminated abruptly around 11.5 ky BP. Recent results suggest that this BA/YD sequence may have extended throughout all the Northern Hemisphere but the evidence of a late transition cooling is still poor for the Southern Hemisphere. Here we present a detailed isotopic record analyzed in a new ice core drilled at Dome B in East Antarctica that fully demonstrates the existence of an Antarctic cold reversal (ACR). These results suggest that the two-step shape of the last deglaciation has a worldwide character but they also point to noticeable interhemispheric differences. Thus, the coldest part of the ACR, which shows a temperature drop about three times weaker than that recorded during the YD in Greenland, may have preceded the YD. Antarctica did not experienced abrupt changes and the two warming periods started there before they started in Greenland. The links between Southern and Northern Hemisphere climates throughout this period are discussed in the light of additional information derived from the Antarctic dust record.     

Grain-size-sensitive flow and shear-stress enhancement at the brittle–ductile transition of the continental crust

Localized shear zones along low-angle normal faults have been identified in regions of extension at the brittle-ductile transition of the continental crust. The possibility of the strain localizing at a depth of 10 km is interpreted here as a consequence of an increase in the equivalent shear stress applied to the flow of the lower crust. This enhancement of the flow stress is seen as a prerequisite for the triggering of brittle deformation mechanisms leading to strain localization. The lower crust rheology used to examine this stress increase is strain-rate, temperature and grain-size dependent, due to the coupling of dislocation and diffusion creep. The model structure proposed consists of a top layer, the upper crust, gliding rigidly above a bottom layer, the lower crust, which deforms in simple shear. During a short time interval (1400 years), the equivalent shear stress is found to increase by a factor of up to 3 (67 MPa for anorthite and 17 MPa for quartz). For anorthite, this stress could explain the activation of a Mohr-Coulomb failure with a friction coefficient of 0.2, which is reasonable at the depth of 10 km. Dislocation creep is activated during a rapid change in the prescribed velocity, whereas diffusion creep dominates if the velocity is held constant, highlighting the importance of grain-size sensitivity for lower crustal rheology.     

Dissolved noble gases in marine waters

The supersaturation of neon in southeastern Pacific deep sea water is unexpectedly high, 6.6% on the average, while surface waters have values about a factor of two lower. A comparison of neon and argon concentrations indicates the presence of injected air in the deep water. The results from surface samples cannot be reconciled with air injection.     

Chemical composition of Luna 20 soil and rock fragments

Abundances of 22 elements, including 9 rare earth elements (REE), have been determined by ‘monostandard’ instrumental neutron activation analysis of samples from the Luna 20 soil and in 6 rock fragments, including a crystalline rock of highland origin, a breccia of similar composition, a glass and a feldspar grain. The soil appears to have been contaminated with W and Mo. The REE content of the soil is very low, being close to 2.3 times below the level in the Luna 16 soil. Sampling errors, for most elements, are negligible in the case of analyses performed on one or several tens of mg of soil, but they become significant on crystalline rock fragments in the 1–2 mg range.