Zur Anwendung der Kathodolumineszenz in der Karbonatpetrographie

Mn-activated cathodoluminescence can be used in several fields of carbonate petrography. It may, for instance, be possible to recognize

1. cement sequences and their correlation (Tab. 1, Figs. 1, 2, 4; Tab. 2, Fig. 1)
2. growth fabrics of skeletons (Tab. 2, Figs. 2, 3, 4; Tab. 3, Figs. 1, 2)
3. dolomitisation processes and problems (Tab. 1, Figs. 1, 2; Tab. 4, Fig. 2)
4. transformation paths from Mg-calcite to calcite and from aragonite to calcite (Tab. 2, Fig. 1; Tab. 3, Figs. 3, 4; Tab. 4, Fig. 1)
5. growth structures in certain types of ooids (Tab. 1, Fig. 4; Tab. 3, Fig. 3; Tab. 4, Fig. 1)
6. reworked skeletal particles (Tab. 3, Fig. 4)
7. phantom grains and fossil-outlines in a micro- or macrocrystalline groundmass (Tab. 4, Figs. 2, 3)
8. healed fissures crossing micro- or macrocrystalline carbonate rocks (Tab. 4, Fig. 4).

These are, however, no general luminescence criteria indicating the depositional environment. Luminescence of calcite and dolomite requires 20–40 ppm Mn, with the equipments used in this study. Aragonite is not yet investigated systematically. Zonal luminescence in carbonate cements may indicate changes of the chemical composition of the aquifer and may be used for “cement stratigraphy”. In skeletons it rather indicates physiological changes. While aragonitic skeletons lose their luminescence Zonation during replacement by calcite, Mg-calcite skeletons may keep parts of it, because their replacement preserves the original crystal fabric. Blotchy luminescence developes in Mg-calcitic particles during their adjustment to lower Mg-calcites by dissolution-precipitation processes in solutions with changing Mn/Fe-ratios.     

Concepts for reference frames in geodesy and geodynamics: The reference directions

Modern high accuracy measurements of the non-rigid earth are to be referred to four-dimensional, i.e., time- and space-dependent reference frames. Geodynamic phenomena derived from these measurements are to be described in a terrestrial reference frame in which both space- and time-like variations can be monitored. Existing conventional terrestrial reference frames (e.g. CIO, BIH) are no longer suitable for such purposes. The ultimate goal of this study is the establishment of a reference frame, moving with the earth in some average sense, in which the geometric and dynamic behavior of the earth can be monitored, and whose motion with respect to inertial space can also be determined. The study is conducted in several parts. In the first part problems related to reference directions are investigated, while subsequent parts deal with positions, i.e., with reference origins and scale. Only the first part is treated in this paper. The approach is based on the fact that reference directions at an observation point on the earth surface are defined by fundamental vectors (gravity, earth rotation, etc.), both space and time variant. These reference directions are interrelated by angular parameters, also derived from the fundamental vectors. The interrelationships between these space- and time-variant angular parameters are illustrated in a commutative diagram, tower of triads, which makes the derivation of the various relationships convenient. In order to determine the above parameters from observations using least squares techniques, a model tower of triads is also presented to allow the formation of linear observation equations. Although the model tower is also space and time variant, its variations are described by adopted parameters representing our current knowledge of the earth.     

Compressional and shear wave velocities at high temperature and confining pressure in basalts from the Faeroe Islands

Compressional (V_P) and shear (V_S) wave velocities and the dependent elastic constants have been determined by the pulse transmission technique to 6 kb confining pressure at room temperature and to 700° C at 6 kb confining pressure for eleven basalts from the Faeroe Islands. The Faeroe basalts investigated are tholeiitic, they clearly lie within the tholeiitic area, and display a pronounced trend of iron enrichment from rocks with an M/M + F ratio of 0.5 to rocks with an M/M + F ratio of about 0.25. The mean V_P and V_S for eleven specimens are 5.57 km/sec and 3.18 km/sec, respectively. Velocity—density relations for the basalts might be more appropriately described by non-linear solutions than by linear relations commonly used for basalts. In general, V_P and V_S remain unaffected by temperature up to 300° C. At higher temperature the changes in wave velocities are influenced by metamorphic processes and are, therefore, somewhat erratic. In zeolite-bearing specimens an abrupt velocity decrease around 350°C is observed, which correlates well with a drastic compaction of bulk volume. Additional experiments on cold-pressed zeolite powder clearly indicate that the sharp velocity decrease in the basalts is related to dehydration of zeolite minerals. Partial-melting processes, which occur within vesicules and pore-spaces at distinctly higher temperatures have no additional effect on wave velocity. Comparison with field data reveals that, without exception, the velocities at 0.5 kb confining pressure display the same range that has been commonly noted in refraction data for Layer 2. There are no significant differences in wave velocities and the pressure—temperature dependence in samples recovered from the upper, middle, and lower basalt series in the Faeroe Islands.     

On the origin of compressional intraplate stresses in South America

Intraplate stresses in middle South America are not negligible. We report thrust-faulting mechanisms for five intraplate earthquakes, which indicate a dominant horizontal deviatoric compressional stress oriented in a NW-SE direction. We conclude that this state of stress is due to forces connected with spreading on the Mid Atlantic Ridge and resistive forces exerted by the Caribbean plate to the north and the Nazca plate to the west. The existence and nature of the resistive forces is inferred from earthquake mechanisms and geological evidence presented in other studies. All the available intraplate stress data for Nazca and South America indicate that both plates are under deviatoric compression generated at spreading centers. The absence of tensional earthquake focal mechanisms, particularly in the Nazca plate near the trench, suggests that the forces associated with the gravitational sinking of subducted lithosphere are locally compensated. We present a simple numerical calculation of a non-subducting plate to show how the compressional deviatoric stresses in middle South America can be used to estimate an upper bound of about 10²¹ P for the viscosity of the mantle.     

Impaktite von Köfels,Tirol

Zusammenfassung Die glasführenden Gesteine von Köfels, Tirol, wurden petrologisch untersucht. Sowohl Elektronenstrahl-Mikrosondenanalysen der Phasen als auch chemische Pauschalanalysen einiger Gesteine werden angegeben.Das Vorhandensein von Cr- und Si-führendem Nickeleisen, Lechatelierit, Kalifeldspatglas, Fe-reichen Gläsern, Olivin sowie die kräftigen Inhomogenitäten in der Glasphase sind nur durch eine Impakt-Entstehung dieser Gesteine erklärbar.

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Impactites from Koefels, Tyrol, Austria

Summary The glass-bearing rocks from Koefels, Tyrol, have been investigated petrologically. Electron-microprobe Analyses of the phases and chemical bulk analyses of some rocks are presented.The presence of Cr- and Si-bearing nickel-iron, lechatelierite, potassium-feldspar-glass, olivine, as well as the pronounced inhomogenities of the glasses strongly suggest an impact origin of these rocks.

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Mit 7 Abbildungen     

Solar-Blind Diamond Detectors for Lyra, the Solar VUV Radiometer on Board Proba II

Fabrication, packaging and experimental results on the calibration of metal-semiconductor-metal (MSM) photodetectors made on diamond are reported. LYRA (Lyman- RAdiometer onboard PROBA-2) will use diamond detectors for the first time in space for a solar physics instrument. A set of measurement campaigns was designed to obtain the XUV-to-VIS responsivity of the devices and other characterizations. The measurements of responsivity in EUV and VUV spectral ranges (40–240 nm) have been carried out by the Physkalisch-Technische Bundesanstalt (PTB) in Germany at the electron storage ring BESSY II. The longer wavelength range from 210 to 1127 nm was measured with monochromatic light by using a Xe-lamp at IMO-IMOMEC. The diamond detectors exhibit a photoresponse which lie in the 35–65 mA/W range at 200 nm (corresponding to an external quantum efficiency of 20–40%) and indicate a visible rejection ratio (200–500 nm) higher than four orders of magnitude.     

Greenhouse Gas Dynamics of an Increased Use of Wood in Buildings in Switzerland

Long-living wood products contribute to the mitigation of climate change in many ways. They act as a carbon pool during their service life, as they withdraw CO₂ from its natural cycle. After their service life, they can stitute for fossil fuels if they are incinerated in adequate furnaces. Furthermore, wood products can stitute for more energy-intense products made of ‘conventional’ materials. This paper quantifies the stitution and pool effects of an increased use of wood in the building sector in Switzerland for the years 2000–2130. Life cycle data on greenhouse gas (GHG) emissions of 12 wood products and their stitutes are used as proxies for relevant building products; this data is linked to the forecasted wood flows for each group of building products in a cohort-model. For the political assessment, GHG effects occurring abroad and in Switzerland are distinguished. The results show that the pool effect of an increased use of long-living wood products is of minor importance, whereas the energetic and material stitution effects are much more relevant, especially on a long-term. For construction products, the Swiss share of the GHG effect related to the material stitution is relatively high, as mainly nationally produced materials are stituted for. For interior products, the Swiss share of the GHG effect related to the material stitution is rather small because mainly imports are stituted for. The results must be considered as rough estimates. Nonetheless, these calculations show that an increased use of wood in the building sector is a valid and valuable option for the mitigation of greenhouse gas emissions and for reaching GHG emission targets in a mid- to long-term. Still, the pool and stitution capacity of an increased use of wood is relatively small compared to the overall GHG emissions of Switzerland.     

A Fully Depleted pn-Junction CCD for Infrared-, UV- and X- ray detection

This paper describes the performance of the Fully Depleted pn-junction CCD (pn-CCD) system, developed for ESA's XMM-satellite mission for soft x-ray imaging and spectroscopy in the single photon counting mode in the 100 eV to 10 keV photon range. The 58 mm x 60 mm large pn-CCD array, designed and fabricated at the Semiconductor Lab (Halbleiterlabor) of the Max-Planck-Institut, uses pn-junctions for registers and as backside structure. This concept naturally enables full depletion of the detector volume independent of the silicon wafer's resistivity and thickness, and as such make it an efficient detector for the x-ray region and the infrared. For high detection efficiency in the soft x-ray region and UV, an ultrathin pn-CCD backside deadlayer has been realized. Each pn-CCD-channel is equipped with its own on-chip JFET amplifier which, in combination with the CAMEX-amplifier and multiplexing chip, facilitates parallel readout and fast data rate: the cooled pn-CCD system can be read out at a data rate up to 3 MHz with an electronic noise floor of ENC < 5 e-.