Phosphate removal from water by naturally occurring shale,sandstone, and laterite: The role of iron oxides and of soluble species

Aqueous phosphate removal by three geomaterials from Ivory Coast was evaluated to determine their potential application as low-cost phosphate adsorbents in wastewater treatment. Batch experiments showed that phosphate uptake strongly depended on pH. Laterite and sandstone dissolution was less pronounced compared to shale. A correlation between concentrations of aqueous cation species released from shale and phosphate uptake was observed. The kinetics were well described using the pseudo-second-order model. Isotherms displayed a saturation level on shale, while phosphate uptake continuously increased for laterite and sandstone. The removal efficiency decreased in the following ranking order: laterite > sandstone > shale. Laterite was also the most efficient adsorbent in column experiments. The high phosphate removal efficiency of laterite (8.3 mg PO₄ g^?1) was attributed to the presence of superparamagnetic low grain sizes of goethite. Laterite is a particularly promising material for further investigation in wastewater treatment technology such as constructed wetlands.     

Biosedimentary record of postglacial coastal dynamics: high‐resolution sequence stratigraphy from the northern Tuscan coast (Italy)

Integrating analysis of the benthic palaeoecological record with multivariate ordination techniques represents a powerful synergy able to provide an improved characterization of coastal depositional facies in a sequence stratigraphical perspective. Through quantitative analysis of benthic foraminifer, ostracod and mollusc associations from the postglacial succession of Core M3 (Arno coastal plain, Tuscany, Italy), and application of detrended correspondence analysis (DCA) to the mollusc sub‐data set, we offer a refined picture of stratigraphical variations in faunal content from a paralic depositional setting, and reconstruct the palaeoenvironmental gradients that account for such variations. Despite distinct ecological behaviours, and taphonomic and sedimentological constraints, a strong ecological control on meio‐ and macrofaunal biofacies and taxa turnover is documented across the study succession. Amongst all possible mechanisms that may play a role in ‘shaping’ fossil distribution, the ecological signal driven by salinity represents the most prominent factor controlling the composition of fossil associations in the cored succession. Molluscs can even provide outstanding quantitative estimates of palaeosalinity along the sampled core. When plotted stratigraphically, the three fossil sub‐data sets show consistent patterns of vertical evolution that enable prompt identification of the key surfaces for sequence stratigraphical interpretation in otherwise lithologically indistinguishable deposits. The concomitant maximum richness of species with strong marine affinity, paralleled by the highest DCA salinity estimates, allows recognition of the maximum flooding zone, dated to ～7.7 cal. ka BP, within a homogeneous succession of outer lagoon clays. These clays are sandwiched between early transgressive, swamp to inner lagoon deposits and overlying prograding coastal?alluvial plain facies.     

Objects Detection in Hyperspectral Images Using Spectral Derivative

In recent years hyperspectral imaging has proved its significance in the detection and mapping of various objects of interest in a scene. Various methods for object detection in hyperspectral images have been developed with their advantages and limitations. In the present study, a methodology comprising spectral derivative (first order) and spectral information divergence has been investigated for detection of objects in hyperspectral images. The efficacy of the detection scheme has been examined over two different hyperspectral data sets of Hyperion images. Tea plants (Camellia sinensis) and Sal trees (Shorea robusta) (pure pixels) have been detected as the objects of interest in the hyperspectral images independently with reduced false pixels. The proposed methodology may in future be applied for classification of mixed pixels.     

Semi-automatic mapping of anthropogenic impervious surfaces in an urban/suburban area using Landsat 8 satellite data

Impervious surfaces have a significant impact on urban runoff, groundwater, base flow, water quality, and climate. Increase in Anthropogenic Impervious Surfaces (AIS) for a region is a true representation of urban expansion. Monitoring of AIS in an urban region is helpful for better urban planning and resource management. Cost effective and efficient maps of AIS can be obtained for larger areas using remote sensing techniques. In the present study, extraction of AIS has been carried out using Double window Flexible Pace Search (DFPS) from a new index named as Normalized Difference Impervious Surface Index (NDAISI). NDAISI is developed by enhancing Biophysical Composition Index (BCI) in two stages using a new Modified Normalized Difference Soil Index (MNDSI). MNDSI has been developed from Band 7 and Band 8 (PAN) of Landsat 8 data. In comparison to existing impervious surface extraction methods, the new NDAISI approach is able to improve Spectral Discrimination Index (SDI) for bare soil and AIS significantly. Overall accuracy of mapping of AIS, using NDAISI approach has been found to be increased by nearly 23% when compared with existing impervious surface extraction methods.     

Separation of rifting and lithospheric folding signatures in the NW-Alpine foreland

The development of the Alpine mountain belt has been governed by the convergence of the African and European plates since the Late Cretaceous. During the Cenozoic, this orogeny was accompanied with two major kinds of intraplate deformation in the NW-European foreland: (1) the European Cenozoic Rift System (ECRIS), a left-lateral transtensional wrench zone striking NNE-SSW between the western Mediterranean Sea and the Bohemian Massif; (2) long-wavelength lithospheric folds striking NE and located between the Alpine front and the North Sea. The present-day geometry of the European crust comprises the signatures of these two events superimposed on all preceding ones. In order to better define the processes and causes of each event, we identify and separate their respective geometrical signatures on depth maps of the pre-Mesozoic basement and of the Moho. We derive the respective timing of rifting and folding from sedimentary accumulation curves computed for selected locations of the Upper Rhine Graben. From this geometrical and chronological separation, we infer that the ECRIS developed mostly from 37 to 17 Ma, in response to north-directed impingement of Adria into the European plate. Lithospheric folds developed between 17 and 0 Ma, after the azimuth of relative displacement between Adria and Europe turned counter-clockwise to NW–SE. The geometry of these folds (wavelength = 270 km; amplitude = 1,500 m) is consistent with the geometry, as predicted by analogue and numerical models, of buckle folds produced by horizontal shortening of the whole lithosphere. The development of the folds resulted in ca. 1,000 m of rock uplift along the hinge lines of the anticlines (Burgundy–Swabian Jura and Normandy–Vogelsberg) and ca. 500 m of rock subsidence along the hinge line of the intervening syncline (Sologne–Franconian Basin). The grabens of the ECRIS were tilted by the development of the folds, and their rift-related sedimentary infill was reduced on anticlines, while sedimentary accumulation was enhanced in synclines. We interpret the occurrence of Miocene volcanic activity and of topographic highs, and the basement and Moho configurations in the Vosges–Black Forest area and in the Rhenish Massif as interference patterns between linear lithospheric anticlines and linear grabens, rather than as signatures of asthenospheric plumes.

Lithology-dependent seismic anisotropic amplitude variation with offset correction in transversely isotropic media

Analysis of amplitude variation with offset is an essential step for reservoir characterization. For an accurate reservoir characterization, the amplitude obtained with an isotropic assumption of the reservoir must be corrected for the anisotropic effects. The objective is seismic anisotropic amplitude correction in an effective medium, and, to this end, values and signs of anisotropic parameter differences (Δδ and Δε) across the reflection interfaces are needed. These parameters can be identified by seismic and well log data. A new technique for anisotropic amplitude correction was developed to modify amplitude changes in seismic data in transversely isotropic media with a vertical axis of symmetry. The results show that characteristics of pre-stack seismic data, that is, amplitude variation with offset gradient, can be potentially related to the sign of anisotropic parameter differences (Δδ and Δε) between two layers of the reflection boundary. The proposed methodology is designed to attain a proper fit between modelled and observed amplitude variation with offset responses, after anisotropic correction, for all possible lithofacies at the reservoir boundary. We first estimate anisotropic parameters, that is, δ and ε, away from the wells through Backus averaging of elastic properties resulted from the first pass of isotropic pre-stack seismic inversion, on input data with no amplitude correction. Next, we estimate the anisotropic parameter differences at reflection interfaces (values and signs of Δδ and Δε). We then generate seismic angle gather data after anisotropic amplitude correction using Rüger's equation for the P-P reflection coefficient. The second pass of isotropic pre-stack seismic inversion is then performed on the amplitude-corrected data, and elastic properties are estimated. Final outcome demonstrates how introduced methodology helps to reduce the uncertainty of elastic property prediction. Pre-stack seismic inversion on amplitude-corrected seismic data results in more accurate elastic property prediction than what can be obtained from non-corrected data. Moreover, a new anisotropy attribute (ν) is presented for improvement of lithology identification.     

Studies on Schumann Resonance Phenomena and Some Recent Advancements

Geomagnetism and Aeronomy - Discrete spectra of frequencies at 8, 14, 20, 26, … Hz are generated by electromagnetic emission from lightning sources and can be regarded as excitation of AC...     

Earthquake hazard assessment through geospatial model and development of EaHaAsTo tool for visualization: an integrated geological and geoinformatics approach

An earthquake is a natural phenomenon which is very frequent in Himalayan region in India. In southern peninsula India, the spatial occurrence of earthquake is irregular, whereas the northeastern, the north and the northwestern Himalayan parts of India are subjected to regular occurrences of earthquakes as they mark the boundary of the Eurasian and the Indian Plate. Hence, it is important to study and develop spatial model and information tool to understand the seismic phenomenon. The geoinformatic technique plays a significant role in the analysis of geodatabase to study the natural disaster and hazard assessment. The main aim of the present study is to develop geospatial model based on earthquake hazard assessment tool (EaHaAsTo) through integrated geological and geoinformatic techniques to better understand the earthquake occurrences zones. The spatial and non-spatial data were collected and integrated in a GIS to prepare geospatial databases. The thematic and quantitative databases were generated, and analysis was carried out to understand the seismic characteristics of the study area. The geospatial model was developed by integrating thematic databases and geospatial analyzed using weighted linear combination method. Finally, the GIS based on customized EaHaAsTo was developed to visualize the output of the model in qualitative and quantitative forms.