Projective ordination by SIMCA: A dynamic strategy for cost-efficient environmental monitoring around offshore installations

A method for environmental monitoring using benthic species profiles as input is developed in this work. The method, referred to as projective ordination, utilises local principal component modelling (SIMCA) to obtain a cross-validated model which spans the natural variation in a region around offshore oil-producing installations. The borderline between regions with disturbed and non-disturbed species communities is subsequently decided from the residual distribution. This distribution is used to design an approximate F-test for assessing whether a community at a particular sampling location is disturbed or not. If so, the nature of the disturbance is determined by projecting the data on the PC model.Projective ordination utilises information from previous surveys to define the permissible variation in species communities, i.e. the limit of the natural variation. In addition, the method is dynamic, in a sense that the sampling locations may vary from survey to survey.Furthermore, our analysis shows that the customary number of replicate samples per station can be reduced. Modelling with only four randomly chosen replicates out of the complete set of five for each sampling location, does not affect the model significantly. On the other hand, taking only 3 replicates into account leads to significant divergences.A model based on the 1990 and 1993 surveys at the Statfjord field is presented as an example of the technique.     

The low-pressure stability of phase A,Mg7Si2O8(OH)6

 Phase A, Mg₇Si₂O₈(OH)₆, is a dense hydrous magnesium silicate whose importance as a host of H₂O in the Earth’s mantle is a subject of debate. We have investigated the low-pressure stability of phase A in experiments on the reaction phase A=brucite+forsterite. Experiments were conducted in piston-cylinder and multi-anvil apparatus, using mixtures of synthetic phase A, brucite and forsterite. The reaction was bracketed between 2.60 and 2.75 GPa at 500° C, between 3.25 and 3.48 GPa at 600° C and between 3.75 and 3.95 GPa at 650^° C. These pressures are much lower than observed in the synthesis experiments of Yamamoto and Akimoto (1977). At 750^° C the stability field of brucite + chondrodite was entered. The enthalpy of formation and entropy of phase A at 1 bar (10⁵ Pa), 298 K, were derived from the experimental brackets on the reaction phase A=brucite+forsterite using a modified version of the thermodynamic dataset THERMOCALC of Holland and Powell (1990), which includes a new equation of state of H₂O derived from the molecular dynamics simulations of Brodholt and Wood (1993). The data for phase A are: ΔH ^o _f =−7126±8 kJ mol^-1, S ^o=351 J K^-1 mol^-1. Incorporating these data into THERMOCALC allows the positions of other reactions involving phase A to be calculated, for example the reaction phase A + enstatite=forsterite+vapour, which limits the stability of phase A in equilibrium with enstatite. The calculated position of this reaction (753° C at 7 GPa to 937° C at 10 GPa) is in excellent agreement with the experimental brackets of Luth (1995) between 7 and 10 GPa, supporting the choice of equation of state of H₂O used in THERMOCALC. Comparison of our results with calculated P-T paths of subducting slabs (Peacock et al. 1994) suggests that, in the system MgO–SiO₂–H₂O, phase A could crystallise in compositions with Mg/Si>2 at pressures as low as 3 GPa. In less Mg rich compositions phase A could crystallise at pressures above approximately 6 GPa. Received: 3 July 1995/Accepted: 14 December 1995     

From oblique subduction to intra-continental transpression: Structures of the southern Kermadec-Hikurangi margin from multibeam bathymetry,side-scan sonar and seismic reflection

The southern Kermadec-Hikurangi convergent margin, east of New Zealand, accommodates the oblique subduction of the oceanic Hikurangi Plateau at rates of 4–5 cm/yr. Swath bathymetry and sidescan data, together with seismic reflection and geopotential data obtained during the GEODYNZ-SUD cruise, showed major changes in tectonic style along the margin. The changes reflect the size and abundance of seamounts on the subducting plateau, the presence and thickness of trench-fill turbidites, and the change to increasing obliquity and intracontinental transpression towards the south. In this paper, we provide evidence that faulting with a significant strike-slip component is widespread along the entire 1000 km margin. Subduction of the northeastern scrap of the Hikurangi Plateau is marked by an offset in the Kermadec Trench and adjacent margin, and by a major NW-trending tear fault in the scarp. To the south, the southern Kermadec Trench is devoid of turbidite fill and the adjacent margin is characterized by an up to 1200 m high scarp that locally separates apparent clockwise rotated blocks on the upper slope from strike-slip faults and mass wasting on the lower slope. The northern Hikurangi Trough has at least 1 km of trench-fill but its adjacent margin is characterized by tectonic erosion. The toe of the margin is indented by 10–25 km for more than 200 km, and this is inferred to be the result of repeated impacts of the large seamounts that are abundant on the northern Hikurangi Plateau. The two most recent impacts have left major indentations in the margin. The central Hikurangi margin is characterized by development of a wide accretionary wedge on the lower slope, and by transpression of presubduction passive margin sediments on the upper slope. Shortening across the wedge together with a component of strike-slip motion on the upper slope supports an interpretation of some strain partitioning. The southern Hikurangi margin is a narrow, mainly compressive belt along a very oblique, apparently locked subduction zone.     

Impact of spatial resolution on simulated surface water mass transformations in the Atlantic

We analyze the water mass transformation in coarse (1°) and high (1/6°) resolution ocean simulations with the identical configuration of the CLIPPER model and interannual ERA15 forcing function. Climatological characteristics of surface water mass transformation in the two experiments are quite different. The high resolution experiment exhibits a stronger surface transformation in equatorial and tropical regions, in the Gulf Stream area and in the location of the formation of Subtropical Mode Water (STMW), associated with high levels of eddy kinetic energy. The coarse resolution experiment shows a better representation of the transformation rates corresponding to the densest subpolar mode waters and Labrador Sea Water (LSW). This is explained by the differences in lateral mixing procedures between high and coarse resolution experiments. The high resolution 1/6° run is eddy-resolving only in the tropics and mid-latitudes. In these areas eddies are found to enhance the process of water mass transformation compared to the isopycnal diffusion used to parameterized the eddies in the 1° model. Despite its 1/6° resolution, the high resolution model does not adequately represent eddies in the subpolar gyre and Labrador Sea. In these areas the high resolution model fails to correctly simulate water mass transformation because the lateral mixing (provided through the bi-harmonic sub-gridscale parameterization) of newly ventilated waters with surrounding waters is not efficient enough. In contrast in the coarse 1° resolution model, the strong lateral mixing and the unrealistically broad boundary currents imposed by the high diffusivity required for numerical stability mixes newly formed LSW waters with the warmer and saltier waters of the rim current. Finally, it results in a more effective representation of the surface water mass transformation in high latitudes in the 1° model. A possible impact of the increased lateral diffusion in high resolution experiment on the representation of re-stratification in the Labrador Sea was studied in sensitivity experiments with different lateral diffusion coefficients compared to the regional eddy-resolving 1/15° simulation in the subpolar North Atlantic. If the eddies are not resolved in subpolar latitudes (as in the case of 1/6° model), the GM90 parameterization with the coefficient close to 800 m² s⁻¹ provides the closest agreement with the solution of eddy-resolving 1/15° model.     

Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily - Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.     

Geometry and structure of the Vitiaz Trench Lineament (SW Pacific)

Swath bathymetric, sonar imagery and seismic reflection data collected during the SOPACMAPS cruise Leg 3 over segments of the Vitiaz Trench Lineament and adjacent areas provide new insights on the geometry and the stuctural evolution of this seismically inactive lineament. The Vitiaz Trench Lineament, although largely unknown, is one of the most important tectonic feature in the SW Pacific because it separates the Cretaceous crust of the Pacific Plate to the north from the Cenozoic lithosphere of the North Fiji and Lau Basins to the south. The lineament is considered to be the convergent plate boundary between the Pacific and Australian Plates during midde to late Tertiary time when the Vitiaz Arc was a continuous east-facing are from the Tonga to the Solomon Islands before the development of the North Fiji and Lau Basins. Progressive reversal and cessation of subduction from west to east in the Late Miocene-Lower Plioene have been also proposed. However, precise structures and age of initiation and cessation of deformation along the Vitiaz Trench Lineament are unknown.The lineament consists of the Vitiaz Trench and three discontinuous and elongated troughs (Alexa, Rotuma and Horne Troughs) which connect the Vitiaz Trench to the northern end of the Tonga Trench. Our survey of the Alexa and Rotuma Troughs reveals that the lineament is composed of a series of WNW-ESE and ENE-WSW trending segments in front of large volcanic massifs belonging to the Melanesian Border Plateau, a WNW trending volcanic belt of seamounts and ridges on Pacific crust. The Plateau and Pacific plate lying immediately north of the lineament have been affected by intense normal faulting, collapse, and volcanism as evidenced by a series of tilted blocks, grabens, horsts and ridges trending N 120° to N100° and N60°–70°. This tectonism includes several normal faulting episodes, the latest being very recent and possibly still active. The trend of the fault scarps and volcanic ridges parallels the different segments of the Vitiaz Trench Lineament, suggesting that tectonics and volcanism are related to crustal motion along the lineament.Although the superficial observed features are mainly extensional, they are interpreted as the result of shortening along the Vitiaz Trench Lineament. The fabric north of the lineament would result from subduction-induced normal faulting on the outer wall of the trench and the zig-zag geometry of the Vitiaz Trench Lineament might be due to collision of large volcanic edifices of the Melanesian Border Plateau with the trench, provoking trench segmentation along left-lateral ENE-WSW trending transform zones. The newly acquired bathymetric and seismic data suggest that crustal motion (tectonism associated with volcanism) continued up to recent times along the Vitiaz Trench Lineament and was active during the development of the North Fiji Basin.     

Compressive tectonism along the eastern margin of Malaita Island (Solomon Islands)

New bathymetric and geophysical data were collected in the region east of the island of Malaita during the SOPACMAPS II cruise of the French research vessel L'ATALANTE. This region, part of the Malaita Anticlinorium was interpreted as a piece of oceanic crust from the Ontong Java Plateau obducted over the old Solomon Islands arc during collision between the Pacific and Australian plates. It has been generally accepted that convergent motion between the Australia and Pacific plates since the Late Miocene was absorbed exclusively along the San Cristobal trench, southwest of the Solomon Islands Arc.Bathymetry, imagery, and geophysical data (magnetism, gravity, seismic) acquired during the SOPACMAPS II survey allow us to classify the successive parallel ridges mapped within the region as being recent volcanic, oceanic crust, or deformed sedimentary ridges.Seismic profiling provides evidence of successive compressive events along the Malaita margin caused by the relative motion between the Solomon Islands and the Pacific plate. The main phase of convergence probably occurred during Oligocene-early Miocene time, but some relative motion between the two domains are still being absorbed along the East Malaita boundary. The existence of active faulting in the sedimentary cover throughout the region and the present-day deformation of the outer sedimentary ridge is a good illustration of this phenomenon.     

Spring distribution of dissolved organic matter in a system encompassing the Northeast Water Polynya: Implications for early-season sources and sinks

This study addresses sources and diagenetic state of early-season dissolved organic matter (DOM) in the Northeast Water Polynya (NEWP) area northeast of Greenland from distributions of humic substance fluorescence (HSfl), dissolved organic carbon (DOC), and dissolved organic nitrogen (DON) in the water column inside and outside the NEWP area. The water masses of the polynya area had acquired their spring/summer temperature–salinity characteristics at the time of sampling, and also had individual, different DOM signatures. DOC concentrations were variable within and among water masses in the polynya area, indicating patchy local sources and sinks of DOC. PySW and polynya intermediate water (PyIW) had higher average DON concentrations and average lower C:N ratios than polynya bottom water (PyBW), indicating a larger fraction of fresh DOM in PySW and PyIW than in PyBW. Ice-covered, polynya area surface waters (PySW) had higher DOC concentrations (113±14 μM, n=68) than surface water (SW) outside the polynya area (96±18 μM, n=6). The DOM C:N ratios in a low-salinity, ice-melt subgroup of PySW samples indicate labile material, and these low-salinity surface waters appeared to have a local DOC and DON source. In contrast, HSfl was significantly lower inside than outside the NEWP area. Despite the lower HSfl values within the NEWP area, the PySW values were high when compared to open-ocean water. There were no local terrestrial sources for HSfl to the NEWP area and the East Greenland Current is therefore proposed as a likely source of allochtonous HSfl. When HSfl was used as a conservative tracer, up to 70% of the water in PySW and PyIW was found to be derived from SW, which contains a high fraction of water from the East Greenland Current. Similarly, a mixing model based on HSfl indicated that 80% of early-season DOC and 90–100% of early-season DON in PySW and PyIW were derived from SW, indicating a potentially high fraction of terrestrially-derived, relatively refractory DOM in the early-season NEWP area.     

Sixty volumes of the Journal du Conseil / ICES Journal of Marine Science

Article 1 of the ICES Convention of 1964 sets out the fundamentalpurposes of the Council and includes as the third and finalpoint: "to publish or otherwise disseminate the results of researchand investigations carried out under its auspices or to encouragethe publication thereof". Publication and dissemination of informationabout the living resources and their environment have been atthe heart of ICES from the first