Temporal features in thunder days in the United States

1901–80 data for the contiguous U.S. show that secular variability of thunder days was very much less than that of precipitation or of frequency of extra tropical cyclones. Overall, there may have been a slight decline, but more evident was an increase to the thirties followed by a falling off, broken only by a peak in the seventies. These up-and-down movements were evident in most months of the year and regions of the U.S. The general decrease, however, was clear only in the South East and replaced by an increase in the Upper Great Lakes region. Secular variation in thunder day frequency was slightly correlated positively with that of extra tropical cyclone frequency and negatively with sea level pressure. The analysis also confirmed well known seasonal and regional patterns of thunder activity.     

The partitioning of Fe and Mg between olivine and carbonate and the stability of carbonate under mantle conditions

We have investigated the effect of Fe on the stabilities of carbonate (carb) in lherzolite assemblages by determining the partitioning of Fe and Mg between silicate (olivine; ol) and carbonates (magnesite, dolomite, magnesian calcite) at high pressures and temperatures. Fe enters olivine preferentially relative to magnesite and ordered dolomite, but Fe and Mg partition almost equally between disordered calcic carbonate and olivine. Measurement of K _d (X _Fe ^carb X _Mg ^ol /X _Fe ^ol X _Mg ^carb ) as a function of Fe/ Mg ratio indicates that Fe–Mg carbonates deviate only slightly from ideality. Using the regular solution parameter for olivine W _FeMg ^ol of 3.7±0.8 kJ/mol (Wiser and Wood 1991) we obtain for (FeMg)CO₃ a W _FeMg ^carb of 3.05±1.50 kJ/mol. The effect of Ca–Mg–Fe disordering is to raise K _d substantially enabling us to calculate W _CaMg ^carb -W _CaFe ^carb of 5.3±2.2 kJ/mol. The activity-composition relationships and partitioning data have been used to calculate the effect of Fe/Mg ratio on mantle decarbonation and exchange reactions. We find that carbonate (dolomite and magnesian calcite) is stable to slightly lower pressures (by 1 kbar) in mantle lherzolitic assemblages than in the CaO–MgO–SiO₂(CMS)–CO₂ system. The high pressure breakdown of dolomite + orthopyroxene to magnesite + clinopyroxene is displaced to higher pressures (by 2 kbar) in natural compositions relative to CMS. CO₂. We also find a stability field of magnesian calcite in lherzolite at 15–25 kbar and 750–1000°C.     

The “geo” of United States national strategy

The paper discusses the geo dimensions of the new world order, with particular emphasis on the increasing role of geoeconomics, and its impact on US national strategy. While the paper uses the US experience to illustrate the growing importance of geoeconomic considerations, the issues raised have direct bearing on many other nations throughout the world.US post Cold War strategy is determined by its three geo challenges. The most important is the geoeconomic challenge caused by the tri-polar division of the world along trading bloc lines, instant global communication and other technologies overcoming the constraints of physical geography, transnational corporations (TNCS) that are becoming supranational in character, and the emergence of a well educated global labor force. The geopolitical challenge is characterized by America's declining relative economic power and its traditional military allies having become economic competitors, while religious, ethnic, and regional tensions threaten its global interests. The third challenge is the military geography issue of effectively projecting power over distance, within the constraints of greatly reduced budgets and loss of overseas bases.     

Volatile fluxes from volcanoes

Volatile fluxes from Mid Ocean Ridge (MOR) and subaerial volcanism have been estimated or re-evaluated using several natural tracers-³He, ²¹⁰Po, SO₂-and chemical ratios of volatile species in lavas and volcanic gases.
These estimates confirm the net predominance of anthropogenic fluxes over volcanic fluxes for CO₂, SO₂ and trace metals.
They also suggest that, while most of the volatiles transferred during MOR volcanism come from the mantle, volatiles stored at the surface of the Earth supply an appreciable fraction of subaerial fluxes and can be the dominant source for some of them.
The surface inventory of volatile species cannot result from steady-state degassing with constant rate and needs much greater fluxes in the past or other volatile supply processes. This inventory is the result of several of the following processes: capture of the solar nebula and its subsequent partial escape, impact degassing of accreting bodies, and, from Archean to present mantle, degasssing through volcanism and associated phenomena, with recycling into the mantle through subduction.     

Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.     

Applicability of the theory of hollow inclusions for overcoring stress measurements in rock

Summary Whenever solid or hollow inclusions are used as instrumented probes in overcoring techniques, residual stresses remain in the overcored rock sample and in the probes. When using such devices for computing the in-situ stress field components from measured strains or displacements, it is common practice to assume that the overcoring diameter is infinite and that there is a perfect bonding between the rock and the probes. The validity of these assumptions depends on the magnitude of the residual stresses at the rock-probe contact as compared to the tensile and shear strengths of the rock-probe bond material. It also depends on the distribution of residual stresses in the overcored sample.In comparison to previous work, new expressions are proposed in this paper for the residual stresses associated with solid or hollow inclusion type stress probes in anisotropic ground. These expressions are presented in dimensionless form and are used to show that the distribution and magnitude of residual stresses depend on the isotropic-anisotropic rock character, the degree and type of rock anisotropy, the orientation of the rock anisotropy with respect to the hole in which the probes are located and the relative deformability of the rock with respect to the deformability of the material comprising the probes. The conditions that are required for neglecting the overcored sample diameter are also discussed. This is shown for rocks that can be described as isotropic, transversely isotropic and orthotropic materials.