Crustal structure measurements near FRAM II in the pole abyssal plain

An extensive refraction profiling program was carried out during the FRAM II experiment (March–May, 1980) in the eastern Arctic Ocean. Two structural areas were covered: north of the ice camp (86°N, 24°W) into the basin of the Pole Abyssal Plain and south onto the flanks of the Morris Jesup Rise. Digital multichannel data on an 800 by 800 m, 24 channel hydrophone array and a single 2-component ocean bottom seismometer (OBS) were recorded for offsets from 2.5 to 100 km. Arrival times, amplitudes and phase velocities of the seismic signals recieved on the hydrophone array were determined using high resolution array processing. From these measurements and the OBS data, preliminary velocity structural models of the crust have been derived. For the purposes of this paper, 2 refraction lines have been analyzed, a 40 km line on a flat region of the Pole Abyssal Plain and an 86 km line on a slightly dipping region taken as the drifting ice camp shoaled on the Morris Jesup Rise. These preliminary analyses yield a sedimentary layer with a gradually increasing velocity 1.5–2 km thick. This cover overlays a crust with a thin layer 2 (< 1 km) and yields a total ocean bottom to mantle thickness of 4–7 km.     

Role of molecular oxygen in the dissolution of siderite and rhodochrosite

The dissolution of siderite (FeCO₃) and rhodochrosite (MnCO₃) under oxic and anoxic conditions is investigated at 298 K. The anoxic dissolution rate of siderite is 10^−8.65 mol m⁻² s⁻¹ for 5.5 < pH < 12 and increases as [H⁺]^0.75 for pH < 5.5. The pH dependence is consistent with parallel proton-promoted and water hydrolysis dissolution pathways. Atomic force microscopy (AFM) reveals a change in pit morphology from rhombohedral pits for pH > 4 to pits elongated at one vertex for pH < 4. Under oxic conditions the dissolution rate decreases to below the detection limit of 10⁻¹⁰ mol m⁻² s⁻¹ for 6.0 < pH < 10.3, and hillock precipitation preferential to steps is observed in concurrent AFM micrographs. X-ray photoelectron spectroscopy (XPS) and thermodynamic analysis identify the precipitate as ferrihydrite. At pH > 10.3, the oxic dissolution rate is as high as 10^−7.5 mol m⁻² s⁻¹, which is greater than under the corresponding anoxic conditions. A fast electron transfer reaction between solution O₂ or [Fe³⁺(OH)₄]⁻ species and surficial >Fe^II hydroxyl groups is hypothesized to explain the dissolution kinetics. AFM micrographs do not show precipitation under these conditions. Anoxic dissolution of rhodochrosite is physically observed as rhombohedral pit expansion for 3.7 < pH < 10.3 and is chemically explained by parallel proton- and water-promoted pathways. The dissolution rate law is 10^−4.93[H⁺] + 10^−8.45 mol m⁻² s⁻¹. For 5.8 < pH < 7.7 under oxic conditions, the AFM micrographs show a tabular precipitate growing by preferential expansion along the a-axis, though the macroscopic dissolution rate is apparently unaffected. For pH > 7.7 under oxic conditions, the dissolution rate decreases from 10^−8.45 to 10^−9.0 mol m⁻² s⁻¹. Flattened hillock precipitates grow across the entire surface without apparent morphological influence by the underlying rhodochrosite surface. XPS spectra and thermodynamic calculations implicate the precipitate as bixbyite for 5.8 < pH < 7.7 and MnOOH (possibly feitnkechtite) for pH >7.7.     

Fire intensity,slopewash and bio‐transfer of sediment in eucalypt forest,Australia

Sediment movement (slopewash and bio‐transfer), runoff, and organic matter movement (mainly leaf litter, ash and charcoal) were monitored on ten plots for a six‐month period following bushfires in eastern Australia in the 1990s. Plots were installed in areas which had experienced high, moderate and low intensity burns. Although between‐plot variability was high, slopewash and organic matter amounts were greatest on the intensely burnt areas, and progressively less on moderate and low intensity burns. In contrast, most leaf litter input from scorched leaf fall was derived from, and collected in, moderately burnt areas. Bio‐transfer of sediment (direct downslope surface movement produced by faunal activity) occurred mainly by ant mounding, and was more than ten times greater on moderately burnt areas than on plots having high or low intensity burns. Bio‐transfer accounted for approximately 36 per cent of total sediment collected, with this material being recorded least often and in smallest quantities on areas of high intensity burns. Bio‐transfer by ant mounding and animal scratchings contributed loose surface sediment for transport by overland flow, disproportionately increasing total sediment movement to plot aprons in areas of moderate intensity burns. Copyright © 2002 John Wiley & Sons, Ltd.     

The Ecological Impact of Conquest and Colonization on a Medieval Frontier Landscape: Combined Palynological and Geochemical Analysis of Lake Sediments from Radzyń Chełminski,Northern Poland

Slavic and German colonization of the southern Baltic between the 8th and 15th centuries A.D. is well‐documented archaeologically and historically. Despite the large number of pollen profiles from Poland, few palaeoecological studies have examined the ecological impact of a process that was central to the expansion of European, Christian, societies. This study aims to redress this balance through multiproxy analysis of lake sediments from Radzyń Chełminski, Northern Poland, using pollen, element geochemistry (Inductively Coupled‐Optical Emission Spectroscopy [ICP‐OES]), organic content, and magnetic susceptibility. The close association between lake and medieval settlements presents the ideal opportunity to reconstruct past vegetation and land‐use dynamics within a well‐documented archaeological, historical, and cultural context. Three broad phases of increasing landscape impact are visible in the pollen and geochemical data dating from the 8th/9th, 10th/11th, and 13th centuries, reflecting successive phases of Slavic and German colonization. This involved the progressive clearance of oak‐hornbeam dominated woodland and the development of an increasingly open agricultural landscape. Although the castles and towns of the Teutonic Order remain the most visible signs of medieval colonization, the palynological and geochemical data demonstrate that the major phase of woodland impact occurred during the preceding phase of Slavic expansion; Germans colonists were entering a landscape already significantly altered.     

Spatial variability in community structure of Dictyoceratida sponges across Torres Strait,Australia

Spatial variability in community structure of dictyoceratid sponges (class Demospongiae; order Dictyoceratida) was examined on coral reefs in Torres Strait, an archipelago of islands and reefs between northern Queensland, Australia, and Papua New Guinea. Dictyoceratid sponge abundances and environmental factors were recorded at four locations, separated by 50–220 km. Each location was subdivided into 5–7 sites, each ?2 km apart. At each site, four 50×2 m belt transects were quantitatively surveyed, recording the dictyoceratid numbers, substrate type (rock, rubble and sand), water clarity, degree of reef slope and depth. Dictyoceratid abundance was similar among locations over large spatial scales, averaging 15.5 individuals per 100 m², but varied significantly among sites within particular locations (i.e. small scale heterogeneity). Twenty-three dictyoceratid species were recorded in Torres Strait, with approximately half (12/23) found in only one location. The canonical correspondence analysis determined that the measured environmental factors explained only 26% of the spatial variation. Cluster analysis revealed a complex dictyoceratid community structure with similarities among neighbouring sites and among sites separated by hundreds of kilometres. Conversely the abundance and composition of dictyoceratids could vary greatly between neighbouring sites 2 km apart and on the same reef complex. The results of this study suggest that spatial variability of dictyoceratid sponges in Torres Strait is influenced by a combination of environmental, biological and stochastic processes.     

Dissolution of hausmannite (Mn3O4) in the presence of the trihydroxamate siderophore desferrioxamine B

That microbial siderophores may be mediators of Mn(III) biogeochemistry is suggested by recent studies showing that these well known Fe(III)-chelating ligands form very stable Mn(III) aqueous complexes. In this study, we examine the influence of desferrioxamine B (DFOB), a trihydroxamate siderophore, on the dissolution of hausmannite, a mixed valence Mn(II, III) oxide found in soils and freshwater sediments. Batch dissolution experiments were conducted both in the absence (pH 4-9) and in the presence of 100 μM DFOB (pH 5-9). In the absence of the ligand, there is a sharp decrease in the extent of proton-promoted dissolution above pH 5 and no appreciable dissolution above pH 8. The resulting aqueous Mn²⁺ activities were in good agreement with previous studies, indirectly supporting the accepted two-step mechanism involving the formation of manganite and reprecipitation of hausmannite. Desferrioxamine B enhanced hausmannite dissolution over the entire pH range investigated, both via the formation of a Mn(III) complex and through surface-catalyzed reductive dissolution. Above pH 8, non-reductive ligand-promoted dissolution dominated, whereas below pH 8, dissolution was non-stoichiometric with respect to DFOB. Concurrent proton-promoted, ligand-promoted, reductive, and induced dissolution was observed, with Mn release by either reductive or induced dissolution increasing linearly with decreasing pH. The fast kinetics of the DFOB-promoted dissolution of hausmannite, as compared to iron oxides, suggest that the siderophore-promoted dissolution of Mn(III)-bearing minerals may compete with the siderophore-promoted dissolution of Fe(III)-bearing minerals.     

Black hole growth in hierarchical galaxy formation

We incorporate a model for black hole growth during galaxy mergers into the semi-analytical galaxy formation model based on ΛCDM proposed by Baugh et al. Our black hole model has one free parameter, which we set by matching the observed zero-point of the local correlation between black hole mass and bulge luminosity. We present predictions for the evolution with redshift of the relationships between black hole mass and bulge properties. Our simulations reproduce the evolution of the optical luminosity function of quasars. We study the demographics of the black hole population and address the issue of how black holes acquire their mass. We find that the direct accretion of cold gas during starbursts is an important growth mechanism for lower mass black holes and at high redshift. On the other hand, the re-assembly of pre-existing black hole mass into larger units via merging dominates the growth of more massive black holes at low redshift. This prediction could be tested by future gravitational wave experiments. As redshift decreases, progressively less massive black holes have the highest fractional growth rates, in line with recent claims of 'downsizing' in quasar activity.     

Biogeochemistry of iron oxidation in a circumneutral freshwater habitat

Iron(II) oxidation in natural waters at circumneutral pH, often regarded as an abiotic process, is frequently biologically mediated at iron-rich redox gradients. West Berry Creek, a small circumneutral tributary that flows through a mixed coniferous forest in Big Basin State Park, California, contains localized iron (hydr)oxide precipitates at points along its course where anoxic groundwater meets oxygenated creek water. These mixing zones establish redox gradients that may be exploited by microbes forming microbial mats that are intimately associated with iron (hydr)oxide precipitates. Water sampling revealed strong correlations between the concentrations of aqueous inorganic species, suggesting a rock-weathering source for most of these solutes. Liquid chromatography–electrospray ionization–mass spectrometry techniques detected significant concentrations of organic exudates, including low molecular mass organic acids and siderophores, indicating that active biogeochemical cycling of iron is occurring in the creek. X-ray diffraction and elemental analysis showed the precipitates to be amorphous, or possibly poorly crystalline, iron-rich minerals. Clone libraries developed from 16S rDNA sequences extracted from microbial mat communities associated with the precipitates revealed the presence of microorganisms related to the neutrophilic iron oxidizing bacteria Gallionella and Sideroxydans. Sequences from these libraries also indicated the presence of significant populations of organisms related to bacteria in the genera Aquaspirillum, Pseudomonas, Sphingomonas, and Nitrospira. These geosymbiotic systems appear to be significant not only for the biogeochemical cycling of iron in the creek, but also for the cycling of organic species, inorganic nutrients, and trace metals.