Baseline metals pollution profile of tropical estuaries and coastal waters of the Straits of Malacca

The status report on metal pollution in tropical estuaries and coastal waters is important to understand potential environmental health hazards. Detailed baseline measurements were made on physicochemical parameters (pH, temperature, redox potential, electrical conductivity, salinity, dissolved oxygen, total dissolved solid), major ions (Na, Ca, Mg, K, HCO₃, Cl, SO₄ and NO₃) and metals concentrations (²⁷Al, ⁷⁵As, ¹³⁸Ba, ⁹Be, ¹¹¹Cd, ⁵⁹Co, ⁶³Cu, ⁵²Cr, ⁵⁷Fe, ⁵⁵Mn, ⁶⁰Ni, ²⁰⁸Pb, ⁸⁰Se, ⁶⁶Zn) at estuaries and coastal waters along the Straits of Malacca. Principal component analysis (PCA) was employed to reveal potential pollution sources. Seven principal components were extracted with relation to pollution contribution from minerals-related parameters, natural and anthropogenic sources. The output from this study will generate a profound understanding on the metal pollution status and pollution risk of the estuaries and coastal system.     

Mesoscale surface circulation and variability of Southern Indian Ocean derived by combining satellite altimetry and drifter observations

High resoultion Eulerian mean velocity field has been derived by combining the satellite tracked surface drifter data with satellite altimetry and ocean surface winds. The drifter data used in this study includes Argos and surface drifter data from Global Drifter Program. Maps of Sea Level Anomaly(MSLA) weekly files with a resolution of(1/3)° in both Latitude and Longitude for the period 1993–2012 have been used. The Ekman current is computed using ocean surface mean wind fields from scatterometers onboard ERS 1/2,Quikscat and ASCAT. The derived mean velocity field exhibits the broad flow of Antarctic Circumpolar Current with speeds up to 0.6 m/s.Anomalous field is quite significant in the western part between 20° and 40°E and in the eastern part between 80°E and 100°E with velocity anomaly up to 0.3 m/s. The estimated mean flow pattern well agrees with the dynamic topography derived from in-situ observations. Also,the derived velocity field is consistent with the in-situ ADCP current measurements. Eddy kinetic energy illustrates an increasing trend during 1993–2008 and is in phase coherence with the Southern Annular Mode by three month lag. Periodic modulations are found in the eddy kinetic energy due the low frequency Antarctic Circumpolar Wave propagation.     

Compositional appraisal and quality implication of Emiworo metacarbonate deposit in Central Nigeria

Metacarbonate deposit occurring in Emiworo area, northcentral Nigeria are low grade marble associated with Proterozoic basement complex rocks. Integrated inorganic geochemical, physical and thermal characteristics of the samples were investigated with the aim of revealing their economic viability. The phase characteristics of the metacarbonate show that dolomite is the dominant phase with calcite and phlogopite as minor phases, while silicates, graphites and pyrites constitute the accessories. Reactivity of the quicklime measured after calcination at different temperatures revealed that only the quicklime produced in 1 hour at 950°C and 1000°C was found to be reactive. Physical properties and comparative data show that the Emiworo marble displays lower water absorption and higher compressive strength, loss on ignition and bulk specific gravity, compared to other metacarbonate rocks occurring in other parts of Nigeria and elsewhere. These attributes makes the deposit suitable for many conventional industrial applications.     

Surfactants in the sea-surface microlayer and their contribution to atmospheric aerosols around coastal areas of the Malaysian peninsula

A study was done to determine the concentrations of surfactants on the sea-surface microlayer and in atmospheric aerosols in several coastal areas around the Malaysian peninsula. The concentrations of surfactants from the sea-surface microlayer (collected using rotation drum) and from aerosols (collected using HVS) were analyzed as methylene blue active substances and disulphine blue active substances through the colorimetric method using a UV-vis spectrophotometer. The results of this study showed that the average concentrations of surfactants in the sea-surface microlayer ranged between undetected and 0.36 ± 0.34 μmol L⁻¹ for MBAS and between 0.11 ± 0.02 and 0.21 ± 0.13 μmol L⁻¹ for DBAS. The contribution of surfactants from the sea-surface microlayer to the composition of surfactants in atmospheric aerosols appears to be very minimal and more dominant in fine mode aerosols.     

CFD simulation and experimental analysis of flow dynamics and grinding performance of opposed fluidized bed air jet mill

This paper presents a three dimensional Computational Fluid Dynamics (CFD) model to investigate the flow dynamics of solid–gas phases during fine grinding in an air jet mill. Alpine 100AFG fluidized bed air jet mill is considered for the study and the jet milling model is simulated using FLUENT 6.3.2 using a standard k-ε model. The model is developed in GAMBIT 2.3.16 and meshed by tet/hybrid (T-Grid) and Triangular (Pave) meshes. The effects of operating parameters such as solid feed rate, grinding air pressure and internal classifier speed on the performance of the jet mill are analyzed. The CFD simulation results are presented in the forms of dual phase vector plot, volume fraction of phases and particle trajectories during fine grinding process. The mass of ground feed entering and leaving the cyclone (underflow) is also computed by simulation. The proposed model gives realistic predictions of the flow dynamics within the jet mill. Experiments are conducted on the Alpine 100AFG jet mill to study the particle size, morphology and mass of the ground product. The numerical results are found in good agreement with the experimental results.     

Experimental study on loss factor for corrugated plates by bandwidth method

The material loss factor for technically orthotropic plates was measured by half-power bandwidth method. Rectangular and trapezoidal corrugated plates of steel were considered. A simple isotropic steel plate was also considered for comparison of the results. The concept of single degree of freedom system was adopted. The tests were undertaken at very low frequency range (0–100) Hz. The plate models were suspended freely with two wires to minimize or prevent excessive extraneous energy dissipation. Out of plane point force, random in nature was applied to the top middle of the plates and the responses were measured from the middle point of the plates by FFT analyzer using miniature small mass accelerometer as sensor. The aim of these tests is to investigate the effects of bending rigidity and mode orders over material loss factor. The values of estimated modal damping loss factors are compared and tabulated for the plates models considered. Natural frequencies of some of the initial modes of the plates are also presented.It is observed that the higher the value of bending rigidity of the plates, the larger the values of loss factor of it. There was a significant increase in value of loss factor in corrugated plates to that of the isotropic plate.     

Risk assessment of polycyclic aromatic hydrocarbons in the West Port semi-enclosed basin (Malaysia)

Sediment samples collected from the West Port, the west coastal waters of Malaysia, were analyzed by standard methods to determine the degree of hydrocarbon contamination and identify the sources of polyaromatic hydrocarbons (PAHs). Concentrations of PAHs in the port sediments ranged from 100.3 to 3,446.9 μg/kg dw. The highest concentrations were observed in stations close to the coastline, locations affected by intensive shipping activities and industrial input. These were dominated by high-molecular-weight PAHs (4–6 rings). Source identification showed that PAHs originated mostly pyrogenically, from the combustion of fossil fuels, grass, wood, and coal or from petroleum combustion. Regarding ecological risk estimation, only station 7 was moderately polluted, the rest of the stations suffered rare or slight adverse biological effects with PAH exposure in surface sediment, suggesting that PAHs are not considered as contaminants of concern in the West Port.     

Structural Mapping of the Bentong‐Raub Suture Zone Using PALSAR Remote Sensing Data,Peninsular Malaysia: Implications for Sediment‐hosted/Orogenic Gold Mineral Systems Exploration

The Bentong‐Raub Suture Zone (BRSZ) of Peninsular Malaysia is one of the major structural zones in Sundaland, Southeast Asia. It forms the boundary between the Gondwana‐derived Sibumasu terrane in the west and Sukhothai Arc in the east. The BRSZ is genetically related to the sediment‐hosted/orogenic gold deposits associated with the major lineaments in the Central Gold Belt of Peninsular Malaysia. In this investigation, the Phased Array type L‐band Synthetic Aperture Radar (PALSAR) satellite remote sensing data were used to map major geological structures in Peninsular Malaysia and provide detailed characterization of lineaments and curvilinear structures in the BRSZ, as well as their implication for sediment‐hosted/orogenic gold exploration in tropical environments. Major structural lineaments such as the Bentong‐Raub Suture Zone (BRSZ) and Lebir Fault Zone, ductile deformation related to crustal shortening, brittle disjunctive structures (faults and fractures) and collisional mountain range (Main Range granites) were detected and mapped at regional scale using PALSAR ScanSAR data. The major geological structure directions of the BRSZ were N–S, NNE–SSW, NE–SW and NW–SE, which derived from directional filtering analysis to PALSAR fine and polarimetric data. The pervasive array of N–S faults in the Central Gold Belt and surrounding terrain is mainly linked to the N–S trending of the Suture Zone. N–S striking lineaments are often cut by younger NE–SW and NW–SE‐trending lineaments. Gold mineralized trend lineaments are associated with the intersection of N–S, NE–SW, NNW–SSE and ESE–WNW faults and curvilinear features in shearing and alteration zones. Compressional tectonic structures such as the NW–SE trending thrust, ENE–WSW oriented faults in mylonite and phyllite, recumbent folds and asymmetric anticlines in argillite are high potential zones for gold prospecting in the Central Gold Belt. Three generations of folding events in Peninsular Malaysia have been recognized from remote sensing structural interpretation. Consequently, PALSAR satellite remote sensing data is a useful tool for mapping major geological structural features and detailed structural analysis of fault systems and deformation areas with high potential for sediment‐hosted/orogenic gold deposits and polymetallic vein‐type mineralization along margins of Precambrian blocks, especially for inaccessible regions in tropical environments.     

Bacterial community and some physico-chemical characteristics in a subtropical mangrove environment in Bahrain

A study of bacterial communities and some physico-chemical parameters of a subtropical mangrove habitat in the Arabian Gulf (Bahrain) was carried out in 1993-1994. Six stations at different parts of the tidal channel were selected for sampling. The mangrove habitat was found to harbor diverse bacterial communities, included among them anoxygenic phototrophs (AP), oxygenic phototrophs (OP), organotrophs (OT), total coliforms (TC), faecal coliforms (FC) and haloalkaliphiles (HA). Spatial and temporal variations in bacterial communities and environmental parameters were found. Each of the OT, AP, TC, and FC were dominant in the innermost stations (S1&S2) and gradually decreased seaward. The HA community on the other hand, was dominant at the seaward stations (S5&S6) and was most likely to have originated from the sea through the tidal flows. Both AP and OT were considered as part of the mangrove native flora, whereas TC and FC were alien and believed to have been introduced through partially treated sewage released at the upstream of the tidal channel. Closely monitoring of the mangrove water revealed succession pattern in bacterial communities. The AP community was predominant from November 1993 to March 1994, succeeded by dominance of OP from June 1994 to October 1994. Both bacterial blooms gave water a pinkish, purple, or green color, respectively. Although OT prevailed during Transitional period between AP and OP eutrophication, it remained comparatively constant (not less than 2 x 10(5)cfu/ml) through other periods. Frequent eutrophication phenomena of OP, which took place in summer and autumn, coincided with increases in water temperature, chlorophyll a, and nutrients (NO(3)(-) and PO(4)(-)). On the other hand, OT and AP were negatively correlated with temperature, salinity and chlorophyll a, but no specific pattern was observed in relation to NO(3)(-) and PO(4)(-). In comparison with seawater, nutrients such as NO(3)(-) and PO(4)(-) were consistently higher in the mangrove habitat. Partially treated sewage and farm drainage canals are proposed to form additional sources of nutrients. Although, the mangrove habitat has been demonstrated to possess self-cleaning properties, data obtained suggest that anthropogenic pollution has a deleterious effect.