Sedimentological constraints on hydrometeor-enhanced particle deposition: 1992 Eruptions of Crater Peak, Alaska

Water is a dominant component of volcanic clouds and has fundamental control on very fine particle deposition. Particle size characteristics of distal tephra-fall (100s km from source volcano) have a higher proportion of very fine particles compared to predictions based on single particle settling rates. In this study, sedimentological analyses of fallout from for the 18 August and 16–17 September 1992 eruptions of Crater Peak, Alaska, are combined with satellite observations, and cloud trajectory and microphysics modeling to investigate meteorological influences on particle sedimentation. Total grain size distributions of tephra fallout were reconstructed for both Crater Peak eruptions and indicate a predominance of fine particles < 125 μm. Polymodal analysis of the deposits has identified a particle subpopulation with mode ~ 15–18 μm involved in particle aggregation. Accounting for the magmatic water source only, calculated ice water content of the 3.7 hour old September 1992 Spurr cloud was ~ 4.5 × 10^− 2 g m^− 3 (based on an estimated cloud thickness of ~ 1000 m from trajectory modeling). Hydrometeor formation on particles in the volcanic cloud and subsequent sublimation may induce a cloud base instability that leads to rapid bulk (en masse) sedimentation of very fine particles through a mammatus-like mechanism.     

Fine ash content of explosive eruptions

In explosive eruptions, the mass proportion of ash that is aerodynamically fine enough to cause problems with jet aircraft or human lungs (< 30 to 60 μm in diameter) is in the range of a few percent to more than 50%. The proportions are higher for silicic explosive eruptions, probably because vesicle size in the pre-eruptive magma is smaller than those in mafic magmas. There is good evidence that pyroclastic flows produce high proportions of fine ash by communition and it is likely that this process also occurs inside volcanic conduits and would be most efficient when the magma fragmentation surface is well below the summit crater. Reconstructed total grain size distributions for several recent explosive eruptions indicate that basaltic eruptions have small proportions of very fine ash (~ 1 to 4%) while tephra generated during silicic eruptions contains large proportions (30 to > 50%).     

Probing the oxidation-reduction properties of terrestrially and microbially derived dissolved organic matter

Dissolved organic matter (DOM) has been shown to be an integral component in biogeochemical electron transfer reactions due to its demonstrated ability to facilitate redox reactions. While the role of DOM as a facilitator of electron transfer processes has been demonstrated, greater knowledge would lead to better understanding of the structural components responsible for redox behavior, such as quinones and nitrogen and sulfur (N/S) functional groups. This investigation uses direct scan voltammetry (DSV) coupled with fluorescence and NMR spectroscopy as well as thermochemolysis gas chromatography mass spectrometry (GC-MS) and X-ray photoelectron spectroscopy (XPS) to elucidate the organic moieties responsible for facilitating electron transfer reactions. We contrast electrochemical properties and structural details of three organic matter isolates from diverse sources; Great Dismal Swamp DOM (terrestrially derived, highly aromatic), Pony Lake DOM (microbially derived, highly aliphatic) and Toolik Lake (terrestrially derived, photochemically and microbially altered) with juglone (a redox-active model quinone). Aromatic and phenolic constituents were detected (by ¹³C NMR) and recovered (by thermochemolysis GC-MS) from all three fulvic acid samples, highlighting the ubiquity of these compounds and suggesting that the quinone-phenol redox couple is not limited to DOM derived from lignin precursors. The range of hydroxy-benzene and benzoic acid derivatives may explain the lack of a single pair of well-defined oxidation and reduction peaks in the DSV scans. The presence of a wide-range of hydroxylated benzoic acid isomers and other redox-active aromatic residues implies that native DOM possesses overlapping redox potentials analogous to their characteristic range of pK_a values.     

INFORMATION SOURCES FOR NINETEENTH CENTURY MIDWESTERN MIGRATION*

A variety of sources provides different levels of information about the origins of nineteenth century migrants to the Midwest. The advantages and disadvantages of four of the most common records, the federal census, land office records, genealogical collections, and county histories/biographies/atlases, are examined. Characteristics considered are the specific types of data provided, extent of coverage, level of detail, statistical reliability, and accessibility. Examples of studies using each record type are cited.     

Optical observations of FY Persei

The results are presented of multi-channel photometry and spectroscopy of the suspected nova-like variable FY Per. These results suggest that FY Per may be a Herbig Ae/Be star rather than a nova-like variable.     

Effect of divalent cations on the kinetics of Fe(III) complexation by organic ligands in natural waters

We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca²⁺ and Mg²⁺) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 10⁴ to 3.2 × 10⁶ M⁻¹ s⁻¹. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater.     

Subglacial comminution in the deforming bed: Inferences from SEM analysis

This study investigates the variations in erosional processes beneath Briksdalsbreen; a Norwegian valley glacier, with a thin coarse grained deforming bed. The subglacial zone was investigated in situ, close to the central glacial flow line (Site A) and close to the valley wall (Site B), via boreholes. The till was collected using two different sediment samplers and the bed was examined using a borehole video camera. In order to evaluate how representative borehole sampling was of the subglacial environment, the results from in situ subglacial samples were compared with random samples taken from an exposed subglacial surface in the glacier foreland, as well as a sample taken from the site after glacier retreat. The results indicated that the texture of the exposed subglacial surface was similar to in situ samples from subglacial Site B (close to the valley wall), and that the samples collected with the ‘small’ sediment sampler had the closest fit. SEM analysis revealed eroded quartz grains at both sites as a result of rotation (abrasion) and fracture. The samples from close to the valley wall were very poorly sorted, with evidence for rounding and preservation of pre-weathered surfaces, which suggest that a relatively simple pattern of erosion from crushing to rotation dominated. However, the till from the centre of the glacier was better sorted, more angular, and with few pre-weathered surfaces. We suggest that this results from a more complex glacial erosional history associated with greater strain and longer residence time within the deforming layer. When compared with other deformation tills, it was confirmed that there is a relationship between grain size and erosional style. Clay-rich tills show little comminution, fine sand-rich tills generate a significant silt component, whilst the coarse sand-rich tills at Briksdalsbreen showed complex deformational styles but no significant silt component.     

Analysis of an estuarine striped bass population: Effects of environmental conditions during early life

Estuarine fish populations are exposed to a variety of environmental conditions that cause both short-term variability and long-term trends in abundance. We analyzed an extensive data set for striped bass (Morone saxatilis) in the San Francisco Estuary to refine our understanding of how environmental variability influences recruitment. We examined the effects of environmental variability during early life stages on subsequent recruitment (age 3 yr), and the degree to which conditions in early life may have contributed to a long-term decline in abundance of adult striped bass in the San Francisco Estuary. Survival from egg to young-of-the-year varied strongly with freshwater flow; this effect apparently occurred within the first week or two of life, a time period that encompasses transport of eggs and larvae from the rivers to rearing areas and the onset of feeding. The rate of freshwater flow to pumping facilities that export freshwater from the system had small or sporadic effects on survival during the first month or two of life. Although many young striped bass between ages 2 and 8 mo were entrained in export pumping facilities, the resulting high mortality was unrelated to total mortality rates determined from field data on young striped bass. This lack of effect was apparently due to strong density-dependent mortality occurring between ages 1 mo and 3 yr (Kimmerer et al. 2000). The available data do not support previously suggested relationships between recruitment and freshwater flow during early life, or between gross estimates of pesticide input and survival of early life stages. We used a simple life-cycle model to show that various combined factors could have led to a decline in adult abundance, particularly a large and increasing adult mortality, but that events early in life probably did not contribute substantially to the decline. These results demonstrate that several decades of monitoring data from numerous life stages are needed to distinguish among alternative hypotheses about environmental influences on populations of estuarine fish.     

A comparison of the climatology of a tropospherestratosphere-mesosphere model with observations

Mean fields from a perpetual January simulation of a GCM extending from the surface to 0.01 hPa (near 80 km) are compared to observations. The zonal mean temperature and wind fields correspond quite well with reality; the low stratosphere, especially in the polar night, is too cold, but warmer than in the original version of the model, with an upper boundary at 25 hPa. Mean fields at standard levels show that the major features of the troposphere are represented by the model, but rather over emphasised; the stratospheric winter polar vortex is too strong, too cold, and too barotropic; it resembles an `undisturbed' January rather than the climatology. Differences in the stationary eddy activity between the extended and orginal versions of the model are noted, and used to explain some differences between the two simulations.This paper was presented at the International Conference on Modelling of Global Climate Change and Variability, held in Hamburg 11–15 September 1989 under the auspices of the Meteorological Institute of the University of Hamburg and the Max Planck Institute für Meteorology. Guest Editor for these papers is Dr. L. Dümenil     

Stratigraphy of the Toba Tuffs and the evolution of the Toba Caldera Complex,Sumatra, Indonesia

During the past 1.2 m.y., a magma chamber of batholithic proportions has developed under the 100 by 30 km Toba Caldera Complex. Four separate eruptions have occurred from vents within the present collapse structure, which formed from eruption of the 2800 km³ Youngest Toba Tuff (YTT) at 74 ka. Eruption of the three older Toba Tuffs alternated from calderas situated in northern and southern portions of the present caldera. The northern caldera apparently developed upon a large andesitic stratovolcano. The calderas associated with the three older tuffs are obscured by caldera collapse and resurgence resulting from eruption of the YTT. Samosir Island and the Uluan Block are two sides of a single resurgent dome that has resurged since eruption of the YTT. Samosir Island is composed of thick YTT caldera fill, whereas the Uluan Block consists mainly of the Oldest Toba Tuff (OTT). In the past 74000 years lava domes have been extruded on Samosir Island and along the caldera's western ring fracture. This part of the ring fracture is the site of the only current activity at Toba: updoming and fumarolic activity. The Toba eruptions document the growth of the laterally continuous magma body which eventually erupted the YTT. Repose periods between the four Toba Tuffs range between 0.34 and 0.43 m.y. and give insights into pluton emplacement and magmatic evolution at Toba.