Thermal convection of soil air on hillsides

Although diffusion is usually considered to be the main transport process for volatile constituents in the unsaturated zone of soils and other surficial materials, an alternative process of thermally driven convection may be significant, especially on hillsides and over irregular bedrock. Convection in this mode is driven by buoyancy forces arising from differences in soil-air density in a temperature gradient. For bodies with sloping boundaries, the conventional Rayleigh criterion is not directly applicable, so that flow of air is possible in a wide variety of situations. Numerical simulations for several simple cases show that air convection is expected within relatively permeable materials such as sandy soils, gravel deposits, and talus on slopes.     

Studies of volcanic ash from two recent Central American eruptions

The 1971 eruptions of Cerro Negro volcano in Nicaragua and Fuego volcano in Guatemala produced ash blankets with minimum volumes of 7 × 10⁷ m³ and 6 × 10⁷ m³, respectively. Seven new chemical analyses show that ash produced by both eruptions was basaltic and similar to previously — erupted lavas of both volcanoes. Both ash blankets were sampled areally and stratigraphically before they were affected by rain. Chemical analyses of soluble materials leached from these ashes show that near the end of both eruptions the concentrations of soluble materials increased by about an order of magnitude. These changes are believed to reflect changes in the composition of eruptive gases.     

Nuée ardente from santiaguito volcano April 1973

The largest nuée ardente eruption of Santiaguito since November 1929, occurred April 19, 1973. The nuée descended the valley of the Rió Nimá II for a distance of about 4 km. The ash flow itself was restricted to the river bed, but the hot gas cloud devastated an area of more than 3 square kilometers extending hundreds of meters on both sides of the river bed. Because the ash cloud stopped about 2 km from the nearest habitations, there were no fatalities.     

Cl,F, and SO2 in Central American volcanic gases

The Cl, F, SO₂ contents and Cl/F and Cl/SO₄ ratios in Central American volcanic gases are examined. 10³?10⁵ tons SO₂ per day are given off during eruptions and 10² when a prominent vapor cloud persists between eruptive periods. Data regarding Cl and F and SO₄ from leachates, condensates, and incrustations are compared. Our data suggest circumpacific volcanoes are SO₂ poor relative to Cl and may be F poor although F is higher in basaltic Central American volcanoes than others.     

The Los Chocoyos Ash, guatemala: A major stratigraphic marker in middle America and in three ocean basins

The Los Chocoyos Ash, having erupted from vents near the Lake Atitlán caldera, Guatemala, is perhaps the largest Quaternary silicic pyroclastic unit in Central America. It consists of an underlying H-tephra member and an overlying ash-flow member. One-hundred-and-five samples of ash from the Guatemalan Highlands and deep-sea cores in the equatorial Pacific and Gulf of Mexico were analyzed by neutron activation and/or electron microprobe. Glass shard chemistry, determined by microprobe, is useful for distinguishing several very widespread, distinct, deep-sea ash layers, but needs support from trace-element data when applied on land to distinguish between many individual eruptions from the same province. Data from this study support the correlation of the Worzel ‘D’ layer and the Los Chocoyos Ash proposed by Hahn et al. (1979) and Bowles et al. (1973). Chemical data from this study are used to correlate the Y-8 ash layer of the Gulf of Mexico with the Los Chocoyos Ash. The recognition of the Los Chocoyos Ash in the Gulf of Mexico and equatorial Pacific increases the known areal extent of the unit to more than 6 × 10⁶ km² and allows an age of 84,000 yr B.P. to be assigned to the formation on the basis of oxygen-isotope stratigraphy, biostratigraphy, and Pa-Th-isotope data. Trace-element data obtained from seven other ash layers in the Gulf of Mexico and the equatorial Pacific, when combined with new land-based data, should allow further correlation and dating of ash units in Central America.     

Notes on the 1902 eruption of Santa María volcano,Guatemala

The first historic activity of Santa María volcano, Guatemala constituted one of the ten largest historic eruptions in the world, producing 5.5 km³ of debris. In hindsight, the six-month period before the October 1902 eruption was one of extremely abnormal seismicity in all of western Guatemala. The pyroclastis from the eruption were scattered widely over Western Guatemala and Southern Mexico and also caused world-wide atmospheric effects. The volcanics produced were of andesitic-dacitic composition, but there was wide variation from place to place in the sampled material — a fact apparently chiefly attributable to atmospheric-fractionation. There was apparently a change in chemistry of ash during the two-day eruption as well, the first, most voluminous ash was pumicious and white; later ash was finer, denser, darker, and slightly less silicious. The kinetic energy/thermal energy partition is determined to be similar to the value derived for Krakatoa,E _k/E _th ? 5.0 %. The thermal energy of the eruption was estimated at 4.2×10²⁵ ergs. The explosion crater left on Santa María’s southwest flank after the eruption had a volume equal to less than 0.5 km³, a small fraction of the volume of material erupted. The two-day 1902 blast has greatly overshadowed subsequent activity; extrusion of the Santiaguito dome, which has occurred since 1922 in the explosion crater, has produced about 0.7 km³ of dacite lava and 1.6×10²⁵ ergs of thermal energy in 48 years of activity.     

Lake-Sediment Evidence for Local and Remote Sources of Atmospherically Deposited Pollutants on Svalbard

Twenty-one lakes along the west coast of Svalbard were cored between 28 July and 14 August 1995. Five cores were ²¹⁰Pb dated and analysed for spheroidal carbonaceous particles (SCPs), indicators of deposition from fossil-fuel combustion sources, and trace metals. Surface and pre-industrial levels of five cores were analysed for 10 polychlorinated biphenyl (PCB) isomers and 16 polycyclic aromatic hydrocarbon (PAH) compounds, whilst all 21 surface sediments were analysed for SCPs. Temporal and spatial trends in the atmospheric deposition of pollutants were identified. Whilst temporal patterns of deposited pollutants may have been truncated due to concentrations falling below the limits of detection, spatial patterns showed elevated levels of SCP, PAH, PCB, and possibly Pb within 60–70 km of Isfjord. Tenndammen (U), the closest site to Longyearbyen, showed the highest levels of contamination for all pollutants. Differences in the deposition patterns of PAH and PCB are thought to be due to local sources of PAH from coal combustion whilst PCB sources are remote. It is concluded that the impact from atmospheric deposition on Svalbard is due to a combination of spatially limited local sources superimposed on a broad-scale, long-range pattern.