Formation of cordierite-bearing lavas during anatexis in the lower crust beneath Lipari Island (Aeolian arc,Italy)

Cordierite-bearing lavas (CBL;~105 ka) erupted from the Mt. S. Angelo volcano at Lipari (Aeolian arc, Italy) are high-K andesites, displaying a range in the geochemical and isotopic compositions that reflect heterogeneity in the source and/or processes. CBL consist of megacrysts of Ca-plagioclase and clinopyroxene, euhedral crystals of cordierite and garnet, microphenocrysts of orthopyroxene and plagioclase, set in a heterogeneous rhyodacitic-rhyolitic groundmass containing abundant metamorphic and gabbroic xenoliths. New petrographic, chemical and isotopic data indicate formation of CBL by mixing of basaltic-andesitic magmas and high-K peraluminous rhyolitic magmas of anatectic origin and characterize partial melting processes in the lower continental crust of Lipari. Crustal anatectic melts generated through two main dehydration-melting peritectic reactions of metasedimentary rocks: (1) Biotite + Aluminosilicate + Quartz + Albite = Garnet + Cordierite + K-feldspar + Melt; (2) Biotite + Garnet + Quartz = Orthopyroxene + Cordierite + K-feldspar + Melt. Their position into the petrogenetic grid suggests that heating and consequent melting of metasedimentary rocks occurred at temperatures of 725 < T < 900°C and pressures of 0.4–0.45 GPa. Anatexis in the lower crust of Lipari was induced by protracted emplacement of basic magmas in the lower crust (~130 Ky). Crustal melting of the lower crust at 105 ka affected the volcano evolution, impeding frequent mafic-magma eruptions, and promoting magma stagnation and fractional crystallization processes.     

Seismic waves generated by oscillating buildings: analysis of a release test

A three-stories, base-isolated building located in Rapolla (Potenza, Italy) was tested with a snap-back experiment. Free-field measures were performed using 3D seismometers, located at 10 and 50 m from the buildings in direction of motion and at 10 m from the building in direction transverse to the motion. At each measurement point it was possible to separate the soil amplification effects from two source terms, due to the base-isolated building and to the reaction block. The ground motion was noticeable: at 10 m in the longitudinal direction it was comparable with a small size, near-field earthquake.     

Testing a theoretical resistance law for overland flow on a stony hillslope

Overland flow, sediments, and nutrients transported in runoff are important processes involved in soil erosion and water pollution. Modelling transport of sediments and chemicals requires accurate estimates of hydraulic resistance, which is one of the key variables characterizing runoff water depth and velocity. In this paper, a new theoretical power–velocity profile, originally deduced neglecting the impact effect of rainfall, was initially modified for taking into account the effect of rainfall intensity. Then a theoretical flow resistance law was obtained by integration of the new flow velocity distribution. This flow resistance law was tested using field measurements by Nearing for the condition of overland flow under simulated rainfall. Measurements of the Darcy–Weisbach friction factor, corresponding to flow Reynolds number ranging from 48 to 194, were obtained for simulated rainfall with two different rainfall intensity values (59 and 178 mm hr⁻¹). The database, including measurements of flow velocity, water depth, cross-sectional area, wetted perimeter, and bed slope, allowed for calibration of the relationship between the velocity profile parameter Γ, the slope steepness s, and the flow Froude number F, taking also into account the influence of rainfall intensity i. Results yielded the following conclusions: (a) The proposed theoretical flow resistance equation accurately estimated the Darcy–Weisbach friction factor for overland flow under simulated rainfall, (b) the flow resistance increased with rainfall intensity for laminar overland flow, and (c) the mean flow velocity was quasi-independent of the slope gradient.     

Ages, Metallicities and Abundances in Elliptical Galaxies

In this paper we present a recent attempt to infer the age, metallicity and abundance ratios for a selected sample of elliptical galaxies, adopting the line-strength indices H_β, Mg₂ and 〈Fe 〉, which respond in different ways to different parameters such as age (H_β), metallicity and abundance ratios (〈Fe〉 and Mg₂). This revised version was published online in July 2006 with corrections to the Cover Date.     

First rocks sampled in Antarctica (1840): Insights into the landing area and the Terre Adélie craton

In January 1840, Dumont d’Urville's expedition landed along the coast of “Terre Adélie” and took three rock specimens, the first ever sampled on the Antarctic continent. The petrological and geochemical study of these samples, stored at the “Muséum national d’histoire naturelle”, in Paris, characterizes them as migmatitic cordierite + microcline-bearing paragneiss and mesocratic quartz + biotite-bearing amphibolite. The paragneiss reached 670 °C at 3.2 kbar, suggesting an abnormal high-T gradient of ca. 60 °C/km during the regional metamorphism that affected the “Terre Adélie” craton 1.7 Ga ago. The studied samples are identical to the rocks observed at the “Rocher du Débarquement”, confirming that this was the actual landing place. On the other hand, quartz diorite and volcanic rocks reportedly sampled in Adélie Land during the same expedition and stored at Le Mans and Toulouse Museums do not originate from Antarctica. The examination of Dumont d’Urville's map suggests an icecap shrinking by 9 km in the landing area since 1840.     

Zircon U–Pb geochronology of lower crust and quartzo-feldspathic clastic sediments from the Balagne ophiolite (Corsica)

The Balagne ophiolite from central-northern Corsica represents a continent-near paleogeographic domain of the Jurassic Liguria-Piedmont ophiolitic basin. Pillow and massive basalt lavas are primarily associated with Middle–Upper Jurassic pelagic sediments (mostly radiolarites at their base), continental-derived quartzo-feldspathic clastic sediments and ophiolitic breccias containing clasts of gabbros and basalts. The basalt-sedimentary succession is tectonically associated with a slice composed of an intrusive sequence overlain by basalt lavas. A “plagiogranite” from the intrusive sequence was dated by U–Pb zircon geochronology. Although affected by some uncertainty, mainly reflecting common Pb contamination, the U–Pb zircon data suggest a crystallization age of 159 ± 3 Ma (MSWD = 6.3), which is coeval with the formation of oceanic lower crust in the Schistes Lustrés units from Alpine Corsica. The predominance of quartz grains preserving typical volcanic shape, the prevalence of prismatic zircons and the arkose whole-rock composition indicate that the continental-derived quartzo-feldspathic clastic sediments have a low degree of textural maturity. U–Pb zircon geochronology carried out on two distinct levels of quartzo-feldspathic clastic sediments identified the predominance of zircons with within error U–Pb dates at ~280 Ma; minor components at ~457, ~309 and ~262 Ma were also obtained. The U–Pb date distribution is consistent with a source magmatic material mostly developed during the Variscan orogenic collapse.     

Geochemistry and Sr-Nd isotopes of amphibolite dykes of northern Victoria Land, Antarctica

Mafic dykes cutting the gneisses and migmatites in the Deep Freeze Range high-grade metamorphic complex of northern Victoria Land, Antarctica, have undergone strong recrystallization and deformation during amphibolite-facies metamorphism. Metamorphic mobility mostly affected the large-ion lithophile elements (LILE). Rare Earth (RE) and the high field-strength elements (HFSE) were essentially immobile during metamorphism. Together with the major-element geochemistry, this suggests primary characteristics of evolved tholeiitic magmas and mafic cumulates. No precise ages of intrusion are available for the dykes, but geological evidence suggest emplacement during the time interval 800 to 900 Ma. The Rb-Sr isotopic system in some of the dykes were also variably affected by a later thermal event, probably coincident with the time of amphibolite metamorphism, ca. 500–550 Ma ago. This event can be correlated with the Ross Orogeny in the Transantarctic Mountains. Nd isotopes and trace element abundances indicate that the dykes were derived by different degrees of partial melting and fractionation of heterogeneous sub-continental lithospheric mantle. The Nd isotopic compositions range from depleted to enriched signatures (ε^Nd computed back to 850 Ma = +4.5 to −11.61), and are coupled to different trace element normalized patterns characterized by a slight positive Nb anomaly in the former case to a strong negative Mb anomaly for the latter samples. On isotopic and chemical ground the depleted signature of the mantle source resembles that reported for E-type MORB. The nature of the enriched components cannot be uniquely stated; nevertheless, on the basis of isotopic and geochemical data, it could be represented by sediments recycled into the sub-continental mantle or by crustal contamination during underplating of mafic magmas, or a combination of the two processes.     

Chemical alteration of volcanic glasses and related control by secondary minerals: Experimental studies

A detailed experimental mineralogical and geochemical study on hydrothermal alteration processes of volcanic glasses with a different chemical composition and leucites sampled in the Roman Comagmatic Region was carried out. 2g samples of different grain sizes and 50 ml of deionized water or seawater were sealed in bronze Teflon-lined autoclaves and placed in a rotating sample-holder at 200°C. The internal pressure was 16.2 bars. At arbitrary intervals, the pressure vessel was quenched to room temperature and both solids and solutions were separated by filtration. The solids were used to identify possible alteration products by means of X-ray powder diffraction, SEM and microprobe analyses. In all deionized water systems the contact solution reached pH basic values, but in the various systems the consumption of H⁺ ions occurred in different ways. This is probably linked to different concentrations of released cations. In seawater systems, however, pH values initially fell sharply but subsequently increased slightly. After 2 days, cation concentrations were clearly buffered by reaction products in all solutions. These were mainly zeolites and clay minerals. The following crystallization sequences in all glass/deionized water experiments were observed: the first reaction product was represented by phillipsite, followed by analcime and illite in the alkali-trachytic run; chabasite and analcime in the phonolitic-tephritic run; analcime and finally feldspar in shoshonitic and trachytic runs. Phillipsite and smectite crystallized together only in the basaltic run. In leucite/deionized water systems, however, the first reaction phase was illite, followed by analcime and then phillipsite. The reaction products in glass/seawater systems were smectite and anydrite. The chemical composition of synthetic zeolites was clearly controlled by the chemistry of initial glasses. These synthetic zeolites are like the natural ones in volcaniclastic products from central and southern Italy. This suggests that extensive zeolitization processes of these volcaniclastic rocks may occur through interaction of volcanic glasses with fluids at a very low salinity and a temperature close to 200°C.     

The PAH composition of surface sediments from Stagnone coastal lagoon, Marsala (Italy)

This paper examines the presence, distribution, nature and sources of 22 Aromatic Hydrocarbons (PAHs), which are important environmentally and toxicologically, in sediments from the Stagnone coastal lagoon at Marsala (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM). The total concentration of polycyclic aromatic hydrocarbons ranged from 72 to 18381 μg/kg of dry matrix. The relative standard deviation (RSD) of the replicates on the concentrations of individual compounds ranged from 5% to 20%. The accuracy of method was estimated by analyzing “blank” samples added of known quantities of analytes and the recover percentage was 88 ± 9%. The detection limit (LOD) of analytical procedure was less than 0.2 μg/kg d.w. for all analytes. The quantification limit (LOQ) of analytical procedure was less than 0.7 μg/kg d.w.The resulting distributions and weight ratios of specific compounds are discussed in terms of sampling location and origin of organic matter. A comparison with other studies of total PAHs suggests that the levels are within the concentration ranges already reported by other authors. From an eco-toxicological point of view, total PAH concentrations at seven out of the eight sites studied represent a relatively clean environment when compared to other sites.Organic matter content and PAH concentrations were found to be correlated and the compounds present in Stagnone sediments were shown to be mainly of pyrolitic origin, while a negligible quantity of PAHs may derive from biogenic sources since all the sediments contain perylene traces. There is no evidence of coal-tar contamination.Cluster analysis was carried out in order to discriminate between different PAH origins.