Multi-methodological investigation of kunzite, hiddenite, alexandrite, elbaite and topaz, based on laser-induced breakdown spectroscopy and conventional analytical techniques for supporting mineralogical characterization

Gem-quality alexandrite, hiddenite and kunzite, elbaite and topaz minerals were characterized through a multi-methodological investigation based on EMPA-WDS, LA-ICP-MS, and laser-induced breakdown spectroscopy (LIBS). With respect to the others, the latter technique enables a simultaneous multi-elemental composition without any sample preparation and the detection of light elements, such as Li, Be and B. The criteria for the choice of minerals were: (a) the presence of chromophore elements in minor contents and/or as traces; (b) the presence of light lithophile elements (Li, Be and B); (c) different crystal chemistry complexity. The results show that LIBS can be employed in mineralogical studies for the identification and characterization of minerals, and as a fast screening method to determine the chemical composition, including the chromophore and light lithophile elements.     

Low VS crustal zones in the Campanian Plain (Southern Italy)

Shear wave velocities of the lithospheric structure to 73 km depth have been defined along three profiles crossing the Campanian Plain (Southern Italy) from the simultaneous non linear inversion of the local and regional dispersion data. The former consist of group velocity dispersion data obtained from some seismic events which occurred at the borders of the Campanian Plain and recorded at Napoli, and the latter of group and phase dispersion data obtained in previous studies. The main features of the representative V_S models are a carbonate basement deepening to ～5 km in the central part of the Plain and a low velocity zone at a depth of ～15 km, rising to 7 km in the southern part, close to Somma-Vesuvio. The low velocity layer can be correlated with that found at ～10 km of depth below Campi Flegrei and the Neapolitan area, and at 5 km below the Somma-Vesuvio caldera area. Such regional velocity reduction can be associated to the presence of a zone with less than 5% partial melting that can be interpreted as magmatic reservoir of the Campanian volcanism.     

Vertical distribution of two sympatric labrid fishes in the Western Mediterranean and Eastern Atlantic rocky subtidal: local shore topography does matter

Changes in the shore topography (e.g. slope) occur at a scale of hundreds of meters in several locations in the Lusitanian and the Mediterranean Sea provinces. We tested whether differences in the bottom inclination might affect the vertical distribution patterns of two sympatric coastal labrid fishes, the rainbow wrasse Coris julis and the ornate wrasse Thalassoma pavo. Visual censuses were used to determine the distribution and abundance of these labrid species in high (≥30°) and low (≤3°) slope rocky substrates covered by brown macroalgae and at two different depths (shallow, 4–7 m, and deep 14–20 m). Pectoral fin aspect ratio was used as an estimate of swimming performance to potentially explain the patterns observed. Despite the intrinsic biogeographical differences in the overall density of T. pavo and C. julis, on steep coasts the ornate wrasse dominated in shallow waters, whereas the two species coexisted both in shallow and deeper depths on gentle slope coasts. These distribution patterns were consistent across locations, and fin aspect ratio was not a good predictor of between‐habitat use for wrasses. We show that, under specific topographical conditions, the depth segregation pattern seems to be an interactive segregation (likely related to resource competition) rather than a result of selective segregation due to morphological differences in the pectoral fin. Significant ecological changes might occur in locations where the density of T. pavo has recently increased as a result of water warming.     

A laser altimeter for BepiColombo mission: Instrument design and performance model

This paper presents a definition study of a laser altimeter for the topographic exploration of Mercury. The reference scenario is the BepiColombo mission, a cornerstone mission of European Space Agency (ESA) planned for 2012. BepiColombo will offer the chance to make a remarkable new contribution to our knowledge of the Solar System, by venturing into the hot region near the Sun and exploring Mercury, the most enigmatic of the earth's sisters among the terrestrial planets. First images of Mercury surface were acquired by Mariner 10 in 1974 and 1975 offering a coverage and resolution comparable to Earth-based telescopic coverage of the Moon before spaceflight. BepiColombo mission can be very beneficial by using an optical rangefinder for Mercury exploration. In fact starting from the first missions in 1970s until today, laser altimeters have been demonstrating to be particularly appropriate as part of the scientific payload whenever the topography of earth, lunar and planetary surface is the scientific objective of a space mission.Our system design is compliant to Mercury Polar Orbiter (MPO) of the mission. System performance analysis is carried out simulating main hermean topographic features and the potential targets on the planet by means of analytical models and computer codes and several plot are presented to analyse the performance of the instrument.     

Peculiar earthquake damage on a reinforced concrete building in San Gregorio (L��Aquila, Italy): site effects or building defects?

In San Gregorio (L’Aquila, Italy) a three-story, reinforced concrete (RC) building had the first floor collapsed following the earthquake of April 6, 2009. The remaining two stories fell with a displacement in the horizontal projection of about 70 cm. This unusual behaviour is made more puzzling by the fact that buildings located at a short distance and with similar features had little or no damage reported. To understand the causes of the collapse we performed strong motion recordings, microtremor measurements, a detailed geological survey, a high-resolution geo-electrical tomography, a borehole with a down-hole test. On the building we performed a geometrical survey and laboratory tests on concrete cores. The acceleration and noise recordings have shown a high amplification with uphill-downhill direction. The geological survey has revealed the presence of co-seismic fractures on stiff soils. Geo-electrical tomography has shown an unexpected, strong discontinuity just below the building. Taking advantage of excavations in adjacent lots, we have highlighted rare cataclastic decimetric bands with a very low resistance material incorporated in well-stratified calcarenites. The same soft material has been founded in the borehole down to 17 m from ground level, showing a shear wave velocity that starts at 250 m/s, increases with depth and has an abrupt transition in calcarenites at 1,150 m/s. The surface geophysical measurements in the vicinity of the site have not shown similar situations, with flat HVSR curves as expected for a rock outcrop, except for a lateral extension of the soft zone. The analysis on the quality of the building materials has yielded values higher than average for the age and type of construction, and no special design or construction deficiencies have been observed. A strong, peculiar site effect thus appears to be the most likely cause of the damage observed.     

Comparing flow resistance law for fixed and mobile bed rills

Rills caused by run‐off concentration on erodible hillslopes have very irregular profiles and cross‐section shapes. Rill erosion directly depends on the hydraulics of flow in the rills, which may differ greatly from hydraulics of flow in larger and regular channels. In this paper, a recently theoretically deduced rill flow resistance equation, based on a power–velocity profile, was tested experimentally on plots of varying slopes (ranging from 9% to 26%) in which mobile and fixed bed rills were incised. Initially, measurements of flow velocity, water depth, cross‐section area, wetted perimeter, and bed slope, carried out in 320 reaches of mobile bed rills and in 165 reaches of fixed rills, were used for calibrating the theoretical flow resistance equation. Then the relationship between the velocity profile parameter Γ, the channel slope, and the flow Froude number was separately calibrated for the mobile bed rills and for the fixed ones. The measurements carried out in both conditions (fixed and mobile bed rills) confirmed that the Darcy–Weisbach friction factor can be accurately estimated using the proposed theoretical approach. For mobile bed rills, the data were supportive of the slope independence hypothesis of velocity, due to the feedback mechanism, stated by Govers. The feedback mechanism was able to produce quasicritical flow conditions. For fixed bed rills, obtained by fixing the rill channel, by a glue, at the end of the experimental run with a mobile bed rill, the slope independence of the flow velocity measurements was also detected. Therefore, an experimental run carried out by a rill bed fixed after modelling flow action is useful to detect the feedback mechanism. Finally, the analysis showed that, for the investigated conditions, the effect of sediment transport on the flow resistance law can be considered negligible respect to the grain roughness effect.     

An automatic approach for rill network extraction to measure rill erosion by terrestrial and low‐cost unmanned aerial vehicle photogrammetry

For an erosion event (October 2016) occurred at the Sparacia experimental area (Southern Italy), both terrestrial and low‐altitude aerial surveys were carried out by consumer grade camera and quadcopter (low‐cost unmanned aerial vehicle [UAV]) to measure rill erosion on two plots with steepness of 22% and 26%. Applying the structure from motion (SfM) technique, the three‐dimensional digital terrain models (3D‐DTMs) and the quasi three‐dimensional models (2.5D‐digital elevation model [DEM]) were obtained by the two surveys. Furthermore, 3D‐DTM and DEM were built using the available aerial photographs (166) and adding 40 terrestrial photographs. For the first time, the convergence index was applied to high‐resolution rill data for extracting the rill network, and a subsequent separation into contributing and non‐contributing rills was carried out. The comparison among the three surveys (terrestrial, UAV, and UAV + terrestrial) was developed using two morphometric parameters of the rill network (drainage density and drainage frequency). Moreover, using as reference the weight of sediment stored on the tanks located downstream of the plots, the reliability of soil loss measurement by 3D models was tested. For both contributing and non‐contributing rills, the morphometric parameters were higher for the terrestrial than for UAV and UAV + terrestrial surveys. For both plots, SfM always provided reliable soil loss measurements, which were affected by errors ranging from ?8% to 13%. Although the applied technique used a low‐cost UAV and a consumer grade camera, the obtained results demonstrated that a reliable estimate of rill erosion can be obtained in an area of interest.