Coloured dissolved organic matter (CDOM) in Southern North Sea waters: Optical characterization and possible origin

The variability and origin of the Coloured Dissolved Organic Matter (CDOM) were studied in the Belgian coastal and adjacent areas including offshore waters and the Scheldt estuary, through the parameters: absorption at 375 nm, a_CDOM(375), and the slope of the absorption curve, S. a_CDOM(375) varied between 0.20 and 1.31 m⁻¹ and between 0.97 and 4.30 m⁻¹ in the marine area and Scheldt estuary, respectively. S fluctuated between 0.0101 and 0.0203 nm⁻¹ in the marine area and between 0.0167 and 0.0191 nm⁻¹ in the Scheldt estuary. The comparative analysis of a_CDOM(375) and S variations evidenced different origins of CDOM in the BCZ. The Scheldt estuarine waters showed decreasing a_CDOM(375) values with increasing salinity but constant S value of ∼0.018 nm⁻¹ suggesting a dominant terrestrial origin of CDOM. On the contrary, samples collected in the marine domain showed a narrow range of a_CDOM(375) but highly variable S suggesting the additional presence of autochthonous sources of CDOM. This source was evidenced based on the sorting of the marine offshore data according to the stage of the phytoplankton bloom when they were collected. A clear distinction was made between CDOM released during the growth stage characterized by high S (∼0.017 nm⁻¹) and low a_CDOM(375) and the decay phase characterized by low S (∼0.013 nm⁻¹) and high a_CDOM(375). This observation was supported by CDOM measurements performed on pure phytoplankton cultures which showed increased CDOM release along the wax and wane of the bloom but decreasing S. We concluded that the high variability of the CDOM signature in offshore waters is explained by the local biological production and processing of CDOM.     

Estimating the economic impact of the Prestige oil spill on the Death Coast (NW Spain) fisheries

This paper presents an estimation of the economic effects of the Prestige oil spill in Galicia, focusing on the Death Coast fisheries and using fish landings as a market technique. Examining the evolution of landings in the Death Coast before and after the accident, the analysis reveals two opposing trends, with landings of some species increasing and those of other species diminishing.     

Numerical Simulation of Water Level Under Interaction Between Runoff and Estuarine Dynamics in Tidal Reach of the Yangtze River

The Yangtze Estuary, the largest estuary in China, is under an obvious interaction between runoff and astronomical tide. The research on the interaction is very important for the exploitation and utilization of water resources in this area. A horizontal 2D hydrodynamic numerical model is established and verified in the present study with the modeling range from Datong to the Yangtze Estuary. Based on the comparison of high water levels under the interaction between different runoff and estuarine dynamics, s...     

Study on General Performance of Jack-up Under Elevated Condition

Method of checking for jack-up elevated performance including leg structure strength, fixation system or jacking system bearing capacity, pre-load requirements, spud can bearing capacity and overturning stability is suggested in this paper. As an example, a jack-up with truss legs is analyzed by finite element analysis method. This paper may be helpful to the rig owners, operators and designers.     

Effect of Fly Ash on Frost-Resistance and Chloride Ions Diffusion Properties of Marine Concrete

It is necessary to pay more attention to the durability of concrete undergoing freeze-thaw cycles and seawater attack simultaneously.Investigated are the effects of water-binder ratio,fly ash (FA) contents and air-entraining agent on resistance to frost and chloride diffusion of marine concrete blended with FA in natural seawater.The results show that fly ash does not improve the frost resistance of concrete but can improve its resistance to chloride diffusion by addition of less than 30%.The resistance to frost and chloride diffusion of FA concrete can be improved with the decrease of water-binder ratio,and FA may improve both of them simultaneously only being mixed with air-entraining agent.A ratio (named as R) of the frost-resisting durability factor to chloride diffusion coefficient can be used to evaluate the durability of marine concrete.Scanning electron microscope (SEM) analyses are consistent with the evaluations by the value of R.     

Theoretical Analysis of A Buoyant Jet Interacting with Small Amplitude Waves

A new theoretical solution is presented here for the dynamic characteristics of a buoyant jet due to opposing small amplitude waves.The conservation equations of mass,tangential momentum and vertical momentum are solved by the integral method which encompasses the Gaussian profiles of velocity and density.The action of waves is incorporated into the equations of motion as an external force and a new exact solution is obtained to predict the trajectory,velocity distribution and boundary thickness of the buoyant jet over an arbitrary lateral cross section.It is found that the velocity along the centerline is inversely proportional to the ratio of the momentum of the wave to the buoyant jet.The averaged boundary width varies with the fluctuation of the boundary width,the distance from the orifice and the velocity correction function.Owing to the motion d waves,the fluctuation of the boundary width is proportional to the wave steepness.     

Observations of the North Equatorial Current,Mindanao Current,and Kuroshio current system during the 2006/07 El Niño and 2007/08 La Niña

Two onboard observation campaigns were carried out in the western boundary region of the Philippine Sea in December 2006 and January 2008 during the 2006/07 El Niño and the 2007/08 La Niña to observe the North Equatorial Current (NEC), Mindanao Current (MC), and Kuroshio current system. The NEC and MC measured in late 2006 under El Niño conditions were stronger than those measured during early 2008 under La Niña conditions. The opposite was true for the current speed of the Kuroshio, which was stronger in early 2008 than in late 2006. The increase in dynamic height around 8°N, 130°E from December 2006 to January 2008 resulted in a weakening of the NEC and MC. Local wind variability in this region did not appear to contribute to changes in the current system.     

CPLat: first operational experimental processing center for SIRGAS in Argentina

The SIRGAS permanent GPS network which is in fact the IGS network densification for the American continent, consists today of more than 200 stations covering the continent and islands. It is currently processed by the IGS RNAAC SIR centre at Deutsches Geodätisches Forschungsinstitut producing weekly free solutions relying on IGS final orbits and EOP that contribute to the ITRF through IGS. By August 2006, the SIRGAS Working Group I had accepted five proposals for experimental processing centers within the region that would collaborate with IGS RNAAC SIR. One of them, Centro de Procesamiento La Plata (CPLat) in Argentina, began processing 60 stations on October 2006. By January 2007 CPLat reached operational capability, delivering weekly free solution SINEX files, with an internal consistency of 1.5 mm average for the horizontal components, and 3 mm in the vertical. Comparisons with IGS global and IGS RNAAC SIR weekly solutions were taken as external consistency indications, showing average RMS residuals of 1.8, 2.4 and 5 mm for the north, east, and vertical component, respectively. Analysis and comparison of adjusted solution time series from CPLat and other processing centers has proved to be highly valuable for solution QC, namely detection and identification of station anomalous behavior or modelling problems. These procedures will ensure the maintenance of the performance specifications for CPLat solutions. Action is being taken in order to guarantee the continuity of this effort beyond the experimental phase.     

Adsorption of cobalt by using inorganic components of sediment samples from water bodies

The adsorption of cobalt ions was evaluated using sediment samples from water bodies to investigate the adsorption properties of sediment and the behavior of these natural materials in the presence of nuclear and industrial waste.The two sediments(S1 and S2)were treated to eliminate humic and fulvic acids and then they were characterized by several techniques.The minerals found in both the sediments(X-ray diffraction)were quartz and albite;plus,goethite and muscovite in S1,and kaolinite and montmorillonite in S2.Point of zero charge(PZC)of S1 and S2 was 6.00 and 5.22,respectively.The specific area of S1(63.3 m²/g)is higher than S2(1.5 m²/g).Adsorption kinetics data for S1 and S2 were best fitted to the pseudo second-order model.The removal efficiency of S1 for cobalt was 96%with an adsorption capacity(qe)of 0.93 mg/g,and for S2 was 45%with a qeof 0.40 mg/g.The experimental data of the adsorption isotherms were adjusted to Langmuir and Freundlich models for S1 and S2,respectively.The thermodynamic parameters(enthalpy,entropy,and Gibb’s free energy)indicated that the adsorption processes were endothermic,spontaneous,and chemisorption mechanism.The results show that the adsorption capacities of the sediments depend on their composition.These water sediments have important adsorption properties for cobalt,and they can be used in the treatment of nuclear and industrial aqueous wastes.