Used Motor Oil as a Source of MTBE, TAME, and BTEX to Ground Water

Methyl tert-butyl ether (MTBE), the widely used gasoline oxygenate, has been identified as a common ground water contaminant, and BTEX compounds (benzene, toluene, ethylbenzene, and xylenes) have long been associated with gasoline spills. Because not all instances of ground water contamination by MTBE and BTEX can be attributed to spills or leaking storage tanks, other potential sources need to be considered. In this study, used motor oil was investigated as a potential source of these contaminants. MTBE in oil was measured directly by methanol extraction and gas chromatography using a flame ionization detector (GC/FID). Water was equilibrated with oil samples and analyzed for MTBE, BTEX, and the oxygenate tert-amyl methyl ether (TAME) by purge- and-trap concentration followed by GC/FID analysis. Raoult's law was used to calculate oil-phase concentrations of MTBE, BTEX, and TAME from aqueous-phase concentrations. MTBE, TAME, and BTEX were not detected in any of five new motor oil samples, whereas these compounds were found at significant concentrations in all six samples of the used motor oil tested for MTBE and all four samples tested for TAME and BTEX. MTBE concentrations in used motor oil were on the order of 100 mg/L. TAME concentrations ranged from 2.2 to 87 mg/L. Concentrations of benzene were 29 to 66 mg/L, but those of other BTEX compounds were higher, typically 500 to 2000 mg/L.     

Mercury in soils of the Long Valley, California, geothermal system

An evaluation of the Hg distribution in soils of the Long Valley, California, geothermal area, was made. A₁-horizon soil samples were collected utilizing a grid system from the resurgent dome area and the Long Valley area. In addition, samples were collected in five traverses across three fault systems and four traverses across east-west-oriented gullies to measure the importance of aspect. Additional samples were collected in an analysis of variance design to evaluate natural variability in soil composition with sampling interval distance.The primary objectives of this study were to further evaluate the applicability of anomalously high Hg concentration in soils to exploration for geothermal systems and the importance of secondary controls on Hg concentration in soils above geothermal systems.Statistical analysis indicates that there are two populations of Hg concentrations in soils; one affected by geothermal activity and the other unaffected. Samples from the resurgent dome are shown to be statistically different from the samples collected in Long Valley proper with respect to Hg, organic carbon, and pH. This suggests that secondary influences may be important in controlling Hg distribution in soils.Organic carbon in soils is shown by stepwise multiple regression to be the most important secondary parameter controlling Hg concentration. For the most part, the secondary controls of Hg are overwhelmed in an area of prominent geothermal activity. Some faults exhibit prominent anomalies in total Hg concentration and others do not, indicating the possibility of low levels of hydrothermal activity or effective sealing of faults to gas leakage.The analysis of variance results indicate that there is a regional trend in Hg concentration across the resurgent dome. Soils can be sampled for Hg by utilizing a grid of about 0.4 km spacing. However, some local irregularities appear in this pattern and anomalous areas should be prospected at intervals of 100 m or less.     

Fluid inclusions,deformation and recrystallization in granite tectonites

An investigation has been made of the relationships between tectonic processes and fluid inclusions in quartz from variably deformed and syntectonically recrystallized granitic rocks from the Lachlan Fold Belt, eastern Australia. The quartz contains many fluid inclusions which decorate healed fractures introduced as a result of late-stage brittle deformation. The majority of small inclusions however, are associated with deformation band boundaries and deformation lamellae showing that they have been introduced during or subsequent to ductile deformation. Fluid inclusions disappear from the cores of sub-grains during recovery and before recrystallization, and new inclusions which form along sub-grain boundaries coalesce into stringers. Inclusions are eliminated from both sides of low angle boundaries showing that inclusions leak their contents either through the system of dislocations which accompanies grain interior slip, or by a dissolution-condensation process whereby inclusion contents move by lattice diffusion and condense on the boundaries.     

The geochemical origin of sepiolite and kerolite at Amboseli,Kenya

A massive white sepiolite deposit at Amboseli precipitated from magnesium and silica released during the ground water dolomitization of an earlier lacustrine sepiolite. Kerolite has since formed in proximity to the massive sepiolite as an alteration product of sepiolite and as a ground water precipitate when the pH is below 8. Authigenic sepiolite also occurs in the overlying younger sediments. Kerolite is likely to occur but has not yet been positively identified.Presently, ground waters within the Amboseli Basin are supersaturated with respect to sepiolite and kerolite. This supersaturation results from the weathering of alkaline olivine basalts on the edge of the basin. The precipitation of sepiolite and/or kerolite does not control ground water compositions in the basin. These reactions are slow compared to other aqueous-mineral reactions such as those maintaining carbonate mineral equilibria. Equilibrium between disordered-dolomite and calcite buffers the log a _Mg2+/(a _H+)² as a function of log f _{CO 2} in ground waters in the proximity of the massive sepiolite. This reaction can help explain the presence of sepiolite associated with dolomites in other near-surface deposits besides Amboseli.     

Experimental analysis of folding in simple shear

Six experiments of single-layer folding with simple-shear boundary conditions were completed. Using materials of ethyl cellulose, the viscosity ratio of the stiff layer to matrix ranged from 20 to 100. The experiments were monitored by 10–14 photographs taken at equally spaced time intervals. Strain distributions in both the stiff layer and matrix were calculated from the displacements of over 300 ink dots distributed over the surface of each experiment. Both incremental strain (calculated from the relative displacements of the dots between successive photographs) and accumulating strain were determined on the two-dimensional profile of the materials as they folded.Symmetrical fold wavelengths occur and seem to be controlled by the wavelengths of initial perturbations in the stiff layer. If the Biot wavelength was not present initially, it will not occur in the final waveform. Consequently, in a group of natural folds, the mean value of wavelength/thickness ratios apparently reflects the initial perturbations. The mean value should not be confused with the Biot wavelength and should not be used to calculate viscosity ratios in naturally deformed rocks.Substantial layer thickening occurred only with viscosity ratios of 20. The amount of layer thickening also depends on initial perturbations of the stiff layer. If these perturbations are near the Biot wavelength, they are greatly amplified, the folds grow rapidly and layer thickening is small. If the perturbations are not near the Biot wavelength, amplification is small, the folds grow slowly and layer thickening is much greater.Principal elongations of the accumulated strain in the cores of some of the folds are not symmetrically distributed about axial planes and may cut across the axial plane at angles up to 20°. Strain shadows in the matrix, near the convex side of fold hinges, are also prominent. These triangular-shaped regions of low strain are not symmetrically disposed about fold axial planes, in contrast to strain shadows occurring in folds produced under pure-shear boundary conditions.The rotation of accumulating principal elongations in the stiff layer was calculated at fold inflections. Even though the folds themselves are generally symmetrical, these rotations at opposite fold inflections are not. One fold limb exhibits little rotation of principal elongations during folding while the other has rotations up to 70°. In contrast, folds formed in pure-shear boundary conditions have rotations of principal directions on opposite fold limbs equal in magnitude.     

Sr-isotopic studies of the origin of the Morin anorthosite complex,Quebec, Canada

Rb-Sr isotopic investigations of the rock-types within the Morin anorthosite complex, Quebec, suggest that: 1. both the mangerites and the leuconorites and anorthosites within this complex crystallized with a range of ⁸⁷Sr/⁸⁶Sr ratios, and 2. at least some of the mangerites crystallized approximately 100 m.y. after the anorthosites and leuconorites. From this evidence, it is argued that a number of magma sources gave rise to the melts that formed these rocks and that some local hybridization of these melts also took place by assimilation of other rock types. This same pattern is found in the Adirondack and Nain Complexes.     

Effects of pressure on the micromechanics of faulting in San Marcos gabbro

Samples of San Marcos gabbro were deformed to both pre- and post-failure stages at confining pressures of 100, 250 and 350 MPa. Scanning electron microscope observations were performed on the samples after ion-milling. The unstressed gabbro has insignificant crack porosity but a high volume fraction of healed and sealed cracks. Extensive stress-induced cracking at high angles to the maximum compressive stress is observed at the two higher pressures. Such high-angle cracks are mostly associated with the pre-existing healed cracks or cleavage planes, and they control the geometry and length scale of crack networks in plagioclase. Intensive kinking in biotite is widely observed at 350 MPa pressure, which together with the crack networks control the brittle fracture process. Stress-induced cracks in samples deformed at 100 MPa pressure are predominantly subparallel to the maximum compressive stress, and their coalescence leads to shear localization.Quantitative measurements of crack density as a function of differential stress indicate that crack interaction is appreciable beyond about 90% peak stress for all three pressures. The data also show significant decreases in stress-induced anisotropy as pressure increases, suggesting that there may be a threshold pressure beyond which stress-induced anisotropy vanishes with the onset of cataclasis.     

Precise distance measurements in Iceland

Precise distance measurements made on four networks of permanent benchmarks situated on the active axes of Iceland during the four-year period 1968–1972 showed that a combination of left-lateral and extensional movement is occurring on the Reykjanes Peninsula in southwest Iceland at a rate of about 9 mm per year. Elsewhere in Iceland, the movements, if they exist, are too small to be detected. Measurements from a geothermal area in southwest Iceland showed also that large horizontal movements occur in the vicinity of producing geothermal wells.     

Vegetation and associated environments during the past 14,000 years near Moulton Pond,Maine

Pollen influx and percentage diagrams were prepared from an 11.4 m core from Moulton Pond, Maine. The pond basin was deglaciated about 14,000 y. a., after which it was located on an island in a sea of subarctic character until about 12,400 y. a. when the surrounding area emerged from the sea. The terrestrial vegetation was tundra until about 10,000 y. a. A change in the tundra vegetation is synchronous with the emergence from the sea, but synchroneity with the Pineo Ridge glacial readvance, which reached its maximum 50 km to the east of the pond about 12,700 y. a., is also possible because of imprecision in the dating. Comparisons of the Moulton Pond results with late-glacial pollen sequences elsewhere in eastern United States and adjacent Canada reveal a lack of synchroneity in vegetational changes casting doubt on claims of major broad-scale climatic shifts over the entire area.The tundra period at Moulton Pond ended with a transition of a few hundred years to partly open, relatively xeric forests of low diversity dominated by white pine, oak, and birch trees. There was no intervening boreal forest. In the postglacial period the vegetation was continually changing, including in the early portion a series of immigrations of temperate tree taxa which later became important in the forests. The transient nature of these assemblages is further indicated by their differences from the closest modern analogs. From about 7100 y. a. until settlement by Europeans 200 y. a., the forests were closed. A major decline of conifers centering about 4700 y. a. was followed by maxima of mesic hardwoods about a thousand years later. In the most recent 2000 yr, the pollen record suggests greater environmental severity, evidenced by increasing spruce. But for the entire postglacial period, the closest modern vegetational analogs are all in the conifer-hardwood region. Much of the postglacial pollen sequence is inexplicable in climatic terms, as evidenced by nonsynchronous behavior of hemlock and beech.The pollen influx diagram is useful for distinguishing tundra from forest, but for the postglacial period it is difficult to interpret. Pollen influx data are strongly affected by shifts in the pattern of sedimentation in lakes. We propose that such shifts account for the major changes in influx in mid- and late-postglacial time at Moulton Pond and at Rogers Lake, Connecticut. This complicates the interpretation of influx data which otherwise are superior to percentage data.