The kinematics of gouge deformation

The methods and first results of a new approach to examining fault gouge are described. Samples of undisturbed fault gouge from the exhumed Lopez fault zone in the San Gabriel Mountains, California were impregnated with low viscosity epoxy resin and sectioned to produce microscope slides. The slides were photographed using optical and electron microscopy with magnifications ranging in factors of 2 from 12.5 to 1600. At all scales, the particles appeared angular with planar faces, suggesting tensile failure. No shear zones were discernable. The particle size distribution was studied. At each magnification the particles were sorted by diameter into four classes, differing in mean diameter by factors of 2. The numbers in each class were then scaled by the characteristic class dimension. The process revealed a remarkable degree of self-similarity. Over the range examined, the fractal dimension was within 5% of 2.60.On the basis of the observations, a new model for the mechanical processes that generate gouge is offered. It is argued that self-similarity results from repeated tensile splitting of grains. Unlike earlier models that consider splitting probability to be either independent of particle size or due to the preexisting distribution of defects, we propose that failure probability depends largely on the relative size of nearest neighbors. If nearest neighbors of the same size are preferentially broken, any initial distribution of particles will tend toward a self-similar distribution having a fractal dimension of 2.58.The model allows us to outline a procedure whereby the observed comminution in a fault zone can be related to the shear strain that the zone has accommodated and propose a theoretical frequency magnitude relation for the seismic energy emitted by the fracture process.     

A wind-profile index for canopy flow

Canopy wind profiles can often be represented by an exponential function. The associated attenuation index,a, is found to be proportional to [(Flexibility)(Leaf Area)(Density)]^1/3. Leastsquare values of the index have been calculated for wind profiles in about a dozen natural and artificial canopies which included oats, wheat, corn, rice, sunflowers, larch trees, citrus trees, Xmas trees, plastic strips, wooden pegs and bushel baskets. It is found that canopy flow is a function of canopy density, element flexibility, and height and that the behaviour of artificial canopy elements is compatible with that of natural vegetation. The same calculations also show that the attenuation coefficient: (a) is not a universal constant, (b) is however, rather limited in range (-0.3 to 3.0), (c) varies with stage of growth, and (d) increases as density and flexibility increase. A compilation ofa-values for several canopies reveals that lowa-values correspond to sparsely arrayed rigid elements while higha-values correspond to densely arrayed and flexible elements. Finally, lowa-values appear to be relatively independent of wind speed, while higha-values tend to increase as wind speeds increase.     

On the coupling of canopy flow to ambient flow for a variety of vegetation types and densities

A canopy flow coupling parameter is defined from earlier canopy flow research to describe the degree of coupling of air flow in vegetation to ambient flow of the surface boundary layer. This ratio concept employs an exponential wind-height relationship in the canopy referenced to the logarithmic wind-height relationship of the ambient air in close proximity to the vegetation interface. Qualitatively, the coupling ratio decreases as the index of canopy flow increases. Numerical criteria are derived to quantify the coupling upwind of the canopy, at the leading edge, through the transition zone, through the zone of established flow, at the trailing edge, and downwind from the canopy domain. It was found that coupling was relatively independent of element density for the more dense arrays, but increased rapidly as densities became more sparsely arrayed. A high degree of coupling existed both upwind and downwind of well-defined domains, while a degeneration of coupling is clearly evident through the zone of established flow. A seasonal contrast in coupling was also discerned. Gravity and slope flows contributed to a higher degree of coupling.     

Stable isotope systematics in mesozoic granites of Central and Northern California and Southwestern Oregon

¹⁸O, D, and H₂O⁺ contents were measured for whole-rock specimens of granitoid rocks from 131 localitics in California and southwestern Oregon. With 41 new determinations in the Klamath Mountains and Sierra Nevada, initial strontium isotope ratios are known for 104 of these samples. Large variations in ¹⁸O (5.5 to 12.4), D (–130 to –31), water contents (0.14 to 2.23 weight percent) and initial strontium isotope ratios (0.7028 to 0.7095) suggest a variety of source materials and identify rocks modified by secondary processes. Regular patterns of variation in each isotopic ratio exist over large geographical regions, but correlations between the ratios are generally absent except in restricted areas. For example, the regular decrease in D values from west to east in the Sierra Nevada batholith is not correlative with a quite complex pattern of ¹⁸O values, implying that different processes were responsible for the isotopic variations in these two elements. In marked contrast to a good correlation between (⁸⁷Sr/⁸⁶Sr)_o and ¹⁸O observed in the Peninsular Ranges batholith to the south, such correlations are lacking except in a few areas. D values, on the other hand, correlate well with rock types, chemistry, and (⁸⁷Sr/⁸⁶Sr)_o except in the Coast Ranges where few of the isotopic signatures are primary. The uniformly low D values of samples from the Mojave Desert indicate that meteoric water contributed much of the hydrogen to the rocks in that area. Even so, the ¹⁸O values and ¹⁸O fractionations between quartz and feldspar are normal in these same rocks.This reconnaissance study has identified regularities in geochemical parameters over enormous geographical regions. These patterns are not well understood but merit more detailed examination because they contain information critical to our understanding of the development of granitoid batholiths.     

On the magnetic structure of the quiet transition region

Existing models of the quiet chromosphere-corona transition region predict a distribution of emission measure over temperature that agrees with observation for T 10⁵ K. These network models assume that all magnetic field lines that emerge from the photosphere extend into and are in thermal contact with the corona. We show that the observed fine-scale structure of the photospheric magnetic network instead suggests a two-component picture in which magnetic funnels that open into the corona emerge from only a fraction of the network. The gas that makes up the hotter transition region is mostly contained within these funnels, as in standard models, but, because the funnels are more constricted in our picture, the heat flowing into the cooler transition region from the corona is reduced by up to an order of magnitude. The remainder of the network is occupied by a population of low-lying loops with lengths 10⁴ km. We propose that the cooler transition region is mainly located within such loops, which are magnetically insulated from the corona and must, therefore, be heated internally. The fine-scale structure of ultraviolet spectroheliograms is consistent with this proposal, and theoretical models of internally heated loops can explain the behavior of the emission measure below T 10⁵ K.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

The US Geological Survey's national coal resource assessment: the results

The US Geological Survey and the State geological surveys of many coal-bearing States recently completed a new assessment of the top producing coal beds and coal zones in five major producing coal regions—the Appalachian Basin, Gulf Coast, Illinois Basin, Colorado Plateau, and Northern Rocky Mountains and Great Plains. The assessments, which focused on both coal quality and quantity, utilized geographic information system technology and large databases. Over 1,600,000 million short tons of coal remain in over 60 coal beds and coal zones that were assessed. Given current economic, environmental, and technological restrictions, the majority of US coal production will occur in that portion of the assessed coal resource that is lowest in sulfur content. These resources are concentrated in parts of the central Appalachian Basin, Colorado Plateau, and the Northern Rocky Mountains.     

Coal as a source rock for oil: a review

The geological debate about whether, and to what extent, humic coals have sourced oil is likely to continue for some time, despite some important advances in our knowledge of the processes involved. It is clear that not only liptinites, but also perhydrous vitrinites have the potential to generate hydrocarbon liquids in the course of natural coalification. Some liptinites, especially alginite, cutinite, and suberinite, contain a higher proportion of aliphatic moieties in their structure than other liptinites such as sporinite and resinite and are, therefore, more oil-prone. It is of potential value to be able to predict the several environments of deposition in which coals with high liptinite contents or containing perhydrous vitrinites may have been formed. Review of the distribution of oil-prone coals in time and space reveals that most are Jurassic–Tertiary with key examples from Australia, New Zealand, and Indonesia. Methods based both on experimental simulations and the examination of naturally matured samples have been used to determine the order of generation of hydrocarbons from different macerals. Results are not entirely consistent among the different approaches, and there is much overlap in the ranges of degradation, but it seems probable that in the natural environment vitrinites begin to generate early, followed by labile liptinites such as suberinite, then cutinite, sporinite, and, finally, alginite.Petroleum potential may be determined by experimental simulation of natural coalification or inferred through various micro-techniques, especially fluorescence and infrared (IR) spectroscopy, or bulk techniques such as elemental analysis and ¹³C NMR spectroscopy. The latter three techniques enable a measure of the polymethylene component of the coal, which now appears to be one of the best available approaches for determining petroleum potential. No method of experimental simulation of petroleum generation from coals is without criticism, and comparative results are highly variable. However, hydrous pyrolysis, confined pyrolysis, and forms of open-system hydrous pyrolysis approach acceptable simulations.Whether, and to what degree generated liquid hydrocarbons are expelled, has long been the central problem in ‘oil from coal’ studies. The structure of vitrinite was believed until recently to contain an interconnected microporous network in which generated oil would be contained until an expulsion threshold was attained. Recent studies show the pores are not interconnected. Combined with a dynamic model of pore generation, it now seems that expulsion of hydrocarbons is best explained by activated diffusion of molecules to maceral boundaries and ultimately by cleats and fractures to coal seam boundaries. The main reason for poor expulsion is the adsorption of oil on the organic macromolecule, which may be overcome (1) if coals are thin and interbedded with clastic sediments, or (2) if the coals are very hydrogen-rich and generate large quantities of oil.The existence of oil in vitrinite is attested to by solvent extractions, fluorescence properties, and by microscopic observations of oil and bitumen. Experimental simulation of expulsion of oil from coals has only recently been attempted. The relative timing of release of generated CO₂ and CH₄ could have considerable importance in promoting the expulsion of liquid hydrocarbons but the mechanism is unclear. As it is universally agreed that dispersed organic matter (DOM) in some shales readily generates and expels petroleum, it is curious that few consistent geochemical differences have been found between coal macerals and DOM in interbedded shales.Unambiguous evidence of expulsion from coals is limited, and in particular only a few commercial oil discoveries can be confidently correlated to coals. These include Upper Cretaceous Fruitland Formation coals in the USA, from which oil is produced; New Zealand Tertiary coals; and Middle Jurassic coals from the Danish North Sea. It is likely that coals have at least contributed to significant oil discoveries in the Gippsland Basin, Australia; in the Turpan Basin, China; and in the Kutei and Ardjuna basins in Indonesia, but this remains unproven. Early reports that early Jurassic coals in mid-Norway were a major source of the reservoired oils have been shown to be inaccurate.None of the proposed ‘rules of thumb’ for generation or expulsion of petroleum from coals seem particularly robust. Decisions on whether a particular coal is likely to have been an active source for oil should consider all available geological and geochemical information. The assumptions made in computational models should be well understood as it is likely with new understandings of processes involved that some of these assumptions will be difficult to sustain.