Composition and origin of organic matter in surface sediments of Lake Sarbsko: A highly eutrophic and shallow coastal lake (northern Poland)

We present an organic geochemical study of surface sediments of Lake Sarbsko, a shallow coastal lake on the middle Polish Baltic coast. The aim was to provide evidence concerning the origin of the organic matter (OM) and its compositional diversity in surface deposits of this very productive, highly dynamic water body. The content and composition of the OM in the bottom sediments were investigated at 11 sampling stations throughout the lake basin. OM sources were assigned on the basis of bulk indicators [total organic carbon (TOC), total nitrogen (TN), δ¹³C_TOC and δ¹⁵N and extractable OM yield], biomarker composition of extractable OM and compound-specific C isotope signatures. The source characterization of autochthonous compounds was verified via phytoplankton analysis. The distribution of gaseous hydrocarbons in the sediments, as well as temporal changes in lake water pH, the concentration of DIC (dissolved inorganic carbon) and δ¹³C_DIC were used to trace OM decomposition.The sedimentary OM is composed mainly of well preserved phytoplankton compounds and shows minor spatial variability in composition. However, the presence of CH₄ and CO₂ in the bottom deposits provides evidence for microbial degradation of sedimentary OM. The transformation of organic compounds in surface, bottom and pore waters via oxidative processes influences carbonate equilibrium in the lake and seasonally favours precipitation or dissolution of CaCO₃.The data enhance our understanding of the relationships between the composition of sedimentary OM and environmental conditions within coastal ecosystems and shed light on the reliability of OM proxies for environmental reconstruction of coastal lakes.     

Sustainable Soil Particle Size Characterization Through Image Analysis

A rapid, clean, low-energy, image-based method for determining the grain size distribution of soils by image analysis has been developed. The method is called Sediment Imaging or “Sedimaging”. It develops the grain size distribution for particles in the range between a U.S. Standard Sieve No. 10 (2.0 mm openings) and U.S. Standard Sieve No. 200 (0.075 mm openings) range. The system utilizes a high resolution Nikon D7000 digital single lens reflex camera and image processing software developed specifically for interpreting the images and producing the resulting grain size distribution. The Sedimaging system is more sustainable and environmentally friendly than traditional sieving by virtue of its far lower power needs, less water consumption, longer equipment life and less maintenance. From the environmental and health perspectives, Sedimaging is less noisy, generates no vibrations and produces no airborne particulates. Sedimaging is also significantly faster than sieving and produces thousands of data points compared to typically 8 by sieving; it also automatically computes grain size distribution metrics such as the coefficients of uniformity and gradation.     

Little Ice Age subsidence and post Little Ice Age uplift at Juneau, Alaska, inferred from dendrochronology and geomorphology

Application of dendrochronology and geomorphology to a recently emerged coastal area near Juneau, Alaska, has documented a Little Ice Age (LIA) sea-level transgression to 6.2 m above current sea level. The rise in relative sea level is attributed to regional subsidence and appears to have stabilized by the mid 16th century, based on a sea-cliff eroded into late-Pleistocene glaciomarine sediments. Land began emerging between A.D. 1770 and 1790, coincident with retreat of regional glaciers from their LIA maximums. This emergence has continued since then, paralleling regional glacier retreat. Total Juneau uplift since the late 18th century is estimated to be 3.2 m. The rate of downward colonization of newly emergent coastline by Sitka spruce during the 20th century closely parallels the rate of sea-level fall documented by analysis of local tide-gauge records (1.3 cm/yr). Regional and Glacier Bay LIA loading and unloading are inferred to be the primary mechanisms driving subsidence and uplift in the Juneau area. Climate change rather then regional tectonics has forced relative sea-level change over the last several hundred years.     

Ar-Ar laser dating of tektites from the Cheb Basin (Czech Republic): Evidence for coevality with moldavites and influence of the dating standard on the age of the Ries impact

Moldavites (Central European tektites) are genetically related to the impact event that produced the ∼24-km diameter Ries crater in Germany, representing one of the youngest large impact structures on Earth. Although several geochronological studies have been completed, there is still no agreement among ⁴⁰Ar-³⁹Ar ages on both moldavites and glasses from Ries suevites. Even recently published data yielded within-sample mean ages with a nominal spread of more than 0.6 Ma (14.24-14.88 Ma). This age spread, which significantly exceeds current internal errors, must be in part ascribed to geological and/or analytical causes.This study reports the results of a detailed geochronological investigation of moldavites from the Cheb area (Czech Republic), which have never been dated before, and, for comparison, of two samples from type localities, one in southern Bohemia and the other in western Moravia. We used ⁴⁰Ar-³⁹Ar laser step-heating and total fusion techniques in conjunction with microscale petrographic and chemical characterization. In addition, with the purpose of ascertaining the influence of the dating standards on the age of the Ries impact and making data from this study and literature consistent with the now widely used Fish Canyon sanidine (FCs) standard, we performed a direct calibration of multi-grain splits of the Fish Canyon biotite (FCT-3) with FCs. The intercalibration factors (), determined for eight stack positions in one of the three performed irradiations, were indistinguishable within errors and gave an arithmetic mean and a standard deviation of 1.0086 ± 0.0031 (±2σ), in agreement with previous works suggesting that biotite from the Fish Canyon Tuff is somewhat older (∼0.8%) than the coexisting sanidine.Laser total fusion analysis of milligram to sub-milligram splits of five tektite samples from the Cheb area yielded mostly concordant intrasample ⁴⁰Ar-³⁹Ar ages, and within-sample weighted mean ages of 14.66 ± 0.08-14.75 ± 0.12 Ma (±2σ internal errors, ages relative to FCs) that overlap within errors. These ages match those obtained for samples from western Moravia (14.66 ± 0.08 Ma) and southern Bohemia (14.68 ± 0.11 Ma), supporting the genetic link between Cheb Basin tektites and moldavites, and, consequently, between Cheb Basin tektites and the Ries impact. In contrast to samples from the Cheb area and Moravia, ⁴⁰Ar-³⁹Ar ages from total fusion experiments on the Bohemian specimen ranged widely from ∼14.6 to ∼17.0 Ma. Older apparent ages, however, were systematically obtained from fragments characterized by visible surface alteration. Laser step-heating experiments, although displaying slightly disturbed age profiles, were in line with total fusion analyses and yielded well-defined plateau ages of 14.64 ± 0.11-14.71 ± 0.11 Ma (±2σ internal errors, ages relative to FCs).A thorough comparison of our and previous ⁴⁰Ar-³⁹Ar ages on both moldavites and Ries suevite glasses, recalculated relative to the ⁴⁰Ar^∗/⁴⁰K ratio recently determined for FCs using intercalibration factors available in or derivable from the literature, reveals some inconsistencies which may be ascribed to either geological or analytical causes. Based on our data, decay constants in current use in geochronology, and ages calculated relative to FCs, we infer that the age of moldavites is 14.68 ± 0.11 Ma (±2σ, neglecting uncertainties in the ⁴⁰K decay constants).     

Molecular transport in fracture processes

The Asymmetric Continuum Theory based on deformation fields includes the strain rotation as an equally important deformation part as the shear and confining strains; all these fields can be related to their origin in the fracture processes by some displacement motions in a source. Some of these motions may belong to an individual process, some to complex correlated events; in this latter case the displacements related to these strains could be shifted in phase. Moreover, we may expect an appearance of some molecular transport motions; the molecular transport may be helpful for understanding an interaction of the molecular processes and related molecular momentum flux. These correlated events should be mutually related in a source by the release-rebound mechanism. In particular, we consider the point fracture events as associated with a confining load or/and with the shear and rotation processes; we discuss the related effects and their meaning when discussing the fault plane mechanism and emitted waves. It is to be pointed out that such molecular motions are too small to be observed by the existing seismological networks.     

Space–time foam and cosmic-ray interactions

It has been proposed that propagation of cosmic-rays at extreme-energy may be sensitive to Lorentz-violating metric fluctuations (“foam”). We investigate the changes in interaction thresholds for cosmic-rays and gamma-rays interacting on the CMB and IR backgrounds, for a class of stochastic models of space–time foam. The strength of the foam is characterized by the factor (E/M_P)^a, where a is a phenomenological suppression parameter. We find that there exists a critical value of a (dependent on the particular reaction: a_crit3 for cosmic-rays, 1 for gamma-rays), below which the threshold energy can only be lowered, and above which the threshold energy may be raised, but at most by a factor of two. Thus, it does not appear possible in this class of models to extend cosmic-ray spectra significantly beyond their classical absorption energies. However, the lower thresholds resulting from foam may have signatures in the cosmic-ray spectrum. In the context of this foam model, we find that cosmic-ray energies cannot exceed the fundamental Planck scale, and so set a lower bound of 10⁸ TeV for the scale of gravity. We also find that suppression of p→pπ⁰ and γ→e⁻e⁺ “decays” favors values aa_crit. Finally, we comment on the apparent non-conservation of particle energy–momentum, and speculate on its re-emergence as dark energy in the foamy vacuum.     

Meridional Motion and Reynolds Stress from Debrecen Photoheliographic Data

The Debrecen Photoheliographic Data catalogue is a continuation of the Greenwich Photoheliographic Results providing daily positions of sunspots and sunspot groups. We analyse the data for sunspot groups focussing on meridional motions and transfer of angular momentum towards the solar equator. Velocities are calculated with a daily shift method including an automatic iterative process of removing the outliers. Apart from the standard differential rotation profile, we find meridional motion directed towards the zone of solar activity. The difference in measured meridional flow in comparison to Doppler measurements and some other tracer measurements is interpreted as a consequence of different flow patterns inside and outside of active regions. We also find a statistically significant dependence of meridional motion on rotation velocity residuals confirming the transfer of angular momentum towards the equator. Analysis of horizontal Reynolds stress reveals that the transfer of angular momentum is stronger with increasing latitude up to about \(40^{\circ}\), where there is a possible maximum in absolute value.     

Stability analysis of shotcrete supported crown of NATM tunnels with discontinuity layout optimization

For tunnel constructed by New Austrian Tunnelling Method, the crown is the upper part of tunnel section, constructed during excavation process and supported by shotcrete. The stability of the crown has great influence on the safety of tunnel itself and the buildings above, which correlates, among others, with geometrical setup of tunnel and material properties of shotcrete and soil/rock. In this paper, aiming at analyzing the stability of shotcrete supported crown, a recently presented numerical method discontinuity layout optimization is adopted, which introduces a great amount of potential discontinuities cross over one another and provides a wide search space for efficient upper limit analysis. In the analysis, a well‐established hydration model of cementitious material is implemented for accounting the hydration of shotcrete. Then assumptions based on convergence‐confinement method are used for accounting the 3‐dimensional effect in 2‐dimensional analysis, finally providing time‐space–dependent assessments of stability of shotcrete supported crown.     

Application of diffracted wave analysis to time‐lapse seismic data for CO2 leakage detection

Time‐lapse seismic analysis is utilized in CO₂ geosequestration to verify the CO₂ containment within a reservoir. A major risk associated with geosequestration is a possible leakage of CO₂ from the storage formation into overlaying formations. To mitigate this risk, the deployment of carbon capture and storage projects requires fast and reliable detection of relatively small volumes of CO₂ outside the storage formation. To do this, it is necessary to predict typical seepage scenarios and improve subsurface seepage detection methods. In this work we present a technique for CO₂ monitoring based on the detection of diffracted waves in time‐lapse seismic data. In the case of CO₂ seepage, the migrating plume might form small secondary accumulations that would produce diffracted, rather than reflected waves. From time‐lapse data analysis, we are able to separate the diffracted waves from the predominant reflections in order to image the small CO₂ plumes. To explore possibilities to detect relatively small amounts of CO₂, we performed synthetic time‐lapse seismic modelling based on the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) Otway project data. The detection method is based on defining the CO₂ location by measuring the coherency of the signal along diffraction offset‐traveltime curves. The technique is applied to a time‐lapse stacked section using a stacking velocity to construct offset‐traveltime curves. Given the amount of noise found in the surface seismic data, the predicted minimum detectable amount of CO₂ is 1000–2000 tonnes. This method was also applied to real data obtained from a time‐lapse seismic physical model. The use of diffractions rather than reflections for monitoring small amounts of CO₂ can enhance the capability of subsurface monitoring in CO₂ geosequestration projects.