Identifying Controls on Water Chemistry of Tropical Cloud Forest Catchments: Combining Descriptive Approaches and Multivariate Analysis

We investigated controls on the water chemistry of a South Ecuadorian cloud forest catchment which is partly pristine, and partly converted to extensive pasture. From April 2007 to May 2008 water samples were taken weekly to biweekly at nine different subcatchments, and were screened for differences in electric conductivity, pH, anion, as well as element composition. A principal component analysis was conducted to reduce dimensionality of the data set and define major factors explaining variation in the data. Three main factors were isolated by a subset of 10 elements (Ca²⁺, Ce, Gd, K⁺, Mg²⁺, Na⁺, Nd, Rb, Sr, Y), explaining around 90% of the data variation. Land-use was the major factor controlling and changing water chemistry of the subcatchments. A second factor was associated with the concentration of rare earth elements in water, presumably highlighting other anthropogenic influences such as gravel excavation or road construction. Around 12% of the variation was explained by the third component, which was defined by the occurrence of Rb and K and represents the influence of vegetation dynamics on element accumulation and wash-out. Comparison of base- and fast flow concentrations led to the assumption that a significant portion of soil water from around 30 cm depth contributes to storm flow, as revealed by increased rare earth element concentrations in fast flow samples. Our findings demonstrate the utility of multi-tracer principal component analysis to study tropical headwater streams, and emphasize the need for effective land management in cloud forest catchments.     

Influences of upwelling and downwelling winds on red tide bloom dynamics in Monterey Bay,California

It has recently been shown that inner shelf waters of NE Monterey Bay, California function as an “extreme bloom incubator”, frequently developing dense “red tide” blooms that can rapidly spread. Located within the California Current upwelling system, this open bay is strongly influenced by oceanographic dynamics resulting from cycles of upwelling favorable winds and their relaxation and/or reversal. Different wind forcing causes influx of different water types that originate outside the bay: cold nutrient-rich waters during upwelling and warm nutrient-poor waters during relaxation. In this study, we examine how the bay's bloom incubation area can interact with highly variable circulation to cause red tide spreading, dispersal and retention. This examination of processes is supported by satellite, airborne and in situ observations of a major dinoflagellate bloom during August and September of 2004. Remote sensing of high spatial, temporal and spectral resolution shows that the bloom originated in the NE bay, where it was highly concentrated in a narrow band along a thermal front. Upwelling circulation rapidly spread part of the bloom, mixing cool waters of an upwelling filament with warm bloom source waters as they spread. Vertical migration of the dinoflagellate populations was mapped by autonomous underwater vehicle surveys through the spreading bloom. Following bloom expansion, a two-day wind reversal forced intrusion of warm offshore waters that dispersed much of the bloom. Upwelling winds then resumed, and the bloom was further dispersed by an influx of cold water. Throughout these oceanographic responses to changing winds, an intense bloom persisted in sheltered waters of the NE bay, where extreme blooms are most frequent and intense. Microscopic examination of surface phytoplankton samples from the central bay showed that spreading of the bloom from the NE bay and mixing with regional water masses resulted in significantly increased abundance of dinoflagellates and decreased abundance of diatoms. Similar dinoflagellate bloom incubation sites are indicated in other areas of the California Current system and other coastal upwelling systems. Through frequent bloom development and along-coast transports, relatively small incubation sites may significantly influence larger regions of the coastal marine ecosystems in which they reside.     

Electromechanical effects associated with earthquakes

Summary A theoretical model of an electroelastic continuum has been applied in this paper to the problem of electrodynamic phenomena (piezoelectricity, electrostriction, etc.) associated with earthquakes. In such a model the coupling between electric and mechanical fields expresses itself by a change of scale of mechanical effects along the electric field, as well as by the additional electric charge created by the earthquake source.The electrokinetic phenomena associated with earthquakes and caused by the diffusion of fluids into the dilatant region have been considered using the theory of porous media with interstitial fluid flow. General relations describing electrokinetic effects caused by the deformation processes in an earthquake source have been obtained.     

Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska

Compositional heterogeneity (56–64 wt% SiO₂ whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO₂) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10 years) between Augustine's recent eruptive pulses may also inhibit homogenization, as short repose periods and chemically heterogeneous magmas are observed at several volcanoes in the Cook Inlet region of Alaska.     

Use of salt-marsh peat reefs by small juvenile lobsters on Cape Cod,Massachusetts

The habitats utilized by small juvenile (<40 mm carapace length, CL) lobsters (Homarus americanus) are poorly known. We discovered and studied an undescribed juvenile lobster habitat in Nauset Marsh, Cape Cod. Juvenile lobsters (X=26.7 mm carapace length, 6 to 72 mm, n=38) were collected from suction samples primarily 0144 01 in “peat reef” habitats during the period from August 1985 through October 1986. The reefs consisted of large blocks ofSpartina alterniflora peat that had separated from the marsh surface and fallen into adjacent subtidal marsh channels. The smallest lobsters (6 to 7 mm CL) were collected from peat reefs in October 1985, and April and July 1986. In these habitats, juvenile lobster density averaged 2.5 individuals m^?2 (range 0–5.7) in suction samples. Peat reef habitats occur in other salt marshes in the northeastern United States and may be an important nursery habitat for small juvenile lobsters.     

Optimization of the rate of return of the mine production process

Summary The basic foundations of an integrational method of modelling and estimating the economic effectiveness of a deep coal mine production process is presented. The method is founded on the concept of integration of smaller structural elements into larger ones in order to obtain a representational model of the whole mine production process. It involves analysis of the spatial, engineering and time structures of the mining process. The basic structural unit of the production process is the elementary time interval,T, together with a linear function of the approximate intensity of financial outlays or effects. The repeated integration of these elementary time intervals within the spatial, engineering and time structures of the mine production process can be extended to model the whole mine or discrete spatial structure elements.The model may be used to investigate the trends of financial outlays and effects, and their current values updated for arbitrarily assumed updating moments. The model can also be used as an investigation tool for analysing the economical effectiveness of the mine production process.     

Triple oxygen isotope composition of Australasian tektites

Major and trace element analyses and triple oxygen isotope measurements were performed on 11 individual specimens of Australasian tektites (AAT) with exactly known field positions from Laos. The sample set was dominated by Muong Nong‐type tektites (MNAAT), including separated layers of glass of different appearance and chemistry from four samples. This first larger set of oxygen isotope data of MNAAT revealed the δ¹⁸O range 8.7 ≤ δ¹⁸O ≤ 11.6‰ on VSMOW2 scale (12 analyses), only slightly wider than the previously reported range for splash‐form AAT. The Δ’¹⁷O values of MNAAT (?0.098 ≤ Δ’¹⁷O ≤ ?0.069‰; 12 analyses) and splash‐form AAT (?0.080 ≤ Δ’¹⁷O ≤ ?0.068‰; three analyses) are all in the range of data typical for terrestrial crustal rocks, with no mass‐independent oxygen isotope fractionation (from impactor or from exchange with atmospheric O₂) being observed.