Microbially influenced formation of Mg‐calcite and Ca‐dolomite in the presence of exopolymeric substances produced by sulphate‐reducing bacteria

Some species of sulphate‐reducing bacteria (SRB) are known to mediate the formation of dolomite and Mg‐calcite. However, their exact role in the mineralization process remains elusive. Here, we present the result of a laboratory experiment that was designed to test whether formation of carbonate minerals by SRB can occur in the absence of living cells, through passive mineralization of their exopolymeric substances (EPS). SRB capable of mediating dolomite were cultivated in the laboratory, allowing them to secrete EPS. Microbial activity within the cultures was subsequently inhibited with antibiotics. Only after this step, Ca²⁺ and Mg²⁺ were added to the solution and carbonate minerals could form. Mg‐calcite and disordered Ca‐dolomite precipitated in association with EPS. The mol.% of Mg²⁺ in the crystals increased with longer incubation times. This result demonstrates that organic compounds produced by SRB can mediate the formation of Ca‐Mg carbonates in the absence of an active metabolism.     

The Late Cretaceous Klepa basalts in Macedonia (FYROM)—Constraints on the final stage of Tethys closure in the Balkans

The waning stage(s) of the Tethyan ocean(s) in the Balkans are not well understood. Controversy centres on the origin and life‐span of the Cretaceous Sava Zone, which is allegedly a remnant of the last oceanic domain in the Balkan Peninsula, defining the youngest suture between Eurasia‐ and Adria‐derived plates. In order to investigate to what extent Late‐Cretaceous volcanism within the Sava Zone is consistent with this model we present new age data together with trace‐element and Sr–Nd–Pb isotope data for the Klepa basaltic lavas from the central Balkan Peninsula. Our new geochemical data show marked differences between the Cretaceous Klepa basalts (Sava Zone) and the rocks of other volcanic sequences from the Jurassic ophiolites of the Balkans. The Klepa basalts mostly have Sr–Nd–Pb isotopic and trace‐element signatures that resemble enriched within‐plate basalts substantially different from Jurassic ophiolite basalts with MORB, BAB and IAV affinities. Trace‐element modelling of the Klepa rocks indicates 2%–20% polybaric melting of a relatively homogeneously metasomatised mantle source that ranges in composition from garnet lherzolite to ilmenite+apatite bearing spinel–amphibole lherzolite. Thus, the residual mineralogy is characteristic of a continental rather than oceanic lithospheric mantle source, suggesting an intracontinental within‐plate origin for the Klepa basalts. Two alternative geodynamic models are internally consistent with our new findings: (1) if the Sava Zone represents remnants of the youngest Neotethyan Ocean, magmatism along this zone would be situated within the forearc region and triggered by ridge subduction; (2) if the Sava Zone delimits a diffuse tectonic boundary between Adria and Europe which had already collided in the Late Jurassic, the Klepa basalts together with a number of other magmatic centres represent volcanism related to transtensional tectonics.     

4He diffusion in specular hematite

In order to test the chronometer qualities of speculante for the (U + Th)/He dating method, ⁴He release experiments by stepwise heating of two specularites from the Rimbach mineralization locality in the southern Vosgues (France) have been carried out. The diffusion coefficients define linear Arrhenius plots within a temperature interval of 250 to 830 °C, which is suggestive of volume diffusion. Extrapolation of the diffusion behavior to 20° C yields diffusion coefficients (D₂₀ values) smaller than 10^?26 [cm² s^?1] for both hematites with activation energies at 116 [kJ/mole]. The results of our study suggest that specularite is a very helium retentive hematite variety which is capable of quantitatively retaining radiogenic helium over geologic periods of time.     

Test of Hack's slope to bed material relationship in the Southern Eifel Uplands,Germany

The local reach gradient of small gravel bed rivers (drainage area 0-8-110 km²) in the Eifel, West Germany, is adjusted to transport the river bed sediments. Transport of gravel becomes possible under high flow conditions (Shields entrainment factor ≈-03). Mean bed material size for riffle sections increases with distance downstream. For small drainage areas channel slope is a negative exponential function of drainage area, while for the larger region the additional influence of bedload size has to be considered. Good agreement with Hack's data (1957) for Virginia and Maryland, U.S.A., is achieved (S = 0.0066 (D₅₀/A)^{- 40.}, r = 0.67).     

Eocene high pressure metamorphism in the Penninic units of the Tauern Window (Eastern Alps): evidence from40Ar−39Ar dating and petrological investigations

The⁴⁰Ar-³⁹Ar degassing spectra of white micas and amphiboles from three tectonic units of the central Tauern Window (Pennine basement and cover in the Eastern Alps) have been measured. White micas are classified as (1) pre-Alpine low-Si relic micas with an age value of 292 Ma, variously disturbed by the Alpine metamorphism; (2) Alpine phengitic micas of variable composition with an age between 32 and 36 Ma; (3) Alpine low-Si micas with a maximum age of 27 Ma. We attribute the higher Alpine ages to a blueschist facies event, whereas the lower age reflects the late cooling of the nappe pile. Blueschist facies phengites from the basement (Lower Schieferhülle) and the tectonic cover (Upper Schieferhülle) crystallized at a temperature below the closure temperature (T _c) for argon diffusion in white mica and record ages of 32 to 36 Ma. At the same time a thin, eclogite facies unit (Eclogite Zone) was thrust between the Lower and the Upper Schieferhülle and cooled from eclogite facies conditions at about 600°C at 20 kbar to blueschist facies conditions at 450°C or even 300°C at >10 kbar. Eclogite facies phengites closed for argon diffusion and record cooling ages, coinciding with the crystallization ages in the hanging and the footwall unit. Amphibole age spectra (actinolite, glaucophane, barroisite) are not interpretable in terms of geologically meaningful ages because of excess argon.     

Turbulence measurements in a submarine canyon

Profiles of velocity turbulence in Monterey Canyon, made with a recently developed expendable probe, show the existence of a very turbulent bottom boundary layer. The turbulent flow is up to 170 m thick and has peak microscale shears of 1 m s⁻¹ per meter. The rate of dissipation of kinetic energy, based on the observed shear variance, averaged over the depth of the turbulent boundary layer ranged from 70 to 500 × 10⁻⁶W m⁻³. Temperature measurements indicate that the flow was up canyon at a time of low tide. The upper bound for the vertical eddy viscosity is estimated to be17 × 10⁻⁴m²s⁻¹ and for the vertical eddy diffusivity is estimated to be 15 × 10⁻⁴m²s⁻¹. The large vertical scale and the intensity of the observed boundary layer suggest that the flow in Monterey Canyon may be important for the renewal and circulation of water over the continental shelf in the bay area.     

Cyclotella-taxa (Bacillariophyceae) in lakes of the Alpine region and their relationship to environmental variables

Surface sediment diatom assemblages for 86 Alpine lakes were analysed focusing on the dominant genusCyclotella and corresponding environmental data. The range of morphological variability of theCyclotella bodanica/radiosa, C. distinguenda, C. ocellata, C. comensis andC. stelligera complexes was documented. Significance tests included in the canonical correspondence analysis (CCA) indicated that total phosphorus, conductivity and surface water temperature were significantly correlated withCyclotella taxa assemblage distribution. Numerical species optima and tolerances were calculated in respect to these significant variables using weighted averaging (WA) regression and calibration. CCA and WA were able to provide information about the environmental preferences of the various morphotypes observed.     

The coalification pattern in the Northern Apennines and its palaeogeothermic and tectonic significance

The rocks of the Northern Apennines predominantly consist of non-metamorphic terrigeneous deposits (flysches and molasses) some of which are preorogenic, some synorogenic and others postorogenic with respect to the nappe tectonics (Miocene). As plant fragments frequently occur in these sediments, a study of coal rank based on reflectance measurements on vitrinites (% Rm = mean value of the random reflectance in non polarized light) contributes to the clarification of the relation between the orogenic and the palaeogeothermal development. The determination of the Rm values of more than 180 samples from outcrops and three deep drillings revealed some important features. Within the pile of Liguride and Tuscanide nappes, the coal rank increases from the uppermost nappe to the lower nappes until lowgrade metamorphism is reached in the Lower Tuscanides. In the single nappes the rank decreases from the Tyrrhenian coast (internal zone) towards the Po Plain (external zone). This regional trend is disturbed only locally by young post-coalification tectonics. In the uppermost Liguride nappe (M. Antola Unit) a pre-Oligocene (i. e. pre-Apenninic) thermal event was detected. Postorogenic heating is connected with the magmatic activity of Late Miocene to Pleistocene age in Tuscany. Except for these preorogenic and postorogenic thermal events, the main coalification is generally younger than the emplacement of the nappes in the nappe pile during the Apenninic orogeny in the Miocene, but it is older than the last thrust movements and the final tensional tectonics in the internal zones of the chain. For these reasons, the main regional thermal event has to be considered as synorogenic or, more precisely, as late-synorogenic.