Test of Hack's slope to bed material relationship in the Southern Eifel Uplands,Germany

The local reach gradient of small gravel bed rivers (drainage area 0-8-110 km²) in the Eifel, West Germany, is adjusted to transport the river bed sediments. Transport of gravel becomes possible under high flow conditions (Shields entrainment factor ≈-03). Mean bed material size for riffle sections increases with distance downstream. For small drainage areas channel slope is a negative exponential function of drainage area, while for the larger region the additional influence of bedload size has to be considered. Good agreement with Hack's data (1957) for Virginia and Maryland, U.S.A., is achieved (S = 0.0066 (D₅₀/A)^{- 40.}, r = 0.67).     

The BEAM-project: prediction and assessment of mixture toxicities in the aquatic environment

Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.     

Zircon fission‐track ages from Newfoundland—A proxy for high geothermal gradients and exhumation before opening of the Central Atlantic Ocean

Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma.     

Internal morphology, habit and U-Th-Pb microanalysis of amphibolite-to-granulite facies zircons: geochronology of the Ivrea Zone (Southern Alps)

Several types of growth morphologies and alteration mechanisms of zircon crystals in the high-grade metamorphic Ivrea Zone (IZ) are distinguished and attributed to magmatic, metamorphic and fluid-related events. Anatexis of pelitic metasediments in the IZ produced prograde zircon overgrowths on detrital cores in the restites and new crystallization of magmatic zircons in the associated leucosomes. The primary morphology and Th-U chemistry of the zircon overgrowth in the restites show a systematic variation apparently corresponding to the metamorphic grade: prismatic (prism-blocked) low-Th/U types in the upper amphibolite facies, stubby (fir-tree zoned) medium-Th/U types in the transitional facies and isometric (roundly zoned) high-Th/U types in the granulite facies. The primary crystallization ages of prograde zircons in the restites and magmatic zircons in the leucosomes cannot be resolved from each other, indicating that anatexis in large parts of the IZ was a single and short lived event at 299 ± 5 Ma (95% c. l.). Identical U/Pb ages of magmatic zircons from a metagabbro (293 ± 6 Ma) and a metaperidotite (300 ± 6 Ma) from the Mafic Formation confirm the genetic context of magmatic underplating and granulite facies anatexis in the IZ. The U-Pb age of 299 ± 5 Ma from prograde zircon overgrowths in the metasediments also shows that high-grade metamorphic (anatectic) conditions in the IZ did not start earlier than 20 Ma after the Variscan amphibolite facies metamorphism in the adjacent Strona–Ceneri Zone (SCZ). This makes it clear that the SCZ cannot represent the middle to upper crustal continuation of the IZ. Most parts of zircon crystals that have grown during the granulite facies metamorphism became affected by alteration and Pb-loss. Two types of alteration and Pb-loss mechanisms can be distinguished by cathodoluminescence imaging: zoning-controlled alteration (ZCA) and surface-controlled alteration (SCA). The ZCA is attributed to thermal and/or decompression pulses during extensional unroofing in the Permian, at or earlier than 249 ± 7 Ma. The SCA is attributed to the ingression of fluids at 210 ± 12 Ma, related to hydrothermal activity during the breakup of the Pangaea supercontinent in the Upper Triassic/Lower Jurassic. Received: 7 July 1998 / Accepted: 4 November 1998     

An iterative version of the adaptive Gaussian mixture filter

The adaptive Gaussian mixture filter (AGM) was introduced as a robust filter technique for large-scale applications and an alternative to the well-known ensemble Kalman filter (EnKF). It consists of two analysis steps, one linear update and one weighting/resampling step. The bias of AGM is determined by two parameters, one adaptive weight parameter (forcing the weights to be more uniform to avoid filter collapse) and one predetermined bandwidth parameter which decides the size of the linear update. It has been shown that if the adaptive parameter approaches one and the bandwidth parameter decreases, as an increasing function of the sample size, the filter can achieve asymptotic optimality. For large-scale applications with a limited sample size, the filter solution may be far from optimal as the adaptive parameter gets close to zero depending on how well the samples from the prior distribution match the data. The bandwidth parameter must often be selected significantly different from zero in order to make large enough linear updates to match the data, at the expense of bias in the estimates. In the iterative AGM we introduce here, we take advantage of the fact that the history matching problem is usually estimation of parameters and initial conditions. If the prior distribution of initial conditions and parameters is close to the posterior distribution, it is possible to match the historical data with a small bandwidth parameter and an adaptive weight parameter that gets close to one. Hence, the bias of the filter solution is small. In order to obtain this scenario, we iteratively run the AGM throughout the data history with a very small bandwidth to create a new prior distribution from the updated samples after each iteration. After a few iterations, nearly all samples from the previous iteration match the data, and the above scenario is achieved. A simple toy problem shows that it is possible to reconstruct the true posterior distribution using the iterative version of the AGM. Then a 2D synthetic reservoir is revisited to demonstrate the potential of the new method on large-scale problems.     

Cyclotella-taxa (Bacillariophyceae) in lakes of the Alpine region and their relationship to environmental variables

Surface sediment diatom assemblages for 86 Alpine lakes were analysed focusing on the dominant genusCyclotella and corresponding environmental data. The range of morphological variability of theCyclotella bodanica/radiosa, C. distinguenda, C. ocellata, C. comensis andC. stelligera complexes was documented. Significance tests included in the canonical correspondence analysis (CCA) indicated that total phosphorus, conductivity and surface water temperature were significantly correlated withCyclotella taxa assemblage distribution. Numerical species optima and tolerances were calculated in respect to these significant variables using weighted averaging (WA) regression and calibration. CCA and WA were able to provide information about the environmental preferences of the various morphotypes observed.     

The coalification pattern in the Northern Apennines and its palaeogeothermic and tectonic significance

The rocks of the Northern Apennines predominantly consist of non-metamorphic terrigeneous deposits (flysches and molasses) some of which are preorogenic, some synorogenic and others postorogenic with respect to the nappe tectonics (Miocene). As plant fragments frequently occur in these sediments, a study of coal rank based on reflectance measurements on vitrinites (% Rm = mean value of the random reflectance in non polarized light) contributes to the clarification of the relation between the orogenic and the palaeogeothermal development. The determination of the Rm values of more than 180 samples from outcrops and three deep drillings revealed some important features. Within the pile of Liguride and Tuscanide nappes, the coal rank increases from the uppermost nappe to the lower nappes until lowgrade metamorphism is reached in the Lower Tuscanides. In the single nappes the rank decreases from the Tyrrhenian coast (internal zone) towards the Po Plain (external zone). This regional trend is disturbed only locally by young post-coalification tectonics. In the uppermost Liguride nappe (M. Antola Unit) a pre-Oligocene (i. e. pre-Apenninic) thermal event was detected. Postorogenic heating is connected with the magmatic activity of Late Miocene to Pleistocene age in Tuscany. Except for these preorogenic and postorogenic thermal events, the main coalification is generally younger than the emplacement of the nappes in the nappe pile during the Apenninic orogeny in the Miocene, but it is older than the last thrust movements and the final tensional tectonics in the internal zones of the chain. For these reasons, the main regional thermal event has to be considered as synorogenic or, more precisely, as late-synorogenic.     

Vesuvianite-new tool for the U-Pb dating of skarn ore deposits

Summary Vesuvianites from the Early Proterozoic Björntjärn tungsten skarn deposit in northern Sweden were dated with the U-Pb and Pb-Pb methods. Low²⁰⁶Pb/²⁰⁴Pb values make the U-Pb dating of vesuvianite rather sensitive to the common lead correction. However, the combination of Pb-Pb and U-Pb data on the same material permits the deduction of precise ages on Proterozoic vesuvianites. Vesuvianite can be used to date the formation of skarn mineralizations and possibly also the metamorphism and metasomatism of argillaceous limestones.

---

Vesuvianit-ein neues Werkzeug zur U-Pb Datierung von Skarnerzlagerstätten

Zusammenfassung Vesuvianit von der Wolfram-Skarnerzlagerstätte Björntjärn in Nordschweden wurde mit der U-Pb and Pb-Pb Methode datiert. Das tiefe²⁰⁶Pb/²⁰⁴Pb Verhältnis des Vesuvianits macht die U-Pb Altersbestimmung kräftig von der Korrektur des gewöhnlichen Bleis abhängig. Die Kombination von Pb-Pb und U-Pb Altersbestimmung am gleichen Probenmaterial erlaubt jedoch die präzise Datierung proterozoischer Vesuvianite. Vesuvianit kann zur direkten Altersbesimmung von Skarnlagerstätten und möglicherweise der Metamorphose und Metasomatose von mergeligen Kalksteinen verwendet werden.

---

---

With 4 Figures