Investigations on the runoff generation at the profile and plot scales,Swiss Emmental

This article describes an investigation on runoff generation at different scales in the forested catchment of the Sperbelgraben in the Emmental region (Swiss Prealps) where studies in the field of forest hydrology have a history of 100 years. It focuses on the analysis of soil profiles and the subsequent sprinkling experiments above them (1 m²), as well as on surface runoff measurements on larger plots (50 to 110 m²). In the Sperbelgraben investigation area, two very distinct runoff reactions could be observed. On the one hand, very high production of saturation overland flow was registered on wet areas of gleyic soils, with runoff coefficients between 0·39 and 0·94 for profile irrigation. On the other hand, almost no surface runoff was measured on Cambisols, with the exception at some sites of a hydrophobic reaction detected at the beginning of storms after dry periods (coefficients for profile irrigation: 0·01–0·16). This pattern was observed during 1 m² soil plot irrigation and on surface runoff plots. Apart from a less distinctive signal of the water‐repellent litter layer on the larger surface runoff plots, the dominant hydrological processes at the two scales are the same. The determined runoff reaction at the two scales corresponds well with information from a forest site type map describing soil and vegetation characteristics and used as a substitute for a soil map in this study. Theoretical considerations describing forest influence on flood discharge are discussed and evaluated to be in good agreement with observations. These findings are a sound foundation for application in hydrological catchment modelling. Copyright © 2006 John Wiley & Sons, Ltd.     

A geochemical aid to igneous rock type identification in deeply weathered terrain

A technique employing Ti, Zr and Cr to aid in the identification of primary igneous rock type in deeply weathered situations is described. The method is based on Ti/Zr ratio which is little affected either by primary alteration or weathering and adequately defines compositional fields for major igneous rock types. For volcanic rocks Ti/Zr ratios are rhyolite <4< dacite <12< andesite <60< basalt. Ultramafic rocks cannot be discriminated from mafic rocks by Ti/Zr ratio but are generally distinguished by high Cr.     

Sequestration of a Biologically Labile Organic Carbon in Soils by Humified Organic Matter

In a long-term (one year) experiment, a sandy Podzol and a silty-loamy Loess soil were treated with labile (polysaccharides, AG) and stable (mature compost, CMP, and two humic acids from compost, HAC, and lignite, HAL) organic matter and the organic carbon (OC) lost by mineralization was periodically evaluated. The stable materials alone induced a significant reduction of OC losses in Podzol CMP <, HAL, <, HAC, Control), whereas the same treatments, except for CMP, produced an OC loss larger than control in Loess. This was attributed to the diverse textural and physical status of the two soils. The added stable organic matter became protected in the Podzol soil within the aggregates formed by the interaction with the coarse inorganic phase, while it was more easily decomposed in the Loess soils due to the strength of the native humic-clay complexes. In both soils, when the stable organic materials were mixed with polysaccharides (AG), the OC losses from this labile fraction were significantly reduced, being CMP more OC sequestering than HAC and HAL, in the order. These results confirmed that labile organic matter in soils can be protected from biodegradation by repartition into the hydrophobic domains of the stable, humified organic matter. This study suggests that mature compost and humic acids may usefully integrate management practices aimed to sequester organic carbon in soils.     

Challenges in global ballast water management

Ballast water management is a complex issue raising the challenge of merging international regulations, ship's specific configurations along with ecological conservation. This complexity is illustrated in this paper by considering ballast water volume, discharge frequency, ship safety and operational issues aligned with regional characteristics to address ecological risk for selected routes. A re-estimation of ballast water volumes gives a global annual level of 3500 Mton. Global ballast water volume discharged into open sea originating from ballast water exchange operations is estimated to approximately 2800 Mton. Risk based decision support systems coupled to databases for different ports and invasive species characteristics and distributions can allow for differentiated treatment levels while maintaining low risk levels. On certain routes, the risk is estimated to be unacceptable and some kind of ballast water treatment or management should be applied.     

A multi-proxy approach for revealing recent climatic changes in the Russian Altai

For the first time we present a multi-proxy data set for the Russian Altai, consisting of Siberian larch tree-ring width (TRW), latewood density (MXD), δ¹³C and δ¹⁸O in cellulose chronologies obtained for the period 1779–2007 and cell wall thickness (CWT) for 1900–2008. All of these parameters agree well between each other in the high-frequency variability, while the low-frequency climate information shows systematic differences. The correlation analysis with temperature and precipitation data from the closest weather station and gridded data revealed that annual TRW, MXD, CWT, and δ¹³C data contain a strong summer temperature signal, while δ¹⁸O in cellulose represents a mixed summer and winter temperature and precipitation signal. The temperature and precipitation reconstructions from the Belukha ice core and Teletskoe lake sediments were used to investigate the correspondence of different independent proxies. Low frequency patterns in TRW and δ¹³C chronologies are consistent with temperature reconstructions from nearby Belukha ice core and Teletskoe lake sediments showing a pronounced warming trend in the last century. Their combination could be used for the regional temperature reconstruction. The long-term δ¹⁸O trend agrees with the precipitation reconstruction from the Teletskoe lake sediment indicating more humid conditions during the twentieth century. Therefore, these two proxies could be combined for the precipitation reconstruction.     

Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.     

Numerical simulations of the Mediterranean sea outflow: impact of the entrainment parameterization in an isopycnic coordinate ocean model

Gravity current entrainment is essential in determining the properties of the interior ocean water masses that result from marginal sea overflows. Although the individual entraining billows will be unresolvable in large-scale ocean models for the foreseeable future, some large-scale simulations are now being carried out that do resolve the intermediate scale environment which may control the rate of entrainment. Hallberg [Mon. Wea. Rev. 128 (2000) 1402] has recently developed an implicit diapycnal mixing scheme for isopycnic coordinate ocean models that includes the Richardson number dependent entrainment parameterization of Turner [J. Fluid Mech. 173 (1986) 431], and which may be capable of representing the gravity current evolution in large-scale ocean models. The present work uses realistic regional simulations with the Miami Isopycnic Coordinate Ocean Model (MICOM) to evaluate ability of this scheme to simulate the entrainment that is observed to occur in the bottom boundary currents downstream of the Mediterranean outflow. These simulations are strikingly similar to the observations, indicating that this scheme does produce realistic mixing between the Mediterranean outflow and the North Atlantic Central Water. Sensitivity studies identify the critical Richardson number below which vigorous entrainment occurs as a particularly important parameter. Some of these experiments also show meddies detaching from the Mediterranean undercurrent at locations that appear to be highly influenced by topographic features.     

A Global Terrestrial Reference Frame from simulated VLBI and SLR data in view of GGOS

In this study, we assess the impact of two combination strategies, namely local ties (LT) and global ties (GT), on the datum realization of Global Terrestrial Reference Frames in view of the Global Geodetic Observing System requiring 1 mm-accuracy. Simulated Very Long Baseline Interferometry (VLBI) and Satellite Laser Ranging (SLR) data over a 7 year time span was used. The LT results show that the geodetic datum can be best transferred if the precision of the LT is at least 1 mm. Investigating different numbers of LT, the lack of co-located sites on the southern hemisphere is evidenced by differences of 9 mm in translation and rotation compared to the solution using all available LT. For the GT, the combination applying all Earth rotation parameters (ERP), such as pole coordinates and UT1-UTC, indicates that the rotation around the Z axis cannot be adequately transferred from VLBI to SLR within the combination. Applying exclusively the pole coordinates as GT, we show that the datum can be transferred with mm-accuracy within the combination. Furthermore, adding artificial stations in Tahiti and Nigeria to the current VLBI network results in an improvement in station positions by 13 and 12%, respectively, and in ERP by 17 and 11%, respectively. Extending to every day VLBI observations leads to 65% better ERP estimates compared to usual twice-weekly VLBI observations.