Seismic anisotropy of the mantle lithosphere beneath the Swedish National Seismological Network (SNSN)

Body-wave analysis — shear-wave splitting and P travel time residuals — detect anisotropic structure of the upper mantle beneath the Swedish part of Fennoscandia. Geographic variations of both the splitting measurements and the P-residual spheres map regions of different fabrics of the mantle lithosphere. The fabric of individual mantle domains is internally consistent, usually with sudden changes at their boundaries. Distinct backazimuth dependence of SKS splitting excludes single-layer anisotropy models with horizontal symmetry axes for the whole region. Based upon joint inversion of body-wave anisotropic parameters, we instead propose 3D self-consistent anisotropic models of well-defined mantle lithosphere domains with differently oriented fabrics approximated by hexagonal aggregates with plunging symmetry axes. The domain-like structure of the Precambrian mantle lithosphere, most probably retaining fossil fabric since the domains' origin, supports the idea of the existence of an early form of plate tectonics during the formation of continental cratons already in the Archean. Similarly to different geochemical and geological constraints, the 3D anisotropy modelling and mapping of fabrics of the lithosphere domains contribute to tracking plate tectonics regimes back in time.     

On some methodological problems in the use of environmental tracers to estimate hydrogeologic parameters and to calibrate flow and transport models

Environmental tracers are used qualitatively for a better formulation of conceptual models and quantitatively for assessing groundwater ages with the aid of box models or for calibrating numerical transport models. Unfortunately, tracers often yield different ages that do not represent uniquely the water ages. Difficulties result also from different definitions of age, e.g. water age, advective age, tracer age, or radiometric tracer age, that are measured differently and depend on aquifer parameters and characteristics of particular tracers. Even the movement of an ideal tracer can be delayed with respect to the advective movement of water due to diffusion exchange between mobile and immobile water zones, which for fissured rocks or thin aquifers, may lead to significant differences between advective and tracer ages, i.e. also between advective and tracer velocities. The advective velocity is of importance in water resources considerations as being related to Darcy velocity, whereas the tracer velocity is a more useful term for the prediction of pollutant transport. When a groundwater system changes from one hydrodynamic steady state to another, environmental tracers need much more time to reach a new steady state. Several tracer studies are recalled as examples of tracer-specific effects on the estimations of groundwater age.     

Comparative analysis of measurements of stratospheric aerosol by lidar and aerosol sonde above Ny-Ålesund in the winter of 1995 [Comparative analysis of lidar and OPC observations]

Solid polar stratospheric cloud (PSC) layers observed by lidar and a balloon-borne optical particle counter (OPC) on 17 December 1995 are reexamined in a comparative analysis framework. The typical radius of solid particles in the observed PSC is determined through the comparative analysis to have been approximately 2.3 μm. A backward trajectory analysis for the air mass in which the solid particles were observed shows that the air mass had experienced temperatures 2–3 K below the frost point of nitric acid tri-hydrate (NAT) during the 4 days preceding the observations. The back-trajectory analysis traces the air mass back to northern Greenland and Ellesmere Island on 16 December, one day before the observations. A microphysical box model is used to investigate possible mechanisms of formation for the observed solid particles. The results of this model suggest that the solid particles formed under mesoscale temperature fluctuations associated with mountain lee wave activity induced by the relatively high terrestrial elevations of northern Greenland and Ellesmere Island.     

Testing Nano-Powder and Fused-Glass Mineral Reference Materials for In Situ Rb-Sr Dating of Glauconite,Phlogopite, Biotite and Feldspar via LA-ICP-MS/MS

Reference materials (RMs) with well-characterised composition are necessary for reliable quantification and quality control of isotopic analyses of geological samples. For in situ Rb-Sr analysis of silicate minerals via laser ablation inductively coupled plasma tandem mass spectrometry (LA-ICP-MS/MS) with a collision/reaction cell, there is a general lack of mineral-specific and matrix-matched RMs, which limits wider application of this new laser-based dating technique to certain minerals. In this work, pressed nano-powder pellets (NP) of four RMs, GL-O (glauconite), Mica-Mg (phlogopite), Mica-Fe (biotite) and FK-N (K-feldspar), were analysed and tested for in situ Rb-Sr dating, complemented by isotope dilution (ID) MC-ICP-MS Rb-Sr analyses of GL-O and Mica-Mg. In addition, we attempted to develop alternative flux-free and fused ‘mineral glasses’ from the above RMs for in situ Rb-Sr dating applications. Overall, the results of this study showed that among the above RMs only two NP (Mica-Mg-NP and GL-O-NP) were suitable and robust for in situ dating applications. These two nano-powder reference materials, Mica-Mg-NP and GL-O-NP, were thus used as primary RMs to normalise and determine Rb-Sr ages for three natural minerals: MDC phlogopite and GL-O glauconite grains, and also Mica-Fe-NP (biotite). Our in situ analyses of the above RMs yielded Rb-Sr ages that are in good agreement (within 8%) of published ages, which suggests that both Mica-Mg-NP and GL-O-NP are suitable RMs for in situ Rb-Sr dating of phlogopite, glauconite and biotite. However, using secondary RMs is recommended to monitor the quality of the obtained ages.