Enhanced pumping test using physicochemical tracers to determine surface-water/groundwater interactions in an alluvial island aquifer,river Rhône,France

Groundwater extracted from the Barthelasse Island aquifer, surrounded by the river Rhône (southeastern France), contributes to the drinking water supplies of 180,000 inhabitants. Owing to its location close to the river and the presence of two backwaters (oxbow lakes), the pumped groundwater is highly vulnerable to river pollution. A pumping test was conducted over 24 h to analyse and quantify the water exchange processes between the river, backwaters and groundwater. During the pumping test, isotopic (δ¹⁸O, δ²H and ²²²Rn), hydrochemical and hydrophysical monitoring of the groundwater was undertaken. Hydraulic heads were measured in pumping wells and at a piezometer located between the wells. Discrete water samples were collected at several observation points in the field, including the backwater and river. The results show mixing between three end-members, as defined by the deuterium excess and silica concentration, led by river Rhône water which had been affected by water–rock interactions over time and mixing with surface evaporated waters. The pumped water resulted from mixing between three end-members, all of which depended on the river Rhône but differed in terms of residence time in the system. Although the groundwater pumping wells are close to each other (<70 m) and have similar depths, the changes in the contributions from end-member waters at each well were different during the pumping test. Comparing isotopic tracers and geochemistry made it possible to quantify the different hydrological compartments that contribute to the groundwater pumped from the boreholes, which is critical in constructing a conceptual flow model.

     

InterPreting effects of TOCinert organic content on source rock Potential using S2 vs. TOC graPh in Maamba Coalfield,southern Zambia

The authors Present the effects of the total organic carbon( TOCinert )during Pyrolysis and how it overall affects the estimates of the hydrocarbon index( HI)using the cross Plot S2 vs. TOC graPh. A to...     

Quantitative inferences of past hypolimnetic anoxia and nutrient levels from a Canadan Precambrian Shield lake

Paleolimnological analyses were used to infer limnological changes during the past ~ 300 yrs in the west basin of Peninsula Lake, a small (853 ha) Precambrian Shield lake in Ontario, Canada, that has been subjected to moderate cultural disturbances (forest clearance, cottage and resort development). This study represents a pioneering attempt to use sedimentary chironomid assemblages and weighted-averaging models to quantify past hypolimnetic anoxia (expressed as the anoxic factor, AF). Impacts of forest clearance and human land-use on deepwater oxygen availability and surface water quality were assessed by comparing chironomid-inferred AF and diatom-inferred total phosphorus concentration ([TP]) to changes in terrestrial pollen and historical data. This study also discusses the ability of chironomids to quantitatively infer changes in AF.Pre-disturbance chironomid assemblages were stable and dominated by taxa indicative of oxygen-rich hypolimnetic conditions (e.g., Protanypus, Heterotrissocladius, Micropsectra type), while diatoms indicated oligotrophic lake status (diatom inferred [TP] = 5-7 g·l^-1). Chironomids characteristic of lower oxygen availability (e.g., Chironomus, Procladius) increased following land-clearance, road construction, establishment of a grist mill and lakeshore development beginning ca. 1870. Increased abundances of Tanytarsus s. lat., a multigeneric group of mainly littoral chironomids, since 1900, indicated that littoral chironomids may have comprised a greater proportion of fossil assemblages during periods of eutrophication and prolonged anoxia. Abundances of meso-eutrophic diatom taxa (e.g., Fragilaria crotonensis, Asterionella formosa, Aulacoseira ambigua, A. subarctica) increased concurrent with European settlement (ca. 1870) and diatom-inferred [TP] doubled (~ 6-12 g·l^-1), further indicating that naturally-oligotrophic Precambrian Shield lakes were extremely sensitive to initial land-clearance activities.Recent increases in oligotrophic diatom taxa (e.g., Cyclotella stelligera) indicate a shift to more oligotrophic conditions since ca. mid-1960s, with greatest changes since ca. 1980. The chironomids Heterotrissocladius and Micropsectra type also increased at this time suggesting greater deepwater oxygen availability. These recent water-quality improvements, possibly in response to enhanced nutrient removal from detergents and sewage, climate-related reductions in external phosphorus loads, and catchment (but not lake) acidification and reforestation, suggest that habitat for commercially-valuable cold-water fishes has improved in recent decades despite greater recreational lake-use.Paleolimnological assessment of trophic status changes in Peninsula Lake using fossil diatom and chironomid assemblages were in good agreement. Diatom inferences of [TP] and chironomid inferences of AF both suggest that Peninsula Lake was historically oligotrophic, became oligo-mesotrophic after European settlement, and returned to oligotrophy in recent yrs. Chironomid inferences of [TP] consistently underestimated the trophic status of Peninsula Lake, possibly due to its relatively large hypolimnion. These results suggest that AF represents a useful tool for quantitatively reconstructing the past trophic status of deeper, stratified lakes.     

Fingerprinting feldspar phenocrysts using crystal isotopic composition stratigraphy: implications for crystal transfer and magma mingling in S-type granites

 Microsampling of cm-scale feldspar crystals within an S-type granite from the Lachlan Fold Belt of southeastern Australia has revealed complex internal Sr and Nd isotopic variations. The observed isotopic zonations are in part interpreted as recording feldspar crystallisation in a dynamically mixing magma system, the isotopic composition of which was varying in response to the influx of more mafic and isotopically more mantle-like magmas, the latter stages of which are now represented in modified form by microgranular enclaves. Similar core to rim isotopic variations in feldspar megacrysts from a microgranular enclave and the adjacent host granite strongly suggest megacrysts in the enclave were transferred from the granitic magma during crystallisation. Feldspar rims have higher ⁸⁷Sr/⁸⁶Sr_i and lower ɛ_Nd(i) than adjacent whole rock analyses, but match those of mineral separates from the surrounding enclave matrix. This suggests that the final stages of megacryst growth occurred in the presence of a component that had previously interacted with a high ⁸⁷Sr/⁸⁶Sr, low ɛ_Nd(i) component such as metasedimentary wall rocks. Isotopic heterogeneities are also presererved within different mineral phases in the enclave matrix, suggesting that differing phases grew at differing stages of equilibration between the enclave magma and its host granitic magma. Our results reveal major isotopic heterogeneities on a single crystal and also inter-mineral scale in a pluton which shows well constrained evidence for magma mingling. These results indicate the suitability of feldspars as recorders of isotopic change in magmatic systems, even those which have cooled slowly in the plutonic environment and suggest that much heterogeneity in plutonic systems may be overlooked on a whole rock scale. Received: 28 September 1998 / Accepted: 29 December 1999     

Reconstruction of recent sea-level change using testate amoebae

Proxy-based sea-level reconstructions place the instrumentally observed rates of recent sea-level rise in a longer term context by providing data that extend the instrumental sea-level record into past centuries. This paper presents the first sea-level reconstructions based on analyses of testate amoebae, to test their ability to produce high-precision reconstructions of past sea level. We present two reconstructions for the past 100 yr from sites in Maine (USA) and Nova Scotia (Canada) based on short cores from salt marshes, and modern training data from North America and the United Kingdom. These are compared with tide-gauge records and reconstructions based on foraminifera from the same cores. The reconstructions show good agreement with both the tide-gauge data and the foraminifera-based reconstructions. The UK data perform well in predicting known elevations of North American surface samples and produce sea-level reconstructions very similar to those based on the North American data, suggesting the methodology is robust across large geographical areas. We conclude that testate amoebae have the potential to provide robust, higher precision sea-level reconstructions for the past few centuries if modern transfer functions are improved and core sites are located within the main zone of testate amoebae occurrence on the salt marsh.     

Microstrain stability of Peninsular India 1864–1994

We report the results of the South Indian Strain Measuring Experiment (SISME) designed to determine whether strain related to microseismicity in the past century may have deformed the networks of the 19th century Great Trigonometrical Survey of India (GTS). More than a dozen GTS points were measured between Mangalore, Madras, and Kanyakumari in southernmost India using GPS geodesy to determine regional deformation. Detailed measurements were made near two of the original baselines of the survey to determine the reliability of dilatational strain data for the network. The regional measurements revealed negligible regional dilatational (+ 11.2 + 10 microstrain) and shear strain changes (0.66± 1.2μradians) in the southernmost 530 km of India. In addition to these measurements, we determined the rate of northward and eastward motion of a point in Bangalore (1991–1994) in the ITRF92 reference frame to be 39 ± 3.5 mm/year, and 51 ± 11 mm/year respectively. This is consistent with NUVEL-1A plate motion estimate for India. Simultaneous measurements to a point near Kathmandu reveal that the Indian plate and the Southern Himalaya are moving approximately in unison, placing an upper limit on the rate of creep processes beneath the lesser Himalaya of ≈6 mm/year, and suggesting relatively rigid behavior of the Indian plate north of Bangalore. The stability of the Indian plate is confirmed by the absence of significant changes in the lengths of the two baselines at Bangalore and Cape Comorin, which, within the limits of experimental error have not changed since 1869. The measurements place an upper limit for recent deformation in the southern peninsula, and hence a lower limit for the renewal time for intraplate earthquakes in the region of approximately 10,000 years, assuming shear failure strain of approximately 100 μradians. This, in turn, implies that recurrence intervals for Peninsular Earthquakes far exceed the length of the written historic record, suggesting that the characterisation of seismic recurrence intervals from historical studies is likely to be fruitless. In contrast, the SISME experiment demonstrates that the noise level of geodetic studies based on 19th century GTS data is less than 0.02 μstrain/year, providing considerable scope for delineating regions of anomalously high seismogenic strain, by GPS measurements at all available trig points of the 19th century GTS survey.     

Accidents longitudinaux dans la Molasse rouge auct. et dans son substratum sur le versant oriental du Salève (Haute-Savoie, France)

A detailed mapping of the Salève Mountains reveals tectonically important new Molasse rouge auct. outcrops on the NW side of the Petit Salève and on the SE flank of the Grand Salève. On the SE flank the various dips indicate faults, kinks and folds that can be followed up to 5 km long and parallel to the axis of the chain and also affecting the Cretaceous substratum. This demonstrate a more complex connection of the eastern flank of the Salève Mountains with the adjacent plateau des Bornes than was previously supposed.     

Deformation measurements using SAR interferometry: potential and limitations

Most applications of Synthetic Aperture Radar (SAR) make only use of the amplitude information in just one image. Interferometric SAR (InSAR) makes use mainly of the phase measurements in two or more SAR images of the same scene, acquired at two different moments and/or at two slightly different locations. By interference of the two images, very small slant-range changes of the same surface can be inferred. These slant-range changes can be related to topography and/or surface deformations. InSAR thus has the potential of mapping centimeter-scale ground displacements over a region many tens of kilometers in size at a resolution of a few meters making it one of the most promising space-geodetic techniques for monitoring Earth's surface deformations. The goal of this paper is to discuss some of the potential new applications of InSAR for the monitoring of deformations, and to show its major limitations. Some potential new applications of InSAR related to surface-change detection including earthquake and crustal studies, the monitoring of volcanoes and anthropogenic effects, and the monitoring of glaciers and ice sheets are presented. The discussion on the limitations of InSAR for surface-change detection focuses on atmospheric perturbations and the problem of temporal decorrelation.     

The average molecular weight and shape of the “polymeric acids” found in Black Trona Water from the Green River Basin

Macromolecular organic material, called “polymeric acids”, has been isolated from Black Trona Water by exhaustive dialysis and characterized as the sodium salt in 0.10 M sodium carbonate, pH 10, by several physico-chemical methods. Analysis by gel filtration chromatography on Sepharose-CL 6B indicates that the “polymeric acids” are polydisperse and composed of species of relatively high molecular weight ( 4 × 10⁵, using proteins as standards). With this method, the range of molecular weights appears to be rather narrow. If “polymeric acids” are transferred from sodium carbonate, pH 10, into distilled water, selfassociation occurs and all species elute in the void volume. The weight-average molecular weight determined in 0.10 M sodium carbonate, pH 10, by the light scattering method is 1.7 × 10⁵. Sedimentation velocity analysis at 20°C with the analytical ultracentrifuge gives a value for S_20,w of 5.4 and the shape of the Schlieren patterns suggest a polydisperse sample with a relatively narrow range of sizes. Analysis of the molecular weight distribution by a sedimentation equilibrium method indicates that the range of molecular weights is 8 × 10⁴ to 2.1 × 10⁵. The partial specific volume ( ) of “polymeric acids” is 0.874 ml/g. Viscosity measurements yield a value for [η] of 2.5 ml/g, which indicates that the “polymeric acids” are compact (spherical or ellipsoidal) in shape.     

Chemical Characterisation of NIST Silicate Glass Certified Reference Material SRM 610 by ICP-MS, TIMS, LIMS, SSMS, INAA, AAS and PIXE

National Institute of Science and Technology (NIST) silicate glass SRM 610 is widely used as a certified reference material for various micro-analytical techniques such as SIMS or laser ablation ICP-MS. SRM 610 has been nominally doped with sixty one trace elements at the 500 μg g⁻¹ level, but certified concentration data exist for only a few of these elements. This study reports concentration data for fifty nine trace elements obtained by ICP-MS, SSMS, LIMS, TIMS, INAA, AAS, and PIXE analyses of two different SRM 610 wafers. Most elements fall within a 10% band around a median value of about 440 μg g⁻¹. The REE concentrations are shown to be constant to 3% (1 σ), thus emphasizing the value of SRM 610 as a reference material for REE analyses.
Comparison of our values with published data suggests that different SRM 610 wafers are, within errors, chemically identical for most elements. Exceptions to this general rule appear to be restricted to elements which were partly lost during the production of the glass, e.g. Ag and Br. On the basis of six independent determinations of Rb concentrations, which are systematically lower by a few percent than the reported NIST value, we argue that the certified Rb concentration may not be representative for all distributed SRM 610 wafers.