Geodynamic evolution of the Sabzevar zone,northern central Iranian micro-continent

Mineralogy and Petrology - The Northern Central Iranian Micro-continent (CIM) represents Neotethys-related oceanic crust remnants, emplaced due to convergence between CIM and Eurasia plates during...     

New <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar age constraints on cooling and unroofing history of the metamorphic host rocks (and igneous intrusion associates) from the Bulfat Complex (Bulfat area), NE-Iraq

The Northern Zagros Suture Zone (NZSZ), formed as a result of the collision between Arabian and Sanandaj-Sirjan microplate, is considered as part of the Zagros orogenic belt. NZSZ is marked by two allochthonous thrust sheets in upward stacking order: lower and upper allochthon. The Bulfat complex is a part of the upper allochthon or “Ophiolite-bearing terrane” of Albian-Cenomenion age (97–105 Ma). Voluminous highly sheared serpentinites associated with ophiolites occur within this upper allochthon. In addition, the Gemo-Qandil Group is characterized by gabbroic to dioritic Bulfat intrusion with a crystallization age spanning from ~45 to ~?40 Ma, as well as extensive metapelites with contact to the Walash-Naupurdam metavolcanic rocks. Due to the deformation in the Sanandaj-Sirjan Zone along the eastern side of the Iraqi segment of NZSZ, the Gemo-Qandil Group was regionally metamorphosed during late Cretaceous (~?80 Ma). This tectono-compressional dynamics ultimately caused an oscillatory deformation against Arabian continental margin deposits as well. During these events, gabbro-diorite intrusion with high-grade contact metamorphic aureoles occurred near Bulfat. Thus, there is an overlap between regional and contact metamorphic conditions in the area. The earlier metamorphic characteristic can be seen only in places where the latter contact influence was insignificant. Generally, this can only observed at a distance of more than 2.5 km from the contact. According to petrographic details and field observations, the thermally metamorphosed metapelitic units of the metasediment have been completely assimilated, with only some streaks of biotite and relicts of initial foliation. They strongly resemble amphibolite-grade slices from the regional metamorphic rocks in the region. Metapelitic samples far from the intrusion give similar biotite cooling ages as the intrusive rocks. Thus, they may be affected by the same thermal event. ⁴⁰Ar/³⁹Ar dating of biotite in metapelite rocks of Bulfat by step-wise heating with laser gave average weighted isotopic ages of 34.78?±?0.06 Ma. This is interpreted as crystallization/recrystallization age of biotite possibly representing the time of cooling and uplift history of the Bulfat intrusion. Cooling and exhumation rates for the Bulfat gabbro-diorite rocks were estimated as ~?400 °C/Ma and ~?3.3 mm/year respectively. According to petrographic details, field observations and Ar/Ar dating concerning the contact metamorphism near Bulfat due to the gabbro-diorite intrusion, no significant deformation is visible during exhumation processes after the Paleogene tectono-thermal event, indicating that isotopic ages of 34.78?±?0.06 Ma could mark the timing of termination of the island arc activity in the Ophiolite-bearing terrane (upper allochthon).     

InSAR datum connection using GNSS-augmented radar transponders

Deformation estimates from Interferometric Synthetic Aperture Radar (InSAR) are relative: they form a ‘free’ network referred to an arbitrary datum, e.g. by assuming a reference point in the image to be stable. However, some applications require ‘absolute’ InSAR estimates, i.e. expressed in a well-defined terrestrial reference frame, e.g. to compare InSAR results with those of other techniques. We propose a methodology based on collocated InSAR and Global Navigation Satellite System (GNSS) measurements, achieved by rigidly attaching phase-stable millimetre-precision compact active radar transponders to GNSS antennas. We demonstrate this concept through a simulated example and practical case studies in the Netherlands.     

Numerical modelling of multiphase immiscible flow in double‐porosity featured groundwater systems

A numerical model describing the flow of multiphase, immiscible fluids in a deformable, double‐porosity featured soil has been developed. The model is focused on the modelling of the secondary porosity features in soil, which is more relevant to groundwater contamination problems. The non‐linear saturation and relative permeabilities were expressed as functions of the capillary pressures. The governing partial differential equations in terms of soil displacement and fluid pressures were solved numerically. Galerkin's weighted‐residual finite element method was employed to obtain the spatial discretization whereas temporal discretization was achieved using a fully implicit scheme. The model was verified against established, peer‐reviewed works, and the assumption that the immiscible fluids (non‐aqueous phase liquids) will flow preferentially through the secondary porosity features in soil was validated. Copyright © 2011 John Wiley & Sons, Ltd.     

Dione’s spectral and geological properties

We present a detailed analysis of the variations in spectral properties across the surface of Saturn’s satellite Dione using Cassini/VIMS data and their relationships to geological and/or morphological characteristics as seen in the Cassini/ISS images. This analysis focuses on a local region on Dione’s anti-saturnian hemisphere that was observed by VIMS with high spatial resolution during orbit 16 in October 2005. The results are incorporated into a global context provided by VIMS data acquired within Cassini’s first 50 orbits. Our results show that Dione’s surface is dominated by at least one global process. Bombardment by magnetospheric particles is consistent with the concentration of dark material and enhanced CO₂ absorption on the trailing hemisphere of Dione independent of the geology. Local regions within this terrain indicate a special kind of resurfacing that probably is related to large-scale impact process. In contrast, the enhanced ice signature on the leading side is associated with the extended ejecta of the fresh impact crater Creusa (∼49°N/76°W). Although no geologically active regions could be identified, Dione’s tectonized regions observed with high spatial resolution partly show some clean H₂O ice implying that tectonic processes could have continued into more recent times.     

Laboratory chalcopyrite oxidation by Acidithiobacillus ferrooxidans: Oxygen and sulfur isotope fractionation

Laboratory experiments were conducted to simulate chalcopyrite oxidation under anaerobic and aerobic conditions in the absence or presence of the bacterium Acidithiobacillus ferrooxidans. Experiments were carried out with 3 different oxygen isotope values of water (δ¹⁸O_H2O) so that approach to equilibrium or steady-state isotope fractionation for different starting conditions could be evaluated. The contribution of dissolved O₂ and water-derived oxygen to dissolved sulfate formed by chalcopyrite oxidation was unambiguously resolved during the aerobic experiments. Aerobic oxidation of chalcopyrite showed 93 ± 1% incorporation of water oxygen into the resulting sulfate during the biological experiments. Anaerobic experiments showed similar percentages of water oxygen incorporation into sulfate, but were more variable. The experiments also allowed determination of sulfate–water oxygen isotope fractionation, ε¹⁸O_SO4–H2O, of ~ 3.8‰ for the anaerobic experiments. Aerobic oxidation produced apparent ε_SO4–H2O values (6.4‰) higher than the anaerobic experiments, possibly due to additional incorporation of dissolved O₂ into sulfate. δ³⁴S_SO4 values are ~ 4‰ lower than the parent sulfide mineral during anaerobic oxidation of chalcopyrite, with no significant difference between abiotic and biological processes. For the aerobic experiments, a small depletion in δ³⁴S_SO4 of ~? 1.5 ± 0.2‰ was observed for the biological experiments. Fewer solids precipitated during oxidation under aerobic conditions than under anaerobic conditions, which may account for the observed differences in sulfur isotope fractionation under these contrasting conditions.     

Dissolution kinetics of diopside as a function of solution saturation state: Macroscopic measurements and implications for modeling of geological storage of CO2

Measurements of the dissolution rate of diopside (r) were carried out as a function of the Gibbs free energy of the dissolution reaction (ΔG_r) in a continuously stirred flow-through reactor at 90 °C and pH_90 °C = 5.05. The overall relation between r and ΔG_r was determined over a free energy range of −130.9 < ΔG_r < −47.0 kJ mo1⁻¹. The data define a highly non-linear, sigmoidal relation between r and ΔG_r. At far-from-equilibrium conditions (ΔG_r ? −76.2 kJ mo1⁻¹), a rate plateau is observed. In this free energy range, the rates of dissolution are constant, independent of [Ca], [Mg] and [Si] concentrations, and independent of ΔG_r. A sharp decrease of the dissolution rate (∼1 order of magnitude) occurs in the transition ΔG_r region defined by −76.2 < ΔG_r ? −61.5 kJ mo1⁻¹. Dissolution closer to equilibrium (ΔG_r > −61.5 kJ mo1⁻¹) is characterised by a much weaker inverse dependence of the rates on ΔG_r. Modeling the experimental r-ΔG_r data with a simple classical transition state theory (TST) law as implemented in most available geochemical codes is found inappropriate. An evaluation of the consequences of the use of geochemical codes where the r-ΔG_r relation is based on basic TST was carried out and applied to carbonation reactions of diopside, which, among other reactions with Ca- and Mg-bearing minerals, are considered as a promising process for the solid state sequestration of CO₂ over long time spans. In order to take into account the actual experimental r-ΔG_r relation in the geochemical code that we used, a new module has been developed. It reveals a dramatic overestimation of the carbonation rate when using a TST-based geochemical code. This points out that simulations of water-rock-CO₂ interactions performed with classical geochemical codes should be evaluated with great caution.     

Stellar velocity profiles and line strengths out to four effective radii in the early-type galaxies NGC 3379 and 821

We use the integral-field spectrograph SAURON to measure the stellar line-of-sight velocity distribution and absorption line strengths out to four effective radii ( R _e) in the early-type galaxies NGC 3379 and 821. With our newly developed observing technique, we can now probe these faint regions in galaxies that were previously not accessible with traditional long-slit spectroscopy. We make optimal use of the large field-of-view and high throughput of the spectrograph: by adding the signal of all ∼1400 lenslets into one spectrum, we obtain sufficient signal-to-noise in a few hours of observing time to reliably measure the absorption line kinematics and line strengths out to large radius.
We find that the line strength gradients previously observed within 1 R _e remain constant out to at least 4 R _e, which puts constraints on the merger histories of these galaxies. The stellar halo populations are old and metal poor. By constructing orbit-based Schwarzschild dynamical models, we find that dark matter is necessary to explain the observed kinematics in NGC 3379 and 821, with 30–50 per cent of the total matter being dark within 4 R _e. The radial anisotropy in our best-fitting halo models is less than in our models without halo, due to differences in orbital structure. The halo also has an effect on the  Mg  b – V _esc  relation: its slope is steeper when a dark matter halo is added to the model.     

On the election of the flat metric in the bimetric theory of gravitation

The problem of the form of the flat metric in the Rosen bimetric theory is examined in the following work.It is shown, on concrete examples, how necessary it is to write down the flat metric and solve the problem of finding the gravitational field in arbitrary non-inertial frame. It is shown also how to separate the pure gravitational effects from those connected with non-inertiality of the frame by way of comparing both metrics.