Matrix analysis of metamorphic mineral assemblages and reactions: alternatives and extensions

Fisher (1989) advocated using the Singular Value Decomposition (SVD) of the composition matrix of a set of minerals for the determination of reactions between the minerals, and therefore of the compatibility relationships between mineral assemblages. The advantage of using the SVD for this is that an independent set of reactions, the left nullspace of the composition matrix, can be determined for a rank-deficient composition matrix which is close to, or within error of, the observed matrix. The zero singular values in the SVD can be identified by propagating the measurement uncertainties through to the singular values, and saying that singular values are zero if they are within error of zero. Having obtained an independent set of reactions, the reactions in the independent set can be combined linearly to find the full set of reactions. Propagating the measurement uncertainties through to the left nullspace of the composition matrix, the uncertainties in the coefficients of the reactions in the independent set can be determined. From these uncertainties, the uncertainties in all of the reactions can be determined, allowing the identification of reactions which are degenerate within error. This is important because it allows the identification of ambiguities in the compatibility relationships between mineral assemblages.     

Beta track autoradiography and infrared spectroscopy bearing on the solubility of CO2 in albite melt at 2 GPa and 1450° C

Albite glasses with 0.5–2.0 wt.% CO₂ synthesized at 2 GPa and 1450° C, previously analyzed by beta track autoradiography (Tingle 1987), have been analyzed by infrared spectroscopy. Values of CO₂ concentration determined by the beta track technique are 10–50% greater than the amount of CO₂ added to the sample. Values determined by infrared spectroscopy match the loaded CO₂ contents, substantiating the existence of a previously unrecognized error in the beta track technique. Concentrations, and hence solubilities, in albite determined by infrared spectroscopy are more accurate than those determined by beta track autoradiography. Values obtained by the beta track technique for diopside are 10% lower than the loaded CO₂ contents (Tingle 1987) and suggest that the systematic error may be dependent on composition and/or density.     

Analysis of simrad EM12 multibeam bathymetry and acoustic backscatter data for seafloor mapping,exemplified at the Mid-Atlantic Ridge at 45° N

The EM12 multibeam echosounder can record acoustic backscatter information as well as high resolution bathymetry. The dataset presented, from the axis of the Mid-Atlantic Ridge at 45° N, was the first EM12 survey of a mid-ocean ridge. This paper presents methods for utilising the backscatter information. Data processing enables the production of a mosaic of acoustic backscatter, and visualisation techniques are investigated to provide initial qualitative views of the combined backscatter and bathymetry datasets. The co-registration of the backscatter and bathymetry data enables quantitative analysis of their relationships. Various sites of different geological type have been selected and their angular acoustic backscattering relationships estimated, including the effect on backscatter of incidence angle, its regional variability with bottom type and the influence of bottom slope. Incidence angles and bottom type are shown to affect backscatter to a similar degree, while slopes appear to contribute little. The geometry of hull-mounted systems, such as the EM12, is significantly different from that of conventional sidescan sonars, such as GLORIA, and the backscatter images from the two types differ in various respects. Because of the wide variations in incidence angle that are common with hull-mounted systems, and the importance of incidence angle in determining backscatter strength, it is vital to consider the effect of incidence angle during interpretation.     

Hydrogeochemical zonation for groundwater management in the area with diversified geological and land-use setup

Despite its limited aerial extent, the National Capital Territory (NCT) Delhi, India, has diversified geological and topographical setup. A geochemical assessment of prevailing conditions of aquifer underlying the NCT was attempted and further classified into different hydrogeochemical zones on the basis of statistical and analyses and its correlation with land use, geological and climatic setting. Mineral phase study and isotopic analyses were used for the verification of performed clustering. Saturation indices (SI) calculated using the geochemical modelling code PHREEQC were used to distinguish the characteristics of four zones, as saturation states of the water does not change abruptly. Four different hydrogeochemical zones were statistically identified in the area: (1) intermediate (land-use-change-impacted) recharge zone, (2) discharge (agriculture-impacted) zone, (3) recharge (ridge) zone, and (4) recharge floodplain (untreated-discharge-impacted) zone. The distinctiveness of hydro-geochemical zones was further verified using stable isotopic (²H and ¹⁸O) signature of these waters. GIS-based flow regime in association with long-term geochemical evidences implied that these zones are being affected by different problems; thus, it necessitates separate environmental measures for their management and conservation. The study suggested that in a diversified urban setup where the complex interactions between anthropogenic activities and normal geochemical processes are functioning, hydrogeochmical zoning based on the integration of various techniques could be the first step towards sketching out the groundwater management plan.     

Two in one leachate plume in a karstic aquifer

Some sites formerly used for waste disposal purposes, even if they are closed, continue generating leachate that seeps into the ground and contaminates groundwater in the area where they are located. It is believed that the rainfall being in contact with waste becomes a source of leachate. This fluid seeps into the aquifer and may identify sources of pollution. A modeling work which determined the migration times of solutes in the karstic aquifer of Merida, Yucatan, Mexico, is presented. Both existing and generated information was analyzed; a leachate plume was identified. The methodology used in the study is described, the application of which allowed concluding that this plume was generated from two sources: a waste disposal site and the oxidation lagoons located next to it. The procedure consisted of performing simulations considering the sources that contribute to the development of the pollution plume and forecasting their behavior. With the developed methodology, similar cases can be analyzed to avoid locating catchment zones of drinking water in inappropriate places and/or develop projects to place waste disposal sites that could affect existing catchment areas and to preserve this resource, essential for life.     

Paleoecological investigations of recent lake acidification in northern Florida

Thirty-two northern Florida lakes were analyzed to construct a transfer function relating surface sediment diatom assemblages to lakewater pH (R ² =0.89, s.e.=0.34). A paleoecological analysis of sediment cores from six of these lakes indicated that two have become more acidic in the last 50 years. The diatom inferred (DI) pH of L. Barco has declined between 0.56–0.82 in the 1900's and DI ANC (acid neutralizing capacity) by 28–46 eq l^-1. The DI pH of nearby L. Suggs has declined 0.91 pH units and its DI ANC by 19 eq l^-1. The timing of the inferred acidification is synchronous with known increases in emissions of sulfates and nitrates that are associated with acidic precipitation. Also, the increasing accumulation of substances related to emissions from the burning of fossil fuels (e.g., Pb, PAH) co-occurs with the lowering of DI pH in the sedimentary record. However, other processes may have accounted for or contributed to recent lake acidification. For instance, the drawdown of local water tables by human consumption may decrease the inseepage of ANC to seepage lakes. Such an effect would be synchronous with increasing depositions of sulfate. There is also clear evidence that Florida lakes are naturally acidic. Thus, paleoecological results indicate acidic deposition to be at certain contributor, but not necessarily the sole cause, of the recent further acidification of some naturally acidic Florida lakes.This is the tenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.     

Climate change impact on water and salt balances: an assessment of the impact of climate change on catchment salt and water balances in the Murray-Darling Basin, Australia

Climate change has potentially significant implications for hydrology and the quantity and quality of water resources. This study investigated the impacts of climate change and revegetation on water and salt balance, and stream salt concentration for catchments within the Murray-Darling Basin, Australia. The Biophysical Capacity to Change model was used with climate change scenarios obtained using the CSIRO DARLAM 125 (125 km resolution) and Cubic Conformal (50 km resolution) regional climate models. These models predicted up to 25% reduction in mean annual rainfall and a similar magnitude of increase in potential evapotranspiration by 2070. Relatively modest changes in rainfall and temperature can lead to significant reductions in mean annual runoff and salt yield and increases in stream salt concentrations within the Basin. The modelled reductions in mean annual runoff were up to 45% in the wetter/cooler southern catchments and up to 64% in the drier/hotter western and northern catchments. The maximum reductions in salt yield were estimated to be up to 34% in the southern catchments and up to 49% in the northern and western catchments. These changes are associated with average catchment rainfall decreases of 13 to 21%. The results suggest that percentage changes in rainfall will be amplified in runoff. This study demonstrates that climate change poses significant challenges to natural resource management in Australia.     

Modern movement and deformation in the South China Sea shown by GPS measurements and numerical simulation

To better understand the crustal deformation of the South China Sea Basin, we produce a mechanically consistent 2-dimensional model for observing regional velocity field in the South China Sea (SCS). We studied the dominating regional tectonic stress field by geodetic measurements and finite element analysis, the spatial variations of velocity field and strain field, and relative movements among different blocks, using a 2-dimensional model describing crustal deformation of the South China Sea Basin. Strain results show that the SCS is extending at present. The western part of SCS is opening gradually in NWSE direction from its northern margin to the south, but the eastern part of SCS is opening gradually from its central part to the north and south. In addition, we analyzed the plate kinematics to the deformation of the SCS, using a two-dimensional finite element model. Our simulations results are well explained by available geodetic data. The movement of SCS is resulted from interactions among Indian Plate, Pacific Plate, Philippine Sea Plate, and Eurasian Plate.