Timing of granite emplacement and cooling in the Songpan–Garzê Fold Belt (eastern Tibetan Plateau) with tectonic implications

New U–Pb and Rb–Sr geochronology on syn- and post-orogenic granites provide constraints on the timing of major tectonic events in the Songpan–Garzê fold belt, west Sichuan, China. The Ma Nai granite was probably syn-kinematic with the main deformation and yields an age of 197±6 Ma that is interpreted as an upper age limit of the Indosinian event. Zircons and apatites from the post-kinematic Rilonguan granite also yield Jurassic ages (195±6 and 181±4 Ma). The post-orogenic Markam massif gives two ages of 188±1 and 153±3 Ma. Both granites are undeformed and cut structures in the Triassic sedimentary rocks. These results demonstrate that the major deformation and décollement tectonics in the Songpan–Garzê fold belt occurred prior to the Early Jurassic. The wide range of ages obtained for post-kinematic granites (from Early Jurassic to Late Jurassic) suggests that, locally, magmatic activity persisted for a long time (at least 50 Ma) after the Indosinian compressional tectonism. No Tertiary ages have been obtained, suggesting that these granites were not affected strongly by the India–Asia collision.     

Large-eddy simulation of turbulent flow above and within a forest

A large-eddy simulation has been performed of an atmospheric surface layer in which the lower third of the domain is occupied by a drag layer and heat sources to represent a forest. Subgridscale processes are treated using second-order closure techniques. Lateral boundaries are periodic, while the upper boundary is a frictionless fixed lid. Mean vertical profiles of wind velocity derived from the output are realistic in their shape and response to forest density. Similarly, vertical profiles of Reynolds stress, turbulent kinetic energy and velocity skewness match observations, at least in a qualitative sense. The limited vertical extent of the domain and the artificial upper boundary, however, cause some departures from measured turbulence profiles in real forests. Instantaneous turbulent velocity and scalar fields are presented which show some of the features obtained by tower instrumentation in the field and in wind tunnels, such as the vertical coherence of vertical velocity and the slope of structures revealed by temperature patterns.     

Sulphur isotope geochemistry of carbonatites

Sulphur isotopic data for sulphides and barite from several carbonatites (Mountain Pass, Oka, Magnet Cove, Bearpaw Mountains, Phalabora) show that individual carbonatites have different mean sulphide or barite isotopic compositions which deviate from the meteoritic mean $\text{δ}{}^{34}\text{S(0‰)}$.Classification of carbonatites in terms of T,?O₂ and pH during formation of the sulphur-bearing assemblages indicates that with decreasing T and increasing relative ?O₂ the mean δ³⁴S sulphide becomes increasing negative relative to the mean magma δ³⁴S. Only barite-free high temperature carbonatites (Phalabora) in which the mean δ^34S sulphide approaches the mean magmaδ³⁴S as a consequence of the paucity of oxidized anionic sulphur species in the magma can be used to directly estimate the mean isotopic composition of the source material.Barites from the Mountain Pass carbonatite show an increase in δ³⁴S with sequence of intrusion of the carbonatite units; dolomitic carbonatite (mean δ³⁴S, + 5.4‰), calcitic carbonatite (+ 4.8%.), silicified carbonatite (+ 6.9‰), tabular carbonatite dikes (+ 8.7‰), mineralized shear zones (+ 9.5‰). Within each of these units a spread of 6.8%. is evident. Isotopic trends in this low temperature (300°C) carbonatite are evaluated by treating the system as a hydrothermal fluid. The observed isotopic variations can be explained by removal of large amounts of sulphur from a fluid whose mean δ³⁴S is 0 to + 1‰     

Turbidites in the Upper Carboniferous Ross Formation, western Ireland: reconstruction of a channel and spillover system

ABSTRACT The Upper Carboniferous deep‐water rocks of the Shannon Group were deposited in the extensional Shannon Basin of County Clare in western Ireland and are superbly exposed in sea cliffs along the Shannon estuary. Carboniferous limestone floors the basin, and the basin‐fill succession begins with the deep‐water Clare Shales. These shales are overlain by various turbidite facies of the Ross Formation (460 m thick). The type of turbidite system, scale of turbidite sandstone bodies and the overall character of the stratigraphic succession make the Ross Formation well suited as an analogue for sand‐rich turbidite plays in passive margin basins around the world. The lower 170 m of the Ross Formation contains tabular turbidites with no channels, with an overall tendency to become sandier upwards, although there are no small‐scale thickening‐ or thinning‐upward successions. The upper 290 m of the Ross Formation consists of turbidites, commonly arranged in thickening‐upward packages, and amalgamated turbidites that form channel fills that are individually up to 10 m thick. A few of the upper Ross channels have an initial lateral accretion phase with interbedded sandstone and mudstone deposits and a subsequent vertical aggradation phase with thick‐bedded amalgamated turbidites. This paper proposes that, as the channels filled, more and more turbidites spilled further and further overbank. Superb outcrops show that thickening‐upward packages developed when channels initially spilled muds and thin‐bedded turbidites up to 1 km overbank, followed by thick‐bedded amalgamated turbidites that spilled close to the channel margins. The palaeocurrent directions associated with the amalgamated channel fills suggest a low channel sinuosity. Stacks of channels and spillover packages 25–40 m thick may show significant palaeocurrent variability at the same stratigraphic interval but at different locations. This suggests that individual channels and spillover packages were stacked into channel‐spillover belts, and that the belts also followed a sinuous pattern. Reservoir elements of the Ross system include tabular turbidites, channel‐fill deposits, thickening‐upward packages that formed as spillover lobes and, on a larger scale, sinuous channel belts 2·5–5 km wide. The edges of the belts can be roughly defined where well‐packaged spillover deposits pass laterally into muddier, poorly packaged tabular turbidites. The low‐sinuosity channel belts are interpreted to pass downstream into unchannellized tabular turbidites, equivalent to lower Ross Formation facies.     

Product formation from the gas-phase reactions of OH radicals and O3 with a series of monoterpenes

The formation yields of nine carbonyl products are reported from the gas-phase OH radical-initiated reactions (in the presence of NO _x ) and the O₃ reactions with seven monoterpenes. The products were identified using GC/MS and GC-FTIR and quantified by GC-FID analyses of samples collected on Tenax solid adsorbent cartridges. The identities of products from camphene, limonene and -pinene were confirmed by comparison with authentic standards. Sufficient quantities of products from the 3-carene, limonene, -pinene, sabinene and terpinolene reactions were isolated to allow structural confirmation by proton NMR spectroscopy. The measured total carbonyl formation yields ranged from non-detectable for the OH radical reaction with camphene and the O₃ reactions with 3-carene and limonene to 0.5 for the OH radical reaction with limonene and the O₃ reaction with sabinene.     

Short‐term forecasting with a multi‐level spectral primitive equation model part II ‐ Hemispheric prognoses and verification

The spectral global baroclinic primitive equation model described in Part I of this paper has been extensively tested. The model has been run daily from operational analyses for over a year. From this large sample of forecasts, verification statistics have been collected and compared with similar statistics collected from three competitive grid‐point models. The spectral model is also compared with the grid‐point models in a synoptic case study.

A second case study demonstrates the effect of horizontal resolution and physical effects on spectral model forecasts. The results of these experiments demonstrate that the spectral model is highly competitive with other models, in terms of both accuracy and computational efficiency. On 18 February 1976 the spectral model became the operational Canadian large‐scale forecast model.     

Inter-trading permanent emissions credits and rented temporary carbon emissions offsets: some issues and alternatives

Permit trading among polluting parties is now firmly established as a policy tool in a range of environmental policy areas. The Kyoto Protocol accepts the principle that sequestration of carbon in the terrestrial biosphere can be used to offset emissions of carbon from fossil fuel combustion and outlines mechanisms. Although the lack of guaranteed permanence of biological offsets is often viewed as a defect, this paper argues that the absence of guaranteed permanence need not be a fundamental problem. We view carbon emissions as a liability issue. One purpose of an emissions credit system is to provide the emitter with a means to satisfy the carbon liability associated with her firm's (or country's) release of carbon into the atmosphere. We have developed and here expand on a rental approach, in which sequestered carbon is explicitly treated as temporary: the emitter temporarily satisfies his liability by temporarily “parking” his liability, for a fee, in a terrestrial carbon reservoir, or “sink,” such as a forest or agricultural soil. Finally, the paper relates the value of permanent and temporary sequestration and argues that both instruments are tradable and have a high degree of substitutability that allows them to interact in markets.     

Effects of Recharge Wells and Flow Barriers on Seawater Intrusion

The installation of recharge wells and subsurface flow barriers are among several strategies proposed to control seawater intrusion on coastal groundwater systems. In this study, we performed laboratory‐scale experiments and numerical simulations to determine the effects of the location and application of recharge wells, and of the location and penetration depth of flow barriers, on controlling seawater intrusion in unconfined coastal aquifers. We also compared the experimental results with existing analytical solutions. Our results showed that more effective saltwater repulsion is achieved when the recharge water is injected at the toe of the saltwater wedge. Point injection yields about the same repulsion compared with line injection from a screened well for the same recharge rate. Results for flow barriers showed that more effective saltwater repulsion is achieved with deeper barrier penetration and with barriers located closer to the coast. When the flow barrier is installed inland from the original toe position however, saltwater intrusion increases with deeper barrier penetration. Saltwater repulsion due to flow barrier installation was found to be linearly related to horizontal barrier location and a polynomial function of the barrier penetration depth.