Organosilane occurrence in irghizite samples from the Zhamanshin impact crater,Kazakhstan

Abstract— The composition of surface deposits on vesicle walls in irghizites (i.e., impact glasses at site) from the Zhamanshin meteorite crater were studied using time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS). The cavity walls are unique interfaces for condensation of gases from the superheated, high‐silica melt during the impact. Initially, signals from the cavity wall are dominated by hydrocarbon fragments whereas the glass fracture face surrounding the cavity gave only signals corresponding to glass components. After 12 h in ultra high vacuum (UHV), signals from the cavity wall are dominated by peaks corresponding to fragments normally measured from organosilanes and organosiloxanes with the majority of the hydrocarbon signals markedly reduced. Characteristic hydrocarbon fragments are now observed on the glass fracture surface next to the cavity in an annulus around the cavity perimeter. There are also minor signals in this region from organosilanes and organosiloxanes. In contrast, four tektites (Australites) (i.e., glassy distal ejecta) gave no organosilane or organosiloxane signals after the same preparation and vacuum evaporation procedure. These species appear to be formed only at the impact site where higher levels of organic material are likely to be present in soil and are trapped before evaporation. This appears to be the first report of naturally occurring silicon‐organic compounds.     

Further observations of quasars in ESO/SERC field 927

We present the spectra and redshifts of 62 quasars, from observations made with the Cerro Tololo Inter-American Observatory (CTIO) 4-m Blanco Telescope. These quasars form part of a total sample of 118 (with 56 having been published previously), which is being used for analysis of structure in the early universe. Quasars of particular interest are noted, including eight broad absorption line (BAL) quasars and two quasars with unusual emission spectra. Finally, we include a short summary of the present status of the large quasar group (LQG) that was discovered by Clowes & Campusano from the earlier observations. The quasars are from an area ∼25.3 deg² of ESO/SERC field 927, which is centred at (1950) 10^h40^m00^s, 05°00'00'.     

Shallow radar (SHARAD) sounding observations of the Medusae Fossae Formation, Mars

The SHARAD (shallow radar) sounding radar on the Mars Reconnaissance Orbiter detects subsurface reflections in the eastern and western parts of the Medusae Fossae Formation (MFF). The radar waves penetrate up to 580 m of the MFF and detect clear subsurface interfaces in two locations: west MFF between 150 and 155° E and east MFF between 209 and 213° E. Analysis of SHARAD radargrams suggests that the real part of the permittivity is ∼3.0, which falls within the range of permittivity values inferred from MARSIS data for thicker parts of the MFF. The SHARAD data cannot uniquely determine the composition of the MFF material, but the low permittivity implies that the upper few hundred meters of the MFF material has a high porosity. One possibility is that the MFF is comprised of low-density welded or interlocked pyroclastic deposits that are capable of sustaining the steep-sided yardangs and ridges seen in imagery. The SHARAD surface echo power across the MFF is low relative to typical martian plains, and completely disappears in parts of the east MFF that correspond to the radar-dark Stealth region. These areas are extremely rough at centimeter to meter scales, and the lack of echo power is most likely due to a combination of surface roughness and a low near-surface permittivity that reduces the echo strength from any locally flat regions. There is also no radar evidence for internal layering in any of the SHARAD data for the MFF, despite the fact that tens-of-meters scale layering is apparent in infrared and visible wavelength images of nearby areas. These interfaces may not be detected in SHARAD data if their permittivity contrasts are low, or if the layers are discontinuous. The lack of closely spaced internal radar reflectors suggests that the MFF is not an equatorial analog to the current martian polar deposits, which show clear evidence of multiple internal layers in SHARAD data.     

Subsurface structure of Planum Boreum from Mars Reconnaissance Orbiter Shallow Radar soundings

We map the subsurface structure of Planum Boreum using sounding data from the Shallow Radar (SHARAD) instrument onboard the Mars Reconnaissance Orbiter. Radar coverage throughout the 1,000,000-km² area reveals widespread reflections from basal and internal interfaces of the north polar layered deposits (NPLD). A dome-shaped zone of diffuse reflectivity up to 12 μs (∼1-km thick) underlies two-thirds of the NPLD, predominantly in the main lobe but also extending into the Gemina Lingula lobe across Chasma Boreale. We equate this zone with a basal unit identified in image data as Amazonian sand-rich layered deposits [Byrne, S., Murray, B.C., 2002. J. Geophys. Res. 107, 5044, 12 pp. doi:10.1029/2001JE001615; Fishbaugh, K.E., Head, J.W., 2005. Icarus 174, 444-474; Tanaka, K.L., Rodriguez, J.A.P., Skinner, J.A., Bourke, M.C., Fortezzo, C.M., Herkenhoff, K.E., Kolb, E.J., Okubo, C.H., 2008. Icarus 196, 318-358]. Elsewhere, the NPLD base is remarkably flat-lying and co-planar with the exposed surface of the surrounding Vastitas Borealis materials. Within the NPLD, we delineate and map four units based on the radar-layer packets of Phillips et al. [Phillips, R.J., and 26 colleagues, 2008. Science 320, 1182-1185] that extend throughout the deposits and a fifth unit confined to eastern Gemina Lingula. We estimate the volume of each internal unit and of the entire NPLD stack (821,000 km³), exclusive of the basal unit. Correlation of these units to models of insolation cycles and polar deposition [Laskar, J., Levrard, B., Mustard, J.F., 2002. Nature 419, 375-377; Levrard, B., Forget, F., Montmessin, F., Laskar, J., 2007. J. Geophys. Res. 112, E06012, 18 pp. doi:10.1029/2006JE002772] is consistent with the 4.2-Ma age of the oldest preserved NPLD obtained by Levrard et al. [Levrard, B., Forget, F., Montmessin, F., Laskar, J., 2007. J. Geophys. Res. 112, E06012, 18 pp. doi:10.1029/2006JE002772]. We suggest a dominant layering mechanism of dust-content variation during accumulation rather than one of lag production during periods of sublimation.     

Saturn's dynamic D ring

The Cassini spacecraft has provided the first clear images of the D ring since the Voyager missions. These observations show that the structure of the D ring has undergone significant changes over the last 25 years. The brightest of the three ringlets seen in the Voyager images (named D72), has transformed from a narrow, <40-km wide ringlet to a much broader and more diffuse 250-km wide feature. In addition, its center of light has shifted inwards by over 200 km relative to other features in the D ring. Cassini also finds that the locations of other narrow features in the D ring and the structure of the diffuse material in the D ring differ from those measured by Voyager. Furthermore, Cassini has detected additional ringlets and structures in the D ring that were not observed by Voyager. These include a sheet of material just interior to the inner edge of the C ring that is only observable at phase angles below about 60°. New photometric and spectroscopic data from the ISS (Imaging Science Subsystem) and VIMS (Visual and Infrared Mapping Spectrometer) instruments onboard Cassini show the D ring contains a variety of different particle populations with typical particle sizes ranging from 1 to 100 microns. High-resolution images reveal fine-scale structures in the D ring that appear to be variable in time and/or longitude. Particularly interesting is a remarkably regular, periodic structure with a wavelength of ∼30 km extending between orbital radii of 73,200 and 74,000 km. A similar structure was previously observed in 1995 during the occultation of the star GSC5249-01240, at which time it had a wavelength of ∼60 km. We interpret this structure as a periodic vertical corrugation in the D ring produced by differential nodal regression of an initially inclined ring. We speculate that this structure may have formed in response to an impact with a comet or meteoroid in early 1984.     

Lightning storms on Saturn observed by Cassini ISS and RPWS during 2004-2006

We report on Cassini Imaging Science Subsystem (ISS) data correlated with Radio and Plasma Wave Science (RPWS) observations, which indicate lightning on Saturn. A rare bright cloud erupt at ∼35° South planetocentric latitude when radio emissions (Saturn Electrostatic Discharges, or SEDs) occur. The cloud consisting of few consecutive eruptions typically lasts for several weeks, and then both the cloud and the SEDs disappear. They may reappear again after several months or may stay inactive for a year. Possibly, all the clouds are produced by the same atmospheric disturbance which drifts West at 0.45 °/day. As of March 2007, four such correlated visible and radio storms have been observed since Cassini Saturn Orbit Insertion (July 2004). In all four cases the SEDs are periodic with roughly Saturn's rotation rate (h¹⁰m³⁹), and show correlated phase relative to the times when the clouds are seen on the spacecraft-facing side of the planet, as had been shown for the 2004 storms in [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The 2000-km-scale storm clouds erupt to unusually high altitudes and then slowly fade at high altitudes and spread at low altitudes. The onset time of individual eruptions is less than a day during which time the SEDs reach their maximum rates. This suggests vigorous atmospheric updrafts accompanied by strong precipitation and lightning. Unlike lightning on Earth and Jupiter, where considerable lightning activity is known to exist, only one latitude on Saturn has produced lightning strong enough to be detected during the two and a half years of Cassini observations. This may partly be a detection issue.     

Constraints on Saturn’s tropospheric general circulation from Cassini ISS images

An automated cloud tracking algorithm is applied to Cassini Imaging Science Subsystem high-resolution apoapsis images of Saturn from 2005 and 2007 and moderate resolution images from 2011 and 2012 to define the near-global distribution of zonal winds and eddy momentum fluxes at the middle troposphere cloud level and in the upper troposphere haze. Improvements in the tracking algorithm combined with the greater feature contrast in the northern hemisphere during the approach to spring equinox allow for better rejection of erroneous wind vectors, a more objective assessment at any latitude of the quality of the mean zonal wind, and a population of winds comparable in size to that available for the much higher contrast atmosphere of Jupiter. Zonal winds at cloud level changed little between 2005 and 2007 at all latitudes sampled. Upper troposphere zonal winds derived from methane band images are ～10 m s^?1 weaker than cloud level winds in the cores of eastward jets and ～5 m s^?1 stronger on either side of the jet core, i.e., eastward jets appear to broaden with increasing altitude. In westward jet regions winds are approximately the same at both altitudes. Lateral eddy momentum fluxes are directed into eastward jet cores, including the strong equatorial jet, and away from westward jet cores and weaken with increasing altitude on the flanks of the eastward jets, consistent with the upward broadening of these jets. The conversion rate of eddy to mean zonal kinetic energy at the visible cloud level is larger in eastward jet regions (5.2 × 10^?5 m² s^?3) and smaller in westward jet regions (1.6 × 10^?5 m² s^?3) than the global mean value (4.1 × 10^?5 m² s^?3). Overall the results are consistent with theories that suggest that the jets and the overturning meridional circulation at cloud level on Saturn are maintained at least in part by eddies due to instabilities of the large-scale flow near and/or below the cloud level.     

EVALUATION OF BOTANICAL METHODS OF DATING DEBRIS FLOWS AND DEBRIS-FLOW HAZARD IN THE CANADIAN ROCKY MOUNTAINS

The vegetation on debris flow deposits is examined at seven sites in the Canadian Rocky Mountains. Plant cover, colonizing tree ages, species' presence and abundance, and new stem ages on buried willows are vegetation parameters evaluated for the purpose of dating debris flows. The results indicate that general trends of vegetation development on debris flow deposits can be used to date recent events, at least relatively. The use of several methods to corroborate estimations of deposit age is usually necessary. An optimal approach is to combine absolute and relative dating techniques in evaluating debris flow occurrence, extent, and potential hazard.     

Modelling dam-break flows over mobile beds using a 2D coupled approach

Dam-break flows usually propagate along rivers and floodplains, where the processes of fluid flow, sediment transport and bed evolution are closely linked. However, the majority of existing two-dimensional (2D) models used to simulate dam-break flows are only applicable to fixed beds. Details are given in this paper of the development of a 2D morphodynamic model for predicting dam-break flows over mobile beds. In this model, the common 2D shallow water equations are modified, so that the effects of sediment concentrations and bed evolution on the flood wave propagation can be considered. These equations are used together with the non-equilibrium transport equations for graded sediments and the equation of bed evolution. The governing equations are solved using a matrix method, thus the hydrodynamic, sediment transport and morphological processes can be jointly solved. The model employs an unstructured finite volume algorithm, with an approximate Riemann solver, based on the Roe-MUSCL scheme. A predictor–corrector scheme is used in time stepping, leading to a second-order accurate solution in both time and space. In addition, the model considers the adjustment process of bed material composition during the morphological evolution process. The model was first verified against results from existing numerical models and laboratory experiments. It was then used to simulate dam-break flows over a fixed bed and a mobile bed to examine the differences in the predicted flood wave speed and depth. The effects of bed material size distributions on the flood flow and bed evolution were also investigated. The results indicate that there is a great difference between the dam-break flow predictions made over a fixed bed and a mobile bed. At the initial stage of a dam-break flow, the rate of bed evolution could be comparable to that of water depth change. Therefore, it is often necessary to employ the turbid water governing equations using a coupled approach for simulating dam-break flows.